Failures analysis of tube coating in Circulating Fluidized Bed (CFB) boiler.

Circulating Fluidized Bed (CFB) boiler often experience leaks in the wall tube due to corrosion and abrasion of the bed material after use that varies between 3 and 8 months. To avoid erosion corrosion, a coating was done in the form of Chrome Clad Tube Armor (CTA). In this research, a Failure Analysis (FA) was performed on the characterization of the boiler tube using several types of samples, which are Wall Tube Without Coating (WT) and CTA (in new condition and after eight months of use). Macro visual, Field emission scanning electron microscopes (FE-SEM), Fourier-transform infrared spectroscopy (FTIR), corrosion, and Thermogravimetric analysis (TGA) tests showed that the CTA type has better corrosion and thermal resistance. The hardness values of the CTA and WT coating substrates after eight months of use were 197.75 and 195.2 HV. The failure mechanism on the tube was caused by high temperatures (long-term overheating) and friction between the tube and the fluid or metal. Wall tubes in furnaces fail due to erosion and corrosion due to fluid and solid particle mixtures and environmental contact.

Modification of palm fiber with chitosan-AESO blend coating.

Natural fibers are available as an essential substitute for synthetic fiber in many applications. However, the sensitivity of Chinese Windmill Palm or Trachycarpus Fortune Fiber (TFF) to water causes low interfacial bonding between the matrix and the fiber and at the end reduces the mechanical properties of the composite product. Alkaline treatment improves mechanical properties and does not affect water absorption. Hence, additional treatment in the coating is required. This study uses alkaline treatment and coating modification using blended chitosan and Acrylated Epoxidized Soybean Oil (AESO). Blend coating between AESO and chitosan is performed to increase water absorption and mechanical properties. TFF water resistance improved significantly after the coating, with water absorption of the alkaline/blend coating-TFF of 3.98 % ± 0.52 and swell ability of 3.156 % ± 0.17. This indicated that blend coating had formed a cross-link of fiber and matrix after alkalization. Thus, the single fiber tensile strength increased due to the alkaline treatment, and water absorption decreased due to the coating. The combination of alkaline treatment and blend coating on TFF brings excellent properties, as shown by the increase in tensile strength in both single fiber test and composite.

Isolation of microcellulose from timoho fiber using the process of delinigfication and maceration: Evaluation of physical, chemical, structural, and thermal properties.

Timoho fiber (TF) is a biodegradable bio-fiber rich in cellulose and a renewable agro textile fiber rich in cellulose polysaccharides. Isolation of micro cellulose from TF is an alternative reinforcement approach in a bio-composite application. This study characterized TF obtained from isolation employing FTIR, XRD, SEM-EDS, and TGA using hydrolysis. Pretreatment was done using alkaline, bleaching, and hydrolysis. FTIR confirmed that the maximum amount of noncellulosic materials had been removed from TF. The XRD result showed that hydrolysis treatment increased the crystal size and crystallinity index of the TF (88.68 %). TGA also revealed that the highest thermal stability had been found in the hydrolyzed TF. The micro cellulose TF represented an interesting source of cellulose reinforcing materials, and it might be continued in the form of nano cellulose.

Corrosion Inhibition of Honeycomb Waste Extracts for 304 Stainless Steel in Sulfuric Acid Solution.

The extract of honeycomb waste was studied as a corrosion inhibitor on 304 stainless steel in H2SO4 solutions. The honeycomb waste was obtained from beekeeping at Lawang-Malang, East Java, Indonesia. Electrochemical and scanning electron microscopy methods were used to investigate the performance of the corrosion inhibition process. The inhibition efficiency of the inhibitor (2000 mg/L) reached 97.29% in 0.5 M H2SO4 and decreased with the acid concentration. Kinetic parameters were calculated to explain the effect of acid concentration on the inhibition process. The study on the adsorption behavior of the extracts followed the Frumkin isotherm model. The adsorption of the inhibitor on the 304 stainless steel surface was confirmed by the negative and lower values of Gibbs free energy. The obtained scanning electron microscopy (SEM) images were confirmed by comparing the surface of the specimens with and without inhibitor after corroding for one week. The results indicated that the extract acted as a good inhibitor for 304 stainless steel in acid corrosion.