Improved Electrochemical Cycling Durability in a Nickel Oxide Double-Layered Film.

For the first time, a crystalline-amorphous double-layered NiOx film has been prepared by reactive radio frequency magnetron sputtering. This film has exhibited improved electrochemical cycling durability, whereas other electrochromic parameters have been maintained at the required level, namely, a short coloration/bleaching time (0.8 s/1.1 s) and an enhanced transmittance modulation range (62.2 %) at λ=550 nm. Additionally, the double-layered film has shown better reversibility than that of amorphous and crystalline single-layered films.

Hydrogen photochromism in Nb2O5 powders.

In this paper, we report on the hydrogen photochromism in Nb2O5 powders with different structures. Four different powder phases were prepared by calcining Nb2O5·nH2O powders at various temperatures, and their morphology, structure, and electronic band structure were characterized by scanning electron microscopy, structural analyses, thermogravimetric analysis, differential scanning calorimetry, and optical spectroscopy. Nb2O5 powders with different structures and very different properties were formed after different high-temperature treatments of the polymorphous oxide. A pronounced photochromic effect was observed in the M and H phases of Nb2O5, whereas the other phases exhibited poor photochromic responses. Because photochromism arises due to the detachment of hydrogen atoms under the action of light from hydrogen donor molecules previously adsorbed on the oxide surface, the electronic band structure and the morphology have strong influences on the photochromic properties of Nb2O5 powders. For these reasons, a pronounced photochromic effect was achieved in the H phase.

Photoinjection of hydrogen and the nature of a giant shift of the fundamental absorption edge in highly disordered V2O5 films.

Production of atomic photochemical hydrogen under the action of light and its subsequent injection into transition metal oxides has yielded numerous interesting results. Here we report on the mechanism of the photo-induced hydrogen transfer between adsorbed organic molecules and the surface of highly disordered V(2)O(5) films. We have managed to carry out the photoinjection of hydrogen into the V(2)O(5) films at very low temperatures, which is very important both for investigations of the reaction mechanism and for the optical properties of the V(2)O(5) films. The photochemical reaction exhibits all features of proton-coupled electron transfer which is a basic mechanism for bioenergetics conversion. Second, the new possibility to carry out experiments at very low temperatures has yielded a new approach in investigations of the nature of color centers and of the giant "blue" shift of the fundamental absorption edge in the V(2)O(5) films both arising due to injection of hydrogen atoms.