Rheology of a 2D granular film.

We study experimentally the rheology of a macroscopic particle-laden soap film, designated as a "Granular Film", in the simple shear configuration. Macroscopic particles are dispersed in a soap film, while being large enough that they bridge both fluid interfaces. We simultaneously perform macroscopic rheological measurements with a classical rheometer and investigate interactions at the particle scale with a camera underneath the film. The determination of the velocity field of the grains reveals the presence of an inhomogeneous shear within the granular film. Trying to correlate both measurements unveils the non-locality of the rheology of the granular film: similar to what has been observed in a dry granular material, we find an highly-sheared zone close to the moving wall contrasting with a large quasistatic area. This behavior can be accounted for through extended kinetic theory and correlated with a transition in the dominant component of the stress.

Role of particle aggregation in the structure of dried colloidal silica layers.

The process of colloidal drying gives way to particle self-assembly in numerous fields including photonics or biotechnology. Yet, the mechanisms and conditions driving the final particle arrangement in dry colloidal layers remain elusive. Here, we examine how the drying rate selects the nanostructure of thick dried layers in four different suspensions of silica nanospheres. Depending on particle size and dispersity, either an amorphous arrangement, a crystalline arrangement, or a rate-dependent amorphous-to-crystalline transition occurs at the drying surface. Amorphous arrangements are observed in the two most polydisperse suspensions while crystallinity occurs when dispersity is lower. Counter-intuitively in the latter case, a higher drying rate favors ordering of the particles. To complement these measurements and to take stock of the bulk properties of the layer, tests on the layer porosity were undertaken. For all suspensions studied herein, faster drying yields denser dry layers. Crystalline surface arrangement implies large bulk volume fraction (∼0.65) whereas amorphous arrangements can be observed in layers with either low (down to ∼0.53) or high (∼0.65) volume fraction. Lastly, we demonstrate via targeted additional experiments and SAXS measurements, that the packing structure of the layers is mainly driven by the formation of aggregates and their subsequent packing, and not by the competition between Brownian diffusion and convection. This highlights that a second dimensionless ratio in addition to the Peclet number should be taken into account, namely the aggregation over evaporation timescale.

Highly porous layers of silica nanospheres sintered by drying: scaling up of the elastic properties of the beads to the macroscopic mechanical properties.

Layers obtained by drying a colloidal dispersion of silica spheres are found to be a good benchmark to test the elastic behaviour of porous media, in the challenging case of high porosities and nano-sized microstructures. Classically used for these systems, Kendall's approach explicitly considers the effect of surface adhesive forces onto the contact area between the particles. This approach provides the Young's modulus using a single adjustable parameter (the adhesion energy) but provides no further information on the tensorial nature and possible anisotropy of elasticity. On the other hand, homogenization approaches (e.g. rule of mixtures, and Eshelby, Mori-Tanaka and self-consistent schemes), based on continuum mechanics and asymptotic analysis, provide the stiffness tensor from the knowledge of the porosity and the elastic constants of the beads. Herein, the self-consistent scheme accurately predicts both bulk and shear moduli, with no adjustable parameter, provided the porosity is less than 35%, for layers composed of particles as small as 15 nm in diameter. Conversely, Kendall's approach is found to predict the Young's modulus over the full porosity range. Moreover, the adhesion energy in Kendall's model has to be adjusted to a value of the order of the fracture energy of the particle material. This suggests that sintering during drying leads to the formation of covalent siloxane bonds between the particles.

Particle pressure in a sheared suspension: a bridge from osmosis to granular dilatancy.

The normal stress exerted by particles in a sheared suspension is measured by analogy with a method used to measure osmotic pressure in solutions. Particles in a liquid are confined by a fine screen to a gap between two vertical concentric cylinders, the inner of which rotates. Pressure in the liquid is sensed either by a manometer or by a pressure transducer across the screen. The particles are large enough so that Brownian motion and equilibrium osmotic pressure are vanishingly small. The measured pressure yields the shear-induced particle pressure Pi, the nonequilibrium continuation of equilibrium osmotic pressure. For volume fractions 0.3< or =varphi< or =0.5, Pi is strongly dependent on varphi, and linear in shear rate. Comparisons of the measured particle pressure with modeling and simulation show good agreement.

Miniaturization: Chip-based liquid chromatography and proteomics.

Proteomic research is linked with significant technological challenges such as the high dynamic range and low abundance of biologically interesting proteins. Moreover, there is an increasing need for high-throughput and robustness of routinely performed analyses. Solving these difficulties requires refinements in the capability to fractionate and prepare biological samples as well as improvements in speed, automation, separation power and overall analytical sensitivity.Recent innovations in microfluidic devices with integrated on-chip sample enrichment, liquid chromatography and electrospray emitters and their applicability for specific proteomic applications are presented in this review.:

Gravity waves at the interface between miscible fluids and at the top of a settling suspension.

Gravity waves were generated at the interface between miscible fluids, or at the top of a settling suspension or a fluidized bed. For these three systems the dispersion relation was measured and compared to the theory and calculated between two buoyant viscous fluids without surface tension. The experimental findings are found to be in good agreement with theory when effective viscosity and volume-averaged density values are used.