Investigation of natural radionuclides and radiation shielding potential of some commonly used building materials in Northwestern Nigeria.

This study assessed the gamma-ray shielding potential of clay, sand, gypsum and kaolin commonly used as a building material in Northwestern, Nigeria. The radiological status of the samples was first evaluated by determining the activity concentrations of 238U, 232Th and 40K using NaI (Tl) detector after which elemental composition and mass density were determined using Neutron Activation Analytical Technique. After which the mass attenuation coefficients (MAC), linear attenuation coefficients (LAC), half value layer (HVL), tenth value layer (TVL), and effective atomic number (Zeff) were determined experimentally and theoretically using standard point sources of 137Cs and 60Co photon peaks (0.662 and 1.332, 1.173) MeV and Py-MLBUF software. The activity concentrations were found to range from 51 to 59 Bq kg-1 with a mean value of 59 Bq kg-1 for 238U, 24 to 27 Bq kg-1 with a mean value of 29 Bq kg-1 for 232Th, and 219 to 247 Bq kg-1 with a mean value of 247 Bq kg-1 for 40K which were about within the world recommended values of 33, 45 and 420 Bq kg-1 respectively. The results of the elemental compositions show that Si, Al, K, Fe, and Ba in clay and sand samples have concentrations in the range of 36.83-78.48%, 1.92-26.05%, 6.33-21.96%, 2.39-19.09%, and 0.09-1.44%, respectively, while in kaolin and gypsum, results revealed that Si, Al, K, Fe, and Ca range between 0.34 and 65.52%, 1.14-35.82%, 0.00-12.12%, 0.00-5.77%, and 0.00-96.6%, respectively. However, the concentrations of other elements such as Mg, Ti, Mn, Zn, Na, and Ba varied significantly with the samples. The results showed that clay has an average density of 1.96 g/cm3, sand has 2.32 g/cm3, kaolin has 2.63 g/cm3, and gypsum has the highest density with a value of 2.66 g/cm3 compared to other samples. During the measurements, a thallium-activated sodium-iodide NaI (TI) detector was used. A narrow beam transmission geometry condition was adopted for the measurements to ensure minimal scattered radiation. Absorption and attenuation of gamma beams as a function of sample thickness against gamma energy generally exhibit an increasing gamma ray behaviour as the sample thickness increases from 1 to 3 cm. The results showed that the gypsum, kaolin, sand, and clay were capable of attenuating 63.5%, 61.5%, 58.4%, and 44.2 of gamma-ray photons of energy 0.662 MeV at 3 cm thickness %, respectively, and 40.6%, 32.9%, 30.6%, and 27.3% of gamma energy 1.332 MeV at 3 cm thickness, respectively. The results showed that MAC, LAC, and Zeff of all the samples decreased with an increase in photon energy, while those of HVL and TVL increased. The experimental results for all the gamma-ray shielding parameters were found to be in good agreement with the theoretical values obtained using Py-MLBUF. The results have shown that all the samples have similar photon attenuation behaviours; however, gypsum has the best shielding potential than kaolin and this is attributed due to its highest density value.

Radiological consequence analysis for hypothetical accidental release from Nigerian Research Reactor-1.

Radiological dispersion study is a key element in safety analysis report (SAR) of every nuclear facility for the purpose of emergency response planning. In this work, computational approach was used to determine the total effective dose and ground deposition at critical positions onsite and offsite of the Nigerian Research Reactor-1 (NIRR-1) facility which will be useful in the ongoing development of final SAR for NIRR-1 Low Enriched Uranium (LEU) core. In the methodology used, NIRR-1 LEU core was depleted with TRITON module of SCALE 6.2.3 code and the fission inventory in the core was calculated after a continuous operation at full power of 231.931MWD/MTU for 918 Effective Full Power Days (EFPD) at an operation regime of 3 h per day, 3 days per week and 48 weeks per year. Hot Spot was employed for atmospheric transport and dose calculations with consideration of different accidental scenarios in which 20%, 30%, 60% and 100% gaseous inventory was hypothetically released into the atmosphere. From the results obtained, the total effective dose to maximum exposed workers at 10 m and maximum exposed members of public at 300 m from the reactor were 3.10mSvand0.43mSv respectively for the worst-case scenario with 100% release while the maximum ground deposition was 5.5×106Bq/m2 with corresponding maximum ground shine dose rate of 7.5×10-4mSv/hr. This results are at least one order of magnitude below the dose limits recommended by the International Commission on Radiological Protection (ICRP) and indicate that the present LEU core of NIRR-1 is unlikely to cause any detectable health effect on workers and members of public in the event that 100% of its gaseous inventory is released into air in the environment. Hence it could unequivocally be said that the population is safe from the operation of NIRR-1 in its present location.

Application of RESRAD and ERICA tools to estimate dose and cancer risk for artisanal gold mining in Nigeria.

Despite the fact that disruption of the environment through mining of minerals poses severe radiological hazards, there is a dearth of radiological information from gold mining sites in Nigeria. In this study, state-of- the-art computational tools - RESRAD ONSITE, RESRAD OFFSITE and ERICA were applied to a typical representative artisanal goldmining area for a more comprehensive evaluation of radiological risks associated with artisanal gold mining in Nigeria. The estimated doses received by an offsite receptor is within the radiation basic safety limit, while for onsite receptor it is greater than the basic radiation safety limit. It was observed that onsite dwellers of the artisanal goldmining areas may suffer high cancer burden when compared with the US EPA acceptable levels. For non-human biota, the hazard quotient was greater than unity and the total dose rate per organism was greater than the screening dose rate of 10µGy h-1. It was observed that 232Th and 226Ra were the main contributors to the total dose and the pathways that contributed most to the dose were; external exposure (via direct and airborne radiation from soil and Radon) as well as water independent plant, meat and milk consumption. Therefore, monitoring food production will lead to an informed decision making and risk communication towards sustainable mining will contribute in minimizing the level of the anticipated risks as low as reasonably achievable.

Determination of rare earth elements concentration at different depth profile of Precambrian pegmatites using instrumental neutron activation analysis.

The Keffi area hosts abundant pegmatite bodies as a result of the surrounding granitic intrusions. Keffi is part of areas that are geologically classified as North Central Basement Complex. Data on the mineralogy and mineralogical zonation of the Keffi pegmatite are scanty. Hence the need to understand the geology and mineralogical zonation of Keffi pegmatites especially at different depth profiles is relevant as a study of the elemental composition of the pegmatite is essential for the estimation of its economic viability. Here, the relative standardization method of instrumental neutron activation analysis (INAA) has been used to investigate the vertical deviations of the elemental concentrations of rare earth elements (REEs) at different depth profile of Keffi pegmatite. This study adopted the following metrics in investigating the vertical variations of REEs concentrations. Namely, the total contents of rare earth elements (∑REE); ratio of light to heavy rare earth elements (LREE/HREE), which defines the enrichment or depletion of REEs; europium anomaly (Eu/Sm); La/Lu ratio relative to chondritic meteorites. The study showed no significant variations in the total content of rare elements between the vertical depth profiles (100-250m). However, higher total concentrations of REEs (~ 92.65ppm) were recorded at the upper depth of the pegmatite and the europium anomaly was consistently negative at all the depth profiles suggesting that the Keffi pegmatite is enriched with light REEs.

Effect of NiO/SiO2 on thermo-chemical conversion of waste cooking oil to hydrocarbons.

Increase in organic waste generation, dwindling nature of global oil reserves coupled with environmental challenges caused by waste oil disposal and burning of fossil fuels necessitated the need for alternative energy resources. Waste cooking oil obtained from the frying fish outlet was analyzed for its physicochemical properties using ASTM D-975 methods. Acid and Iodine values of the oil were 30.43 ± 0.32 mgKOH/g and 57.08 ± 0.43 mgI2/100 g respectively. Thermo-chemical conversion of the oil using NiO/SiO2 at different reaction conditions (pressure, temperature, and catalyst concentration) at a residence time of 3 h yielded 33.63% hydrocarbons. Hydro-catalytic pyrolysis of waste cooking oil at 400 °C, H2 pressure of 15 bars, and catalyst to oil ratio of 0.25 g/100 cm3 resulted in highest hydrocarbon yield (41.98%). The fuel properties of the product were: cetane number (71.16), high heating value (41.43 MJ/kg), kinematic viscosity (2.01 mm2/s), density (0.94 g/ml), saponification value (185.1 ± 3.96 mgKOH/g), and iodine value (20.57 ± 0.20 I2/100 g) respectively. These results show that the NiO/SiO2 could be a suitable catalyst for conversion of waste vegetable oil to hydrocarbons.

Impact of health education intervention on knowledge and utilization of postnatal care services among women in Edu local Government of Kwara State, Nigeria

Background: This study examined the impact of health education intervention (HEI) on the knowledge and utilization of postnatal care services among women in Edu, Nigeria.Methods: A quasi-experimental research design using pre-test and post-test control group to examine impact of HEI among women. Researchers-developed questionnaire was used for data collection.Intervention: One hundred and twenty women were exposed to ten weeks health education intervention; sixty (n=60) experimental group exposed to postnatal care services lectures and sixty (n=60) control group were exposed to HIV/AIDS prevention lectures. The results were analyzed using descriptive and inferential statistics to answer research question and test null hypothesis at 0.05 significant levels.Results: The findings showed an improvement from pre intervention mean scores of 64.26 to post intervention scores of 98.15 for the experimental group against 68.88 post intervention mean score of control group. While, the pre intervention mean score of utilization was 56.67 compared with post intervention mean scores of 92.91 for the experimental group and 61.04 for the control group utilization This showed positive impact of health education intervention on knowledge and willingness of women of childbearing age to utilize postnatal care services in Edu LGA.Conclusion: Study concluded that, health education intervention had positive impact on knowledge and willingness of WCA to utilize postnatal care, and the knowledge gained need to be sustained to improve WCA health seeking behaviour in the communities of Edu LGA

Redox signalling to nuclear regulatory proteins by reactive oxygen species contributes to oestrogen-induced growth of breast cancer cells.

BACKGROUND: 17ß-Oestradiol (E2)-induced reactive oxygen species (ROS) have been implicated in regulating the growth of breast cancer cells. However, the underlying mechanism of this is not clear. Here we show how ROS through a novel redox signalling pathway involving nuclear respiratory factor-1 (NRF-1) and p27 contribute to E2-induced growth of MCF-7 breast cancer cells. METHODS: Chromatin immunoprecipitation, qPCR, mass spectrometry, redox western blot, colony formation, cell proliferation, ROS assay, and immunofluorescence microscopy were used to study the role of NRF-1. RESULTS: The major novel finding of this study is the demonstration of oxidative modification of phosphatases PTEN and CDC25A by E2-generated ROS along with the subsequent activation of AKT and ERK pathways that culminated in the activation of NRF-1 leading to the upregulation of cell cycle genes. 17ß-Oestradiol-induced ROS by influencing nuclear proteins p27 and Jab1 also contributed to the growth of MCF-7 cells. CONCLUSIONS: Taken together, our results present evidence in the support of E2-induced ROS-mediated AKT signalling leading to the activation of NRF-1-regulated cell cycle genes as well as the impairment of p27 activity, which is presumably necessary for the growth of MCF-7 cells. These observations are important because they provide a new paradigm by which oestrogen may contribute to the growth of breast cancer.

Isodose mapping of terrestrial gamma radiation dose rate of Selangor state, Kuala Lumpur and Putrajaya, Malaysia.

A terrestrial gamma radiation survey for the state of Selangor, Kuala Lumpur and Putrajaya was conducted to obtain baseline data for environmental radiological health practices. Based on soil type, geological background and information from airborne survey maps, 95 survey points statistically representing the study area were determined. The measured doses varied according to geological background and soil types. They ranged from 17 nGy h(-1) to 500 nGy h(-1). The mean terrestrial gamma dose rate in air above the ground was 182 ± 81 nGy h(-1). This is two times higher than the average dose rate of terrestrial gamma radiation in Malaysia which is 92 nGy h(-1) (UNSCEAR 2000). An isodose map was produced to represent exposure rate from natural sources of terrestrial gamma radiation.

Informed consent practices and its implication for emergency obstetrics care in azare, north-eastern Nigeria.

BACKGROUND: Consent practices can affect the institution of emergency obstetrics care in the health facility, and may indeed, determine the degree of maternal mortality and morbidity. OBJECTIVES: This study was aimed at determining informed consent practices and its implication for Emergency Obstetrics Care (EOC). METHODS: A cross-sectional study involving 787 women who presented with obstetric emergencies at the FMC Azare from 1(st) January 2008 to 31(st) December 2009 was done. The sociodemographic characteristics and birth outcome were compared between those that gave early consent (EC) and those that gave delayed consent (DC). Data was analysed using SPSS version 11. Morbidities and mortalities were compared in the two groups and P < 0.05 was considered statistically significant. RESULTS: EC for obstetric intervention was obtained in 260 (33.0%) of the cases, while 527 (66.0%) gave DC. The mean length of time for DC was 4.5 ± 3.5 hours (Range 1.25 to 72 hours). In 62.9% of cases the consent was given by the husband while the patient consented in 5.6%. In-laws, relatives and others were responsible for 13.8%, 8.5%, 5.7% and 3.5% respectively. Consent was significantly delayed when given by the husbands, in-laws and relatives. Patients that gave consents for their own treatment were more likely to be gainfully employed (P=0.019), educated (P=0.004) and booked (P=0.001). Maternal mortality, intrauterine fetal death, low Apgar scores and early neonatal death were significantly increased in the DC group with P values of 0.016, 0.032 and 0.026 respectively. CONCLUSION: Delay in giving Consent contributes significantly to maternal and fetal morbidity and mortality in our environment because it increases the 3(rd) level of delay.