ABSTRACT
Multimodal flexible sensors, consisting of multiple sensing units, can sense and recognize different external stimuli by outputting different types of response signals. However, the recovery and recycling of multimodal sensors are impeded by complex structures and the use of multiple materials. Here, a bimodal flexible sensor that can sense strain by resistance change and temperature by voltage change was constructed using poly(vinyl alcohol) hydrogel as a matrix and poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS) as a sensing material due to its conductivity and thermoelectric effect. The plasticity of hydrogels, along with the simplicity of the sensor's components and structure, facilitates easy recovery and recycling. The incorporation of citric acid and ethylene glycol improved the mechanical properties, strain hysteresis, and antifreezing properties of the hydrogels. The sensor exhibits a remarkable response to strain, characterized by high sensitivity (gauge factor of 4.46), low detection limit (0.1%), fast response and recovery times, minimal hysteresis, and excellent stability. Temperature changes induced by hot air currents, hot objects, and light cause the sensor to exhibit high response sensitivity, fast response time, and good stability. Additionally, variations in ambient humidity and temperature minimally affect the sensor's strain response, and temperature response remains unaffected by humidity changes. The recycled sensors are essentially unchanged for bimodal sensing of strain and temperature. Finally, bimodal sensors are applied to monitor body motion, and robots to sense external stimuli.
ABSTRACT
Green electromagnetic interference (EMI) shielding materials not only require high shielding effectiveness (SE) and low reflection but also need to be recyclable after damage; however, it is challenging to strike a balance in practice. Here, a polyacrylamide (PAM) composite composed of numerous chemically cross-linked PAM@carbon nanotube (cPAM@CNT) core-shell particles featuring rich wrinkled microstructures was prepared using an adsorption-drying-shrinking strategy. The wrinkled microstructures enable the incident electromagnetic waves (EMWs) to undergo attenuation within the composites, achieving an average EMI SE of 67.5 dB in the X band. Due to the hygroscopicity of hydrophobically associated PAM (hPAM, an adhesive for cPAM@CNTs core-shell particles), the average EMI SE of the composites further increased to 83.2 dB after exposure to 91% relative humidity for 24 h, with only a 2.7 dB low reflection. Additionally, the composites also demonstrated excellent Joule heating, photothermal performance, and recyclability, which exhibit substantial promise for advanced EMI shielding applications.
ABSTRACT
The diversity of body joints and the complexity of joint motions cause flexible strain sensors to undergo complex strains such as stretching, compression, bending, and extrusion, which results in sensors that do not recognize different strains, facing great challenges in detecting the true motion characteristics of joints. Here, the monitoring of body joints' real motion characteristics has been realized by the sensor that can output response signals with different resistance trends for different strains. The sensor prepared by the sacrificial template method is characterized by a multilayered interlaced tunnel architecture and carbon black embedded in the inner wall of the tunnel. Stretching, compressive, and bending strains result in increasing, decreasing, and increasing resistance, followed by a decrease in resistance of the sensor, respectively. The sensor can still output distinguishable response signals, even in the presence of complex strains induced by squeezing. Low strain detection limits (0.03%) and wide detection ranges (>600%) are achieved due to the localized strain enhancement caused by the unique structure. The sensor can detect the motion characteristics of different joints in flexion-extension, abduction-adduction, and internal-external rotation, which, in turn, can be used for real-time monitoring of complex joint motions involved in limb rehabilitation. In addition, the sensor recognizes the 26 letters of the alphabet represented by sign language gestures. The above studies demonstrate the potential application of our prepared sensors in flexible, wearable devices.
ABSTRACT
Flexible tactile sensors, with the ability to sense and even discriminate between different mechanical stimuli, can enable real-time and precise monitoring of dexterous and complex robotic motions. However, making them ultrathin and superhydrophobic for practical applications is still a great challenge. Here, superhydrophobic flexible tactile sensors with hierarchical micro- and nanostructures, that is, warped graphene nanosheets adhered to micron-height wrinkled surfaces, were constructed using ultrathin medical tape (40 µm) and graphene. The tactile sensor enables the discrimination of normal and shear forces and senses sliding friction and airflow. Moreover, the tactile sensor exhibits high sensitivity to normal and shear forces, extremely low detection limits (15 Pa for normal forces and 6.4 mN for shear forces), and cyclic robustness. Based on the abovementioned characteristics, the tactile sensor enables real-time and accurate monitoring of the robotic arm's motions, such as moving, gripping, and lifting, during the process of picking up objects. The superhydrophobicity even allows the sensor to monitor the motions of the robotic arm underwater in real time. Our tactile sensors have potential applications in the fields of intelligent robotics and smart prosthetics.
ABSTRACT
Flexible sensors with wide sensing ranges require responsiveness under tiny and large strains. However, the development of strain sensors with wide detection ranges is still a great challenge due to the conflict between the tiny strain requirements of sparse conductive networks and the large strain requirement of dense conductive networks. Herein, we present a facile method for fabricating a gradient conductive network composed of sparse and dense conductive networks. The surface penetration technology in which carbon black (CB) penetrated from the natural rubber latex (NRL) glove surface to the interior was used to fabricate a gradient conductive network. The prolonged immersion time from 1 to 30 min caused the penetration depth of CB to increase from 2 to 80 µm. Moreover, CB formed hierarchical rough micro- and nanoscale structures, creating a superhydrophobic surface. The gradient conductive network of sensors produced an ultrawide detection range of strain (0.05-300%) and excellent reliability and reproducibility. The sensors can detect a wide range of human motions, from tiny (wrist pulse) to large (joint movements) motion monitoring. The flexible sensors attached to a flexible basement can be used to detect pressure in a wide detection range (1.7-2900 kPa). Pressure responsiveness was used to detect the weight, sound pressure, and dripping of tiny droplets. The sensor showed an excellent response to organic solvents, and the response intensity increased with the increasing swelling degree of the solvent for NRL.
ABSTRACT
[This retracts the article DOI: 10.1021/acsomega.8b00488.].
ABSTRACT
In this study, the formability of woven carbon-fiber (CF)-reinforced polyether-ether-ketone (PEEK) composite sheets in the solid-state thermoforming process were investigated, and the failure mechanisms were discussed. The formability of the woven CF/PEEK sheets were analyzed using flexural tests, Erichsen test, and microscopic observation. The results show that the formability of CF/PEEK sheets significantly increases as the temperature rises from 165 to 325 °C, and slightly decreases as the deformation speed rises from 2 to 120 mm/min. The deformation of the sheets is caused by plastic deformation, shear deformation and squeeze deformation, without plastic thinning and fiber slippage, which is due to the restriction of the solid matrix and locked fibers. Moreover, the wrinkles will cause fiber fracture at lower temperatures and delamination at higher temperatures. At higher temperatures, the wrinkles mainly occur at the position with [0°/90°] fibers due to the squeezing of the matrix and fibers.
ABSTRACT
A compatibilizer was melt-blended with intumescent flame-retardant linear low-density polyethylene/nylon six blends (LLDPE/PA6/IFR) by different methods, and the effect of microstructure on the flame retardancy, mechanical properties, and water resistance was investigated. Melt-blending compatibilizers with LLDPE/PA6/IFR above the polyamide-6 (PA6) melt temperature formed the microstructure with IFR dispersion in the LLDPE matrix and good interphase adhesion between the PA6 phase and the matrix. Compared with the blends with the lack of compatibilizers, although good interphase adhesion improved the mechanical properties and water resistance, IFR dispersion in the LLDPE matrix reduced the flame retardancy sharply. To obtain the microstructure with IFR dispersion in the PA6 phase and strong interface adhesion of the PA6 phase with a matrix, a novel method in which a compatibilizer was melt-blended with LLDPE/PA6/IFR between the melt temperatures of LLDPE and PA6 was employed. The results showed that the flame retardancy, mechanical properties, and water resistance were improved simultaneously.