Insight into the effect of catalytic reactions on correlations of soot oxidation activity and microspatial structures.

A catalyst is usually coated on Diesel particulate filter (DPF) for assisted regeneration. In this paper, the oxidation activity and pore structure evolutions of soot under the effect of CeO2 are explored. CeO2 effectively increases the oxidation activity of soot and reduces the initial activation energy; in the meantime, the addition of CeO2 changes the soot oxidation mode. Pure soot particles tend to produce the porous structure in the oxidation process. Mesopores promote the diffusion of oxygen, and macropores contribute to reduce the agglomeration of soot particles. Additionally, CeO2 provides the active oxygen for soot oxidation and promotes the multi-point oxidation at the beginning of soot oxidation. With the oxidation proceeding, catalysis causes the collapsion of soot microspatial structures, in the meantime, the macropores caused by the catalytic oxidation are filled by CeO2. It results in the tight contact between soot and catalyst, further promoting the formation of the available active oxygen for soot oxidation. This paper is meaningful to analyze the oxidation mechanism of soot under catalysis, which lays a foundation for improving the regeneration efficiency of DPF and reducing the particle emission.

Advances in soot particles from gasoline direct injection engines: A focus on physical and chemical characterisation.

With an increasing market share of gasoline direct injection (GDI) vehicles, high particulate emissions of GDI engines are of increasing concern due to their adverse impacts on both human health and the ecological environment. A thorough understanding of GDI nanoparticulate properties is required to develop advanced particulate filters and assess the exhaust toxicity and environmental impacts. To this end, this paper aims to provide a comprehensive review of the physical and chemical characteristics of GDI nanoparticles from a distinctive perspective, including soot oxidation reactivity, morphology, nanostructure, surface chemistry, chemical components, and their correlations. This review begins with a brief description of nanoparticle characterisation methods. Then, the nanoparticle characteristics of GDI engines are reviewed with the following aspects: in-cylinder soot, exhaust particulate features, and a comparison between GDI and diesel nanoparticles. Previous studies showed that exhaust nanoparticle presents a more stable nanostructure and is less prone to oxidation if compared with in-cylinder soot. Additionally, GDI particles are less-ordered, more inorganic and metallic containing, and more reactive than diesel particles. Afterwards, the impacts of engine operating parameters and aftertreatments on GDI soot features are discussed in detail. Finally, the conclusions and future research recommendations are presented.

Insight into the penalty of exhaust emissions and fuel consumption by DPF regeneration of a diesel passenger car.

In order to keep high fuel economy of diesel passenger cars, Diesel particulate filter (DPF) is periodically regenerated. In the regeneration process, extra fuel is injected into combustion chambers to achieve high exhaust temperature for the purpose of oxidizing particles accumulating on DPF substrate. It generates significant impacts on passenger car performance and exhaust emissions. In this paper, real-driving performance and exhaust emissions of a diesel car were tested over sixteen drivers under real-world conditions. DPF regeneration events were identified via exhaust temperature. Vehicle power output, fuel economy, and exhaust emissions in the trips both with and without DPF regeneration were analyzed. The results indicated that DPF regeneration events occurred in three of thirty-two test trips, and the maximum exhaust temperature was 250 °C during DPF regeneration. The DPF regeneration event led to the decrease of fuel economy and the increase of particle number, nitrogen oxides and carbon dioxides emission. Particle number emission factors were increased from approximately 109 #/km to 5 × 1010 #/km during DPF regeneration. The average power output of the car was in the range of 14.5 kW-15.6 kW and 15.8 kW-18.4 kW for the trips with and without DPF regeneration, respectively. However, Carbon monoxide emission factors were insensitive to DPF regeneration in the test trips.

Impact of vehicle type, tyre feature and driving behaviour on tyre wear under real-world driving conditions.

Tyre wear generates not only large pieces of microplastics but also airborne particle emissions, which have attracted considerable attention due to their adverse impacts on the environment, human health, and the water system. However, the study on tyre wear is scarce in real-world driving conditions. In the present study, the left-front and left-rear tyre wear in terms of volume lost in mm3 of 76 taxi cars was measured about every three months. This study covered 22 months from September 2019 to June 2021 and included more than 500 measurements in total. Some of the data was used to evaluate the effects of vehicle type and tyre type on tyre wear. In addition, a machine learning method (i.e., Extreme gradient boosting (XGBoost)) was used to probe the effect of driving behaviour on tyre wear by monitoring real-time driving behaviour. The current statistical results showed that, on average, the tyre wear was 72 mg veh-1 km-1 for a hybrid car and 53 mg veh-1 km-1 for a conventional internal combustion engine car. The average tyre wear measured for a taxi vehicle configuration featuring winter tyres was 160 mg veh-1 km-1, which was 1.4 and 3.0 times as much as those with all-season tyres and summer tyres, respectively. The wear rate of left-front tyres was 1.7 times higher than that of left-rear tyres. The XGBoost results indicated that compared to driving behaviour, tyre type and tyre position had more important effects on tyre wear. Among driving behaviours, braking and accelerating events presented the most considerable impact on tyre wear, followed by cornering manoeuvres and driving speed. Thus, it seems that limiting harsh braking and acceleration has the potential to reduce tyre wear significantly.

Challenges of the UK government and industries regarding emission control after ICE vehicle bans.

Over the last few decades, the annual air pollutants from internal combustion engine (ICE) vehicles have dropped significantly, benefiting from the implementation of strict emission regulations and the development of vehicle technology. Nitrogen oxides (NOx) and particulate matter (PM) emissions from transport sectors contributed more than 32% and 12% of annual total emissions. Although hazardous exhaust emissions from ICE vehicles will be reduced after the bans on ICE vehicle sales in 2030, sustainable technology development of ICE vehicles is still necessary to meet the future challenges. After-treatment retrofitting technology and Inspection/Maintenance (I/M) are particularly important measures to deal with the deterioration of engines and after-treatment systems.

Catalytic effect of diesel PM derived ash on PM oxidation activity.

With diesel particulate filter and gasoline particulate filter periodical regeneration, more and more ash accumulates on the substrate of filter. Ash gathering on the substrate of filter leads to more contact area of particulate matter and ash. Specific ingredients in ash present catalytic effects on particulate matter oxidation. However, the catalytic effect of diesel particulate matter derived ash on its oxidation, mimicking the ash accumulating on filter substrate, is still uncovered using experiments. In this paper, diesel particulate matter derived ash was put at the bottom of particulate matter samples to imitating the soot loading on filter substrate which was covered by much ash. The results indicated that the burnout temperature of diesel particulate matter was in the range of 500-600 °C; while it was 600-700 °C for Printex (U). The burnout temperature drop by ash was lower than 10 °C for diesel particulate matter. The maximum mass loss rate corresponded to approximately 450 °C for diesel particulate matter, and it was changed minorly by ash and ramp rates. However, the temperature corresponding to the maximum mass loss rate was seriously retarded by high ramp rates for Printex (U), and ash presented limited effect on it. The maximum activation energy drop by ash was approximately 60 kJ/mol at the initial stage of oxidation for diesel particulate matter. The activation energy was approximately 132.19, 114.78, 157.26, and 144.67 kJ/mol for diesel PM, diesel PM-ash, Printex (U), and Printex (U)-ash, respectively. Organic compounds dropped gradually in the oxidation process of diesel particulate matter. Nanostructure evolutions of diesel particulate matter and Printex (U) were similar, experiencing smaller sizes and void cores at the end of oxidation process.

Changes of diesel particle diameter and surface area distributions by non-thermal plasma.

A wide literature has demonstrated that internal combustion engines are the main responsible for the emission of fine particles in urban areas. Within this scope, ultrafine particles within diesel exhausted gas have been widely proven to exert a significantly harmful impact on human health and environment. This scenario has led the research community to turn the attention from particle mass to diameter and surface area. In this paper, non-thermal plasma (NTP) technology was applied to a heavy duty diesel engine. Chemical reactions of diesel particles in plasma zone were analyzed. Additionally, variation in diesel particles' number and surface area distributions, engendered by above reactions, were thoroughly investigated. The results showed that diesel exhausted particles experienced oxidation, aggregation, and crush because of enhanced plasma transports and active species in plasma zone. NTP presents excellent reduction effectiveness of diesel particles covering different sizes. Being more than 50%, the most considerable surface area concentration drop was found in correspondence of 1800 RPM. Differently, the lowest drop of surface area concentration was seen at 1200 RPM. As a result of the NTP actions, surface area concentration distributions were almost the same for diameters being larger than 0.5 µm at different engine modes, except at 900 RPM. This research made a foundation of dropping particle emissions and evaluating the effectiveness of NTP dropping particle harms to human health.

Variations of significant contribution regions of NOx and PN emissions for passenger cars in the real-world driving.

Nitrogen oxides (NOx) and particulate number (PN) emissions are the main concerns of the passenger cars in the real-world driving. NOx and PN emissions are greatly dependent on the driving behaviors which differ significantly between standard driving cycles and real-world driving. However, the significant contribution regions (short durations corresponding to high proportions of total emissions) of NOx and PN emissions regarding different driving behaviors (e.g. vehicle speed and acceleration) are still uncovered. NOx20% and NOx50% refer to instantaneous NOx emission rates when NOx emission rates are ranked from high to low level where the sums of NOx emission rates being higher than NOx20% and NOx50% correspond to 20% and 50% of total NOx emissions, respectively. t20% and t50% are corresponding durations where NOx emission rates are higher than NOx20% and NOx50%. In this paper, three Euro-6 compliant direct injection gasoline passenger cars and a diesel passenger car are tested in a real-world driving trial in which nineteen drivers are involved. Novel key performance indicators with reference to the regimes of specific NOx and PN contributions to total emissions are defined. Instantaneous NOx and PN emissions are monitored using a portable emission measurement system (PEMS) in the test. The results indicate that the maximum and minimum average speed over the four cars being approximately 32.3 km/h s and 42.6 km/h, respectively. Average PN emission factor of the diesel car is the lowest among the four given cars. Average t20% and t50% corresponding to NOx20% and NOx50% are lower than 3% and 12%, respectively, for all the passenger cars; additionally, these two parameters show the same pattern. The corresponding t20% and t50% variations of the Euro-6a gasoline car and the diesel car are much lower than the other two. Average acceleration corresponding to 20% and 50% of total NOx emissions for the given diesel car is approximately 1.25 m/s2 and 0.6 m/s2, respectively, being much higher than that of the other three gasoline cars (lower than 1 m/s2 and 0.4 m/s2 respectively) over the specific driving route and drivers. The average PN20% and PN50% of the given diesel car are approximately 7 × 107#/s and 3 × 107#/s respectively, being much lower than the three given gasoline cars (higher than 8 ×109#/s and 2 ×109#/s respectively) under the given test conditions; the corresponding t20% and t50% are lower than 4% and 17% respectively for all the three gasoline cars.

Comparison of NOx and PN emissions between Euro 6 petrol and diesel passenger cars under real-world driving conditions.

With emission standards becoming stricter, nitrogen oxides (NOx) and particle number (PN) emissions are the main concerns of modern passenger cars, especially for the real-world driving. In this paper, two direct injection (DI) petrol passenger cars and a diesel passenger car are tested on the same routes, driven by the same driver. Instantaneous NOx and PN emissions are monitored by a portable emission measurement system (PEMS) in the tests. During the real-world driving, the exhaust temperatures of the two petrol cars are sufficiently high to ensure high efficiency of three-way catalysts (TWCs). On the other hand, the exhaust temperatures of the diesel car in some sections of the route are lower than the crucial light-off temperature of the selective catalytic reduction (SCR) below which its effectiveness in NOx reduction would be much affected. NOx and PN concentrations are low during motorway driving for the petrol passenger car equipped with a gasoline particulate filter (GPF); however, they are high and change frequently in the whole journey for the petrol passenger car without a GPF. NOx emission factors are quite low over most of the driving sections for the diesel car, but some significant high peaks are observed in the acceleration process. NOx emission distributions over speed and acceleration are similar for both petrol cars; and they differ significantly from the diesel counterpart. Particle size from the diesel car is the largest, followed by the petrol car with a GPF.

Comparative analysis of non-exhaust airborne particles from electric and internal combustion engine vehicles.

This paper evaluates the effect of the electrification of the small, medium, and large internal combustion engine (ICE) passenger cars on the levels of total particulate matter (PM). The total mean PM10 and PM2.5 emission factors (EFs) on urban, rural, and motorway roads are in the range of 26.13 - 39.57 mg km-1 veh-1 and 13.39 - 18.44 mg km-1 veh-1, respectively, from small to large ICE passenger cars. Correspondingly, the total mean PM10 and PM2.5 non-exhaust EFs on urban, rural, and motorway roads range from 27.76 to 43.43 mg km-1 veh-1 and 13.17 -19.24 mg km-1 veh-1 from equivalent small to large electric vehicles (EVs) without regenerative braking. These results show that the total non-exhaust PM from the equivalent EVs may exceed all PM from ICE passenger cars, including exhaust particle emissions, which are dependent mainly on the extent of regenerative braking, followed by passenger car type and road type. PM10 EFs for equivalent EVs without regenerative braking on urban, rural, and motorway roads are all higher than those from ICE cars. As for PM2.5, most of the equivalent EVs require different extents of regenerative braking to reduce brake emissions to be in line with all particle emissions from relative ICE cars.

Real-world emissions of construction mobile machines and comparison to a non-road emission model.

This study implemented real-world tests in Nanjing, China for measuring emission factors (EFs) of air pollutants, including Carbon Monoxide (CO), Hydrocarbon (HC), Nitrogen Oxides (NOx), and Particulate Matter (PM) from ten construction machines in three operational modes (idling, moving, and working) with a Portable Emission Measurement System. The idling mode shows the least variation of EFs, and its average CO EFs can be higher than the moving and working modes by 43% and 34%, respectively. The working mode generates the highest emission for all other pollutants with the highest variation. The EFs suggested by the Guide (an official guidebook for developing emission inventory in China) are in general lower than the measured EFs, and the gap becomes larger for older machines. The EFs of CO, NOx, and PM of China Stage II machines are 24%, 120%, and 66% higher than those of the Guide, respectively. The differences go up as high as 126%, 1066%, and 559% for China Stage I machines, indicating the upgrade of engine technology from Stage I to Stage II, as well as the effect of machine deterioration. The result of this study reveals the effectiveness of stringent emission standards in controlling emissions from construction machines. High emissions from older machines emphasize the importance of a more rigorous machine replacement policy and a regulated maintenance strategy. The result also stresses the need to update the Guide with differentiated activity modes, region variations, and machine deterioration effects.

Correction to "Preliminary Investigations of an Opposed Rotary Piston Compressor for the Air Feeding of a Polymer Electrolyte Membrane Fuel Cell System".

[This corrects the article DOI: 10.1021/acsomega.0c03347.].

Preliminary Investigations of an Opposed Rotary Piston Compressor for the Air Feeding of a Polymer Electrolyte Membrane Fuel Cell System.

Automotive polymer electrolyte membrane fuel cell systems are attracting much attention, driven by the requirements of low automotive exhaust emissions and energy consumption. A polymer electrolyte membrane fuel cell system provides opportunities for the developments in different types of air compressors. This paper proposed an opposed rotary piston compressor, which had the merits of more compact structures, less movement components, and a high pressure ratio, meeting the requirements of polymer electrolyte membrane fuel cell systems. Preliminary performance evaluations of the opposed rotary piston compressor were conducted under various scenarios. This will make a foundation for optimizations of outlet pipe layouts of the compressor. A three-dimensional numerical simulation approach was used; further, in-cylinder pressure evolutions, fluid mass flow rates, and P-V diagrams were analyzed. It indicated that the cyclic period of the opposed rotary piston compressor was half of reciprocating piston compressors. The specific mass flow rate of the compressor is in the range of 0.094-0.113 kg·(s·L)-1 for the given scenarios. Outlet ports 1 and 2 dominated the mass flow in the discharge process under scenarios 1, 3, and 4. In-cylinder pressure profiles show multipeaks for all of these scenarios. In-cylinder pressure increased rapidly in the compression process and part of the discharge process, which led to high energy consumption and low adiabatic efficiency. The maximum adiabatic efficiency is approximately 43.96% among the given scenarios.

Hyperspectral Remote Sensing Image Classification Based on Maximum Overlap Pooling Convolutional Neural Network.

In a traditional convolutional neural network structure, pooling layers generally use an average pooling method: a non-overlapping pooling. However, this condition results in similarities in the extracted image features, especially for the hyperspectral images of a continuous spectrum, which makes it more difficult to extract image features with differences, and image detail features are easily lost. This result seriously affects the accuracy of image classification. Thus, a new overlapping pooling method is proposed, where maximum pooling is used in an improved convolutional neural network to avoid the fuzziness of average pooling. The step size used is smaller than the size of the pooling kernel to achieve overlapping and coverage between the outputs of the pooling layer. The dataset selected for this experiment was the Indian Pines dataset, collected by the airborne visible/infrared imaging spectrometer (AVIRIS) sensor. Experimental results show that using the improved convolutional neural network for remote sensing image classification can effectively improve the details of the image and obtain a high classification accuracy.

Particle- and gas-phase PAHs toxicity equivalency quantity emitted by a non-road diesel engine with non-thermal plasma technology.

Polycyclic aromatic hydrocarbon (PAH) toxicity equivalency quantity (TEQ, denoted by benzo(a)pyrene equivalent (BaPeq) concentration) is more meaningful when evaluating the influence of non-road diesel engines PAH toxicity on environment. Particle- and gas-phase PAH BaPeq concentrations were calculated based on gas chromatography-mass spectrometer (GC-MS) results and toxic equivalency factors. A non-thermal plasma (NTP) reactor was applied to a non-road diesel engine to decrease PAH TEQ content. Only the gas-phase Nap BaPeq concentration increased slightly with the action of NTP at three different generator power outputs. BaP dominated the BaPeq concentration for 15 samples with, and without NTP except in the gas-phase at 4 kW. Almost all medium molecular weight (MMW) and high molecular weight (HMW) PAH TEQs increased for particle- and gas-phases at 3 kW power output compared to 2 kW without the use of NTP. Particle-phase Nap, Acp, and AcPy (low molecular weight, LMW) TEQ were under detection at 3 and 4 kW, while gas-phase BkF, IND, DBA, and BghiP (HMW) concentrations were below the limits of detection. The most abundant PAH TEQ compounds were MMW and HMW PAHs for gas- and particle-phase while they were BaA, CHR, BbF, BaP, and IND for PM aggregation. The total BaPeq emission factors were 15.1, 141.4, and 46.5 µg m(-3) at three engine loads, respectively. Significant BaPeq concentration percentage reduction was obtained (more than 80 and 60 %) with the use of NTP for particle- and gas-phases. A high TEQ content was observed for PM aggregation (38.8, 98.4, and 50.0 µg kg(-1)) which may have caused secondary PAH toxicity emissions. With the action of NTP, the breakup of MMW and HMW into LMW PAHs led to reduction of some PAH concentrations.