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Chem Commun (Camb) ; (38): 4576-8, 2008 Oct 14.
Article in English | MEDLINE | ID: mdl-18815688

ABSTRACT

An organopalladium chemical dosimeter of Hg(2+) that methylates Hg(2+), undergoing a colour change in 1 : 1 ethanol-water with submicromolar sensitivity, gives rise to an aqua-palladium complex that is methylated by MeHg(+) in the presence of a dithiol compound, undergoing another colour change, thus making the system suitable for the naked-eye detection of Hg(2+) and MeHg(+), two environmentally important species of Hg(2+).


Subject(s)
Chemistry Techniques, Analytical/instrumentation , Chromogenic Compounds/chemistry , Ethanol/chemistry , Mercury/analysis , Methylmercury Compounds/analysis , Palladium/chemistry , Water/chemistry , Color , Crystallography, X-Ray , Magnetic Resonance Spectroscopy , Sensitivity and Specificity , Titrimetry
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