ABSTRACT
Correction for 'Tailoring of optical properties of fluorescein using green synthesized gold nanoparticles' by Jisha John et al., Phys. Chem. Chem. Phys., 2015, 17, 15813-15821.
ABSTRACT
This is a comment on the previously published paper "Enhancement of nonlinear optical properties of BaTiO3 nanoparticles by the addition of silver seeds," [Opt. Express20, 26511 (2012)10.1364/OE.20.026511]. An erroneous equation given in the manuscript is corrected with a more accurate equation in this comment.
ABSTRACT
Dye-nanoparticle mixtures hold great promise in biological as well as photonics applications due to their capability to tailor the emission behavior of dye by tuning the nanoparticles parameters. However, as compared to the well-defined dye-nanoparticle distance, studies lack the understanding of homogenous mixtures of dye and nanoparticles. In this work, we investigate the influence of shape and concentration of gold nanoparticles prepared via green synthesis on the optical properties of fluorescein dye in a dye-nanoparticle mixture. We have investigated the radiative path of deexcitation using steady state fluorescence and the non-radiative path is probed using a laser based dual-beam thermal lens technique. The energy transfer efficiency as well as dye-nanoparticle distance is studied using both techniques. Furthermore, we have explored the influence of nanoparticles parameters on the fluorescence quantum yield of fluorescein using the thermal lens technique. The studies indicate that spherical nanoparticles are efficient quenchers while star shaped nanoparticles can probe larger dye-NP distances. The tailoring of dye properties by tuning nanoparticle parameters can be utilized in diverse areas including bioimaging, solar cells, and sensors.
Subject(s)
Fluorescein/chemistry , Fluorescence , Fluorescent Dyes/chemistry , Gold/chemistry , Metal Nanoparticles/chemistry , Particle Size , Surface PropertiesABSTRACT
We report novel direct quantitative comparisons between 3D profiling measurements and simulations of human vocal fold vibrations. Until now, in human vocal folds research, only imaging in a horizontal plane was possible. However, for the investigation of several diseases, depth information is needed, especially when the two folds act differently, e.g. in the case of tumour growth. Recently, with our novel depth-kymographic laryngoscope, we obtained calibrated data about the horizontal and vertical positions of the visible surface of the vibrating vocal folds. In order to find relations with physical parameters such as elasticity and damping constants, we numerically simulated the horizontal and vertical positions and movements of the human vocal folds while vibrating and investigated the effect of varying several parameters on the characteristics of the phonation: the masses and their dimensions, the respective forces and pressures, and the details of the vocal tract compartments. Direct one-to-one comparison with measured 3D positions presents-for the first time-a direct means of validation of these calculations. This may start a new field in vocal folds research.
Subject(s)
Kymography/methods , Models, Biological , Speech Production Measurement/methods , Vocal Cords/physiology , Aged , Computer Simulation , Humans , Male , Movement/physiology , VibrationABSTRACT
We designed and developed a laser line-triangulation endoscope compatible with any standard high-speed camera for a complete three-dimensional profiling of human vocal fold vibration dynamics. With this novel device we are able to measure absolute values of vertical and horizontal vibration amplitudes, length and width of vocal folds as well as the opening and closing velocities from a single in vivo measurement. We have studied, for the first time, the generation and propagation of mucosal waves by locating the position of its maximum vertical position and the propagation velocity. Precise knowledge about the absolute dimensions of human vocal folds and their vibration parameters has significant importance in clinical diagnosis and treatment as well as in fundamental research in voice. The new device can be used to investigate different kinds of pathological conditions including periodic or aperiodic vibrations. Consequently, the new device has significant importance in investigating vocal fold paralysis and in phonosurgical applications.
Subject(s)
Imaging, Three-Dimensional/methods , Kymography/methods , Vibration , Vocal Cords/physiology , Calibration , Humans , Lasers , Time FactorsABSTRACT
We report the design of a novel laser line-triangulation laryngoscope for the quantitative visualization of the three-dimensional movements of human vocal folds during phonation. This is the first successful in vivo recording of the three-dimensional movements of human vocal folds in absolute values. Triangulation images of the vocal folds are recorded at the rate of 4000 fps with a resolution of 256x256 pixels. A special image-processing algorithm is developed to precisely follow the subpixel movements of the laser line image. Vibration profiles in both horizontal and vertical directions are calibrated and measured in absolute SI units with a resolution of +/-50 microm. We also present a movie showing the vocal folds dynamics in vertical cross section.
Subject(s)
Image Enhancement/instrumentation , Image Interpretation, Computer-Assisted/instrumentation , Laryngoscopes , Phonation/physiology , Video Recording/instrumentation , Vocal Cords/anatomy & histology , Vocal Cords/physiology , Computer-Aided Design , Equipment Design , Equipment Failure Analysis , Humans , Image Interpretation, Computer-Assisted/methods , Reproducibility of Results , Sensitivity and Specificity , Speech Production Measurement/instrumentation , Speech Production Measurement/methodsABSTRACT
Photothermal beam deflection studies were carried out with GaAs epitaxial double layers grown on semi-insulating GaAs substrates. The impurity densities in thin epitaxial layers were found to influence the effective thermal diffusivity of the entire structure.