ABSTRACT
Here, the comparison of two different semiconductor materials is demonstrated, TiO2 and melem/g-C3N4 composites-modified with balls of approximately 5 nm Ag nanoparticles (NPs) as photocatalysts for the degradation of the model dye acid orange 7 (AO7). The melem molecule synthesized here is one of a series of organic compounds consisting of triazine ring compounds with a structure similar to that of melam and melamine. The photodegradation process of AO7 was carried out to examine all powder materials as a potential photocatalyst. Additionally, two different lamps of wavelengths 368 nm (UV light) and 420 nm (VIS light) were applied to compare the photodegradation tests. A new synthesis route for the acquisition of Ag NPs (Ag content 0.5, 1.0 and 2.5 wt%), based on a wet and low temperature method without the use of reducing reagents was proposed. The best photocatalytic performances under UV and VIS light were obtained for both, TiO2 and melem/g-C3N4 materials (new synthesis route) modified with a very low Ag content-0.5 wt%. The photodegradation activities using UV lamp (3 h, 368 nm irradiation) for samples with 0.5 wt% of Ag: TiO2 and melem/g-C3N4, in excess of 95 and 94%, respectively, were achieved. The highest photoactive materials melem/g-C3N4 with 0.5 and 1 wt% Ag revealed 98% of activity under the VIS lamp after 3 h long irradiation. Our work demonstrates a novel, environmentally acceptable, and cost-effective chemical strategy for preparation of photocatalysts suitable for degradation of organic contaminants in wastewater treatment.
ABSTRACT
Sensing abilities of a one-dimensional photonic crystal (1DPhC) represented by a multilayer dielectric structure are analyzed theoretically and experimentally, using a new wavelength interrogation interference method. The structure comprising a glass substrate and six bilayers of TiO2/SiO2 with a termination layer of TiO2 is employed in both gas sensing based on the Bloch surface wave (BSW) resonance and liquid analyte sensing based on a self-referenced guide-mode resonance (GMR). We model the spectral interference reflectance responses in the Kretschmann configuration with a coupling prism made of BK7 glass and show that a sharp dip with maximum depth associated with the BSW excitation is red-shifted as the refractive index (RI) changes in a range of 1-1.005. Thus, a sensitivity of 1456 nm per RI unit (RIU) and figure of merit (FOM) of 91 RIU-1 are reached. Similarly, we model the responses for aqueous solutions of ethanol to show that dips of maximum depth are associated with the GMRs, and the highest sensitivity and FOM reached are 751 nm/RIU and 25 RIU-1, respectively. Moreover, we show that one of the dips is with the smallest shift as the RI changes, and hence it can be used as a reference. The theoretical results are confirmed by the experimental ones when the BSW resonance is used in sensing of humid air with a sensitivity of 0.027 nm/%relative humidity (RH) and FOM of 1.4×10-3 %RH-1. Similarly, the GMR is used in sensing of aqueous solutions of ethanol, and the highest sensitivity and FOM reached 682 nm/RIU and 23 RIU-1, respectively. The reference dip is also resolved and this self-reference makes the measurement more accurate and repeatable, and less sensitive to optomechanical drifts.
