ABSTRACT
Recently, low-dimensional organic-inorganic lead halide perovskites have attracted a great deal of attention due to their outstanding tunable broadband emission, while the toxicity of lead hinders their further application in the photoelectric field. Here, we report a novel lead-free Cu(I)-based organic-inorganic perovskite-related material of a (MA)4Cu2Br6 single crystal with zero-dimensional clusters, which is a unique Cu2Br64- corner-sharing tetrahedron dimer structure consisting of two connected tetrahedra. The single crystal displays a bright broadband green emission with a high photoluminescence with a quantum yield of ≤93%, a large Stokes shift, and a very long (microsecond) photoluminescence (PL) lifetime, resulting from self-trapped exciton emission. The direct band gap characteristic of (MA)4Cu2Br6 was proven by density functional theory calculation, and its band gap was determined by experiments to be â¼3.87 eV. In the temperature range of 98-258 K, the PL intensity increases gradually with an increase in temperature due to the deep trapping out of strong electro-phonon coupling, while the PL decreases when the temperature increases over 258 K due to phonon scattering. It is worth mentioning that this new material has high chemical and light stability, in contrast to the lead perovskite.
ABSTRACT
Have one ever seen a semiconductor that can issue two-color lasing lines? The diluted magnetic semiconductor (DMS) can do this. Here, we have observed dual lasing lines of 530 nm and 789 nm from a DMS structure of CdS:NiI, in which the excitonic magnetic polaron (EMP) and localized excitonic magnetic polaron (LEMP) are excitations out of ferromagnetic (NiS) x nanocluster and NiI2 nanoclusters within CdS lattice; both of them could lead to the collective EMP state at high excitation and therein produce coherent emission lines simultaneously. This occurrence is due to the superposition of EMP near CdS bandedge and the combination of the charge-transfer band of (NiI) n cluster with the LEMP within CdS lattice by overcoming the strong electron correlation of NiI cluster in a DMS structure, evidenced also by ab initio calculation. This finding opens a way to understand the collective behaviour of spin-coupled excitons in DMS and to find novel applications in the spin-related quantum technology.
