Polarization sensitive optical side leakage radiometry for distributed characterization of anti-resonant hollow-core fibers.

A novel technique referred to as optical side leakage radiometry is proposed and experimentally demonstrated for non-destructive and distributed characterization of anti-resonant hollow-core optical fibers with high spatial resolution. Through in-depth analysis of the leakage light collection, we discover a unique polarization dependence, which is validated by our experiment. By leveraging this effect and employing Fourier filtering, this method enables accurate quantification of propagation attenuations for fundamental and higher order modes (with the uncertainty of <1 dB/km), identification of localized defects (with the resolution of ∼5 cm), and measurement of ultra-low spectral phase birefringence (at the level of 10-7) in two in-house-fabricated nested antiresonant nodeless hollow-core fibers. Such a fiber characterization approach, boasting unprecedently high accuracy and a potentially wide dynamic range, holds the potential to become an indispensable diagnosis tool for monitoring and assisting the manufacture of high-quality anti-resonant hollow-core fiber.

Antiresonant fiber-enhanced Raman spectroscopy gas sensing with 1†ppm sensitivity.

Antiresonant hollow-core fiber (AR-HCF) exhibits unprecedented optical performance in low transmission attenuation, broad transmission bandwidth, and single spatial mode quality. However, due to its lower numerical aperture, when utilizing the Fiber-Enhanced Raman Spectroscopy (FERS) principle for gas detection, the efficiency of AR-HCF in collecting Raman signals per unit length is significantly lower than that of hollow-core photonic crystal fiber. Nonetheless, AR-HCF effectively suppresses higher-order modes and offers bandwidth in hundreds of nanometers. By increasing the length of AR-HCF, its advantages can be effectively harnessed, leading to a considerable enhancement in the system's ability for low-concentration gas detection. We combine the nodeless antiresonant hollow-core fiber and Raman spectroscopy for enhanced Raman gas sensing in a forward scattering measurement configuration to investigate the attenuation behavior of the silica background signals. The silica background attenuation behavior enables the low baseline of the gas Raman spectroscopy and extends the integration time of the system. In addition, a convenient spatial filtering method is investigated. A multimode fiber with a suitable core diameter was employed to transmit the signal so that the fiber end face plays the role of pinhole, thus filtering the silica signal and reducing the baseline. The natural isotopes 12C16O2, 13C16O2, and 12C18O16O in ambient air can be observed using a 5-meter-long AR-HCF at 1 bar with a laser output power of 1.8 W and an integration time of 300 seconds. Limits of detection have been determined to be 0.5 ppm for 13C16O2 and 1.2 ppm for 12C16O2, which shows that the FERS with AR-HCF has remarkable potential for isotopes and multigas sensing.

Pump-probe-alternating photothermal interferometry for two-component gas sensing.

We demonstrate a high-sensitivity acetylene/methane gas sensor based on hollow-core fiber photothermal interferometry (PTI) with a pump-probe-alternating technique. This technique utilizes two distributed-feedback lasers as pump and probe beams alternatively for two gas components to facilitate photothermal phase modulation and detection through time-division multiplexing. With a 2.5-cm-long hollow-core conjoint-tube fiber, noise-equivalent concentrations of 370 ppb and 130 ppb are demonstrated for methane and acetylene, respectively. Noise characteristics of the PTI system are analyzed and experimentally tested. The proposed technique eliminates the need for an additional laser in the traditional PTI setup, enabling the construction of a sensitive yet more cost-effective multi-gas component detection system.

Parameter optimization of hollow-core optical fiber phase modulators.

We studied the effect of varying gas concentration, buffer gas, length, and type of fibers on the performance of optical fiber photothermal phase modulators based on C2H2-filled hollow-core fibers. For the same control power level, the phase modulator with Ar as the buffer gas achieves the largest phase modulation. For a fixed length of hollow-core fiber, there exists an optimal C2H2 concentration that achieves the largest phase modulation. With a 23-cm-long anti-resonant hollow-core fiber filled with 12.5% C2H2 balanced with Ar, phase modulation of π-rad at 100 kHz is achieved with a control power of 200 mW. The modulation bandwidth of the phase modulator is 150 kHz. The modulation bandwidth is extended to ∼1.1 MHz with a photonic bandgap hollow-core fiber of the same length filled with the same gas mixture. The measured rise and fall time of the photonic bandgap hollow-core fiber phase modulator are 0.57 µs and 0.55 µs, respectively.

Selectively gas-filled anti-resonant hollow-core fibers for broadband high-purity LP11 mode guidance.

An anti-resonant hollow-core fiber capable of propagating the LP11 mode with high purity and over a wide wavelength range is proposed and demonstrated. The suppression of the fundamental mode relies on the resonant coupling with specific gas selectively filled into the cladding tubes. After a length of 2.7 m, the fabricated fiber shows a mode extinction ratio of over 40 dB at 1550 nm and above 30 dB in a wavelength range of 150 nm. The loss of the LP11 mode is measured to be 2.46 dB/m at 1550 nm. We discuss the potential application of such fibers in high-fidelity high-dimensional quantum state transmission.

Accurate modeling and measurement of pressure-induced group velocity dispersion variations in anti-resonant hollow-core fibers.

Precise control of group velocity dispersion (GVD) by pressure in a gas-filled hollow-core fiber (HCF) is of essential importance for many gas-based nonlinear optical applications. To accurately calculate the pressure-induced dispersion variations (∂ß2/∂p) in anti-resonant types of HCF, an analytical model combining the contribution of the gas material, capillary waveguide, and cladding resonances is developed, with an insightful physical picture. Broadband (∼1000 nm) GVD measurements in a single-shot manner realize accuracy and precision as low as 0.1 ps2/km and 2 × 10-3 ps2/km, respectively, and validate our model. Consistent with our model, a pronounced negative ∂ß2/∂p is observed experimentally for the first time, to our knowledge. Our model can also be extended to other HCFs with cladding resonances in predicting ∂ß2/∂p, such as in photonic bandgap types of HCF.

Amplified Photothermal Phase Modulation for Carbon Dioxide Detection by Operating a Dual-Mode Interferometer at Destructive Interference.

Photothermal interferometry is a highly sensitive spectroscopic technique for trace gas detection. However, the performance of the state-of-the-art laser spectroscopic sensors is still insufficient for some high-precision applications. Here, we demonstrate optical phase-modulation amplification by operating a dual-mode optical fiber interferometer at destructive interference for ultrasensitive carbon dioxide detection. With a 50 cm long dual-mode hollow-core fiber, amplification of photothermal phase modulation by a factor of nearly 20 is achieved, which enables carbon dioxide detection down to 1 parts-per-billion with a dynamic range of over 7 orders of magnitude. This technique could be readily used to improve the sensitivity of phase modulation-based sensors with a compact and simple configuration.

Birefringent, low loss, and broadband semi-tube anti-resonant hollow-core fiber.

We report on the design, fabrication, and characterization of a low-loss birefringent semi-tube anti-resonant hollow-core fiber (AR-HCF). By optimizing the structure design and the stack-and-draw fabrication technique, a transmission loss of 4.8 dB/km at 1522 nm, a <10 dB/km bandwidth of 154 nm, and a phase birefringence of 1.8 × 10-5 are demonstrated. This achieved loss is more than one order of magnitude lower than the previously reported birefringent AR-HCF and the bandwidth is one order of magnitude broader than the reported birefringent photonic bandgap hollow-core fiber (PBG-HCF) with the same loss level. The polarization extinction ratio (PER) reaches the ∼20 dB level in a 90 m-long fiber under >25 cm bending radius. Combined with the single mode and low dispersion features, the developed semi-tube AR-HCF may find a variety of applications in frequency metrology, interferometric fiber gyroscopes, and long-baseline stellar interferometry.

Air flowing induced thermo-optic effect for thermal sensitivity reduction in anti-resonant hollow core fibers.

The signal propagation delay through an optical fiber changes with environmental temperature, imposing a fundamental limit on performances in many fiber-optic applications. It has been shown that the thermal coefficient of delay (TCD) in hollow core fibers (HCFs) can be 20 times lower than in standard single-mode fibers (SSMFs). To further reduce TCD over a broad wavelength range at room temperature, so that to enrich fiber-optic applications in time- synchronization scenarios, the thermal expansion effect of silica glass must be compensated for. Exploiting the thermo-optic effect of air inside an anti-resonant hollow core fiber (ARF) can be a feasible solution. Nevertheless, an accurate description of the air flow in the course of temperature variation is highly needed to predict the influence of this effect. This work develops an analytical model for quantitatively calculating this temperature-induced air-flowing effect. Across a range of parameters of core diameter, fiber length, and temperature change rate, the experimentally measured propagation delay changes agree well with our model. The resultant low thermal sensitivity is also validated in non-steady conditions and in a practically usable SSMF-ARF-SSMF chain. Our model indicates that a >40-fold TCD reduction relative to SSMFs can be realized in a 60-m-long, 50-µm-diameter ARF, and further TCD reduction should be possible by properly engineering the gas type and the ambient pressure.

Hollow-core anti-resonant fiber based light-induced thermoelastic spectroscopy for gas sensing.

In this paper, a hollow-core anti-resonant fiber (HC-ARF) based light-induced thermoelastic spectroscopy (LITES) sensor is reported. A custom-made silica-based HC-ARF with length of 75 cm was used as light medium and gas cell. Compared to a traditional multi-pass cell (MPC), the using of HC-ARF is advantageous for reducing the sensor size and easing the optical alignment. A quartz tuning fork (QTF) with a resonant frequency of 32766.20 Hz and quality factor of 12364.20 was adopted as the thermoelastic detector. Acetylene (C2H2) and carbon monoxide (CO) with absorption lines located at 6534.37 cm-1 (1530.37 nm) and 6380.30 cm-1 (1567.32 nm) were chosen as the target gas to verify such HC-ARF based LITES sensor performance. It was found that this HC-ARF based LITES sensor exhibits excellent linearity response to the analyte concentrations. The minimum detection limit (MDL) for C2H2 and CO detections were measured as 4.75 ppm and 1704 ppm, respectively. The MDL for such HC-ARF based LITES sensor can be further improved by using a HC-ARF with long length or choosing an absorption line with strong strength.

Background-penalty-free waveguide enhancement of CARS signal in air-filled anti-resonance hollow-core fiber.

We study coherent anti-Stokes Raman spectroscopy in air-filled anti-resonance hollow-core photonic crystal fiber, otherwise known as "revolver" fiber. We compare the vibrational coherent anti-Stokes Raman signal of N2, at ∼2331 cm-1, generated in ambient air (no fiber present), with the one generated in a 2.96 cm of a revolver fiber. We show a ∼170 times enhancement for the signal produced in the fiber, due to an increased interaction path. Remarkably, the N2 signal obtained in the revolver fiber shows near-zero non-resonant background, due to near-zero overlap between the laser field and the fiber cladding. Through our study, we find that the revolver fiber properties make it an ideal candidate for the coherent Raman spectroscopy signal enhancement.

Frequency-Division-Multiplexed Multicomponent Gas Sensing with Photothermal Spectroscopy and a Single NIR/MIR Fiber-Optic Gas Cell.

We report a multicomponent gas sensor based on hollow-core fiber (HCF) photothermal spectroscopy with frequency-division multiplexing (FDM). A single antiresonant HCF (AR-HCF) is used as the gas cell, which supports broadband transmission from near-infrared (NIR) to mid-infrared (MIR), covering the absorption lines of water vapor (H2O) at 1.39 µm, carbon dioxide (CO2) at 2.00 µm, and carbon monoxide (CO) at 4.60 µm. The NIR and MIR pump lasers at the above wavelengths are coupled into the AR-HCF from the opposite ends and modulated at 7.5, 8.0, and 8.5 kHz, respectively, to produce photothermal phase modulations at different frequencies. A common probe Fabry-Perot interferometer at 1.55 µm is adopted to detect the phase modulations, which are demodulated simultaneously using three lock-in amplifiers at the respective second harmonic frequencies. With a 13-cm-long AR-HCF, simultaneous detections of H2O, CO2, and CO are demonstrated with the limits of detection (LODs) of 2.7 ppm, 25 ppb, and 9 ppb for 1 s lock-in time constant, respectively. The LODs go down to 222, 1.5, and 0.6 ppb, respectively, for 1000 s averaging time. The photothermal signals of CO and CO2, which are humidity-level dependent, are well calibrated by use of the measured H2O signal. The multicomponent gas sensor is compact in configuration and shows good stability with signal fluctuation less than 1.7% over 2 h.

High extinction ratio and low backreflection polarization maintaining hollow-core to solid-core fiber interconnection.

We develop a hybrid cold/heat two-step splicing approach for low loss, low backreflection, and high polarization extinction ratio (PER) hollow-core to solid-core fiber interconnection. The employed hollow-core fiber (HCF) is our recently developed high-birefringence polarization-maintaining hollow-core fiber (PM-HCF) with a PER value of ∼30 dB, and the solid-core fiber (SCF) is a commercial Panda polarization-maintaining fiber (Panda fiber). Simultaneous low backreflection (<-35 dB), low insertion loss (IL) (∼0.7 dB), and high PER (∼27 dB) are achieved, representing the first high-performance PM-HCF/SCF interconnections, to the best of our knowledge. This greatly facilitates the applications of PM-HCF in widespread fields such as precise metrologies, gyroscopes, and ultrafast/high-power laser deliveries.

Connector-style hollow-core fiber interconnections.

To go beyond the fundamental limits imposed by latency, nonlinearity, and laser damage threshold in silica glass fibers, the hollow-core fiber (HCF) technique has been intensively investigated for decades. Recent breakthroughs in ultralow-loss HCF clearly imply that long-haul applications of HCF in communications and lasers are going to appear. Nevertheless, up to now, the HCF technique as a whole is still hampered by the limited length of a single span and the lack of HCF-based functional devices. To resolve these two issues, it is of importance to develop ultralow-loss and plug-and-play HCF interconnections. In this work, we report on HCF interconnections with the lowest-ever insertion losses (0.10 dB for HCF to standard single-mode fiber (SMF) and 0.13 dB for HCF to itself in the 1.5 µm waveband) and in a pluggable means. Two fiber mode-field adapters, one based on a graded-index multi-mode fiber (GIF) and the other utilizing a thermally expanded core (TEC) SMF, have been tested and compared. An extra insertion loss arising from imperfect refractive index distribution in a commercial GIF is observed. Our HCF interconnections also realize a back-reflection of <-35 dB over a 100 nm bandwidth as well as other critical metrics in favor of practical applications. Our technique is viable for any type of HCF.

Towards high-power mid-IR light source tunable from 3.8 to 4.5 µm by HBr-filled hollow-core silica fibres.

Fibre lasers operating at the mid-IR have attracted enormous interest due to the plethora of applications in defence, security, medicine, and so on. However, no continuous-wave (CW) fibre lasers beyond 4 µm based on rare-earth-doped fibres have been demonstrated thus far. Here, we report efficient mid-IR laser emission from HBr-filled silica hollow-core fibres (HCFs) for the first time. By pumping with a self-developed thulium-doped fibre amplifier seeded by several diode lasers over the range of 1940-1983 nm, narrow linewidth mid-IR emission from 3810 to 4496 nm has been achieved with a maximum laser power of about 500 mW and a slope efficiency of approximately 18%. To the best of our knowledge, the wavelength of 4496 nm with strong absorption in silica-based fibres is the longest emission wavelength from a CW fibre laser, and the span of 686 nm is also the largest tuning range achieved to date for any CW fibre laser. By further reducing the HCF transmission loss, increasing the pump power, improving the coupling efficiency, and optimizing the fibre length together with the pressure, the laser efficiency and output power are expected to increase significantly. This work opens new opportunities for broadly tunable high-power mid-IR fibre lasers, especially beyond 4 µm.

Microfluidic Raman Sensing Using a Single Ring Negative Curvature Hollow Core Fiber.

A compact microfluidic Raman detection system based on a single-ring negative-curvature hollow-core fiber is presented. The system can be used for in-line qualitative and quantitative analysis of biochemicals. Both efficient light coupling and continuous liquid injection into the hollow-core fiber were achieved by creating a small gap between a solid-core fiber and the hollow-core fiber, which were fixed within a low-cost ceramic ferrule. A coupling efficiency of over 50% from free-space excitation laser to the hollow core fiber was obtained through a 350 µm-long solid-core fiber. For proof-of-concept demonstration of bioprocessing monitoring, a series of ethanol and glucose aqueous solutions at different concentrations were used. The limit of detection achieved for the ethanol solutions with our system was ~0.04 vol.% (0.32 g/L). Such an all-fiber microfluidic device is robust, provides Raman measurements with high repeatability and reusability, and is particularly suitable for the in-line monitoring of bioprocesses.

Fiber-enhanced Raman spectroscopy for highly sensitive H2 and SO2 sensing with a hollow-core anti-resonant fiber.

An innovative fiber-enhanced Raman gas sensing system with a hollow-core anti-resonant fiber is introduced. Two iris diaphragms are implemented for spatial filtering, and a reflecting mirror is attached to one fiber end that provides a highly improved Raman signal enhancement over 2.9 times than the typical bare fiber system. The analytical performance for multigas compositions is thoroughly demonstrated by recording the Raman spectra of carbon dioxide (CO2), oxygen (O2), nitrogen (N2), hydrogen (H2), and sulfur dioxide (SO2) with limits of detection down to low-ppm levels as well as a long-term instability < 1.05%. The excellent linear relationship between Raman signal intensity (peak height) and gas concentrations indicates a promising potential for accurate quantification.

Hollow-core fiber photothermal methane sensor with temperature compensation.

We demonstrate a high sensitivity all-fiber spectroscopic methane sensor based on photothermal interferometry. With a 2.4-m-long anti-resonant hollow-core fiber, a 1654 nm distributed feedback laser, and a Raman fiber amplifier, a noise-equivalent concentration of ${\sim}{4.3}\;{\rm ppb}$ methane is achieved at the room temperature and pressure of ${\sim}{1}\;{\rm bar}$. The effects of temperature on the photothermal phase modulation as well as the stability of the interferometer are studied. By introducing a temperature-dependent compensation factor and stabilizing the interferometer at quadrature, signal instability of ${\sim}{2.1}\%$ is demonstrated for temperature variation from 296 to 373 K.

Background-free fibre optic Brillouin probe for remote mapping of micromechanics.

Brillouin imaging (BI) has become a valuable tool for micromechanical material characterisation, thanks to extensive progress in instrumentation in the last few decades. This powerful technique is contactless and label-free, thus making it especially suitable for biomedical applications. Nonetheless, to fully harness the non-contact and non-destructive nature of BI, transformational changes in instrumentation are still needed to extend the technology's utility into the domain of in vivo and in situ operation, which we foresee to be particularly crucial for wide spread usage of BI, e.g. in medical diagnostics and pathology screening. This work addresses this challenge by presenting the first demonstration of a fibre-optic Brillouin probe, capable of mapping the micromechanical properties of a tissue-mimicking phantom. This is achieved through combination of miniaturised optical design, advanced hollow-core fibre fabrication and high-resolution 3D printing. Our prototype probe is compact, background-free and possesses the highest collection efficiency to date, thus providing the foundation of a fibre-based Brillouin device for remote, in situ measurements in challenging and otherwise difficult-to-reach environments in biomedical, material science and industrial applications.

Ethane detection with mid-infrared hollow-core fiber photothermal spectroscopy.

We report a compact mid-infrared (MIR) photothermal spectroscopic ethane (C2H6) sensor with a hollow-core negative-curvature-fiber (HC-NCF) gas cell. The HC-NCF supports low-loss transmission of an MIR pump (3.348 µm) and a near-infrared (NIR) probe (1.55 µm). The pump and probe laser beams are launched into the gas cell from the opposite ends of the HC-NCF, allowing independent MIR pump delivery and NIR fiber-optic probe circuitry. The use of Fabry-Perot as the probe interferometer simplifies the sensor design and suppresses the common-mode noise in the lead in/out single-mode fiber. With a 14-cm-long HC-NCF, an ethane sensor system with the limit of detection (LOD) of 13 parts-per-billion (ppb) is achieved with 1 s lock-in time constant. The LOD goes down to 2.6 ppb with 410 s average time, which corresponds to noise equivalent absorption (NEA) of 2.0×10-6 and is a record for the hollow-core fiber MIR gas sensors. The system instability is 2.2% over a period of 8 hours.