Heavy metal and persistent organic pollutant profile of sediments from marine protected areas: the northern Persian Gulf.

Marine protected areas (MPAs) are one of the policy tools to support marine biodiversity conservation and sustainable use of marine resources. The distribution, sources, and ecological risk assessment of persistent organic pollutants (POPs), including polycyclic aromatic hydrocarbon (PAHs), total petroleum hydrocarbons (TPHs), polychlorinated biphenyls (PCBs), and heavy metals (HMs) in sediments of MPAs in the northern Persian Gulf, were evaluated for the first time in this study. The Σ16PAHs ranged from 4.65 to 20.86 µg/kg dry weight (dw). The molecular ratios and ring's pattern of PAHs suggested a mixed origin with a predominance of pyrogenic sources. The TPH concentration varied from 5.21 to 17.90 µg/g dw. Ecological risk assessment suggested that sediment samples in Bushehr Province's MPAs can be categorized as medium risk. The mean concentration of ∑18PCB was 0.345-0.419 ng/g dw, and the main components correspond to PCB-77, PCB-105, PCB-81, PCB-101, and PCB-114. The mean concentration of As, Co, Cr, Ni, V, Mg, Pb, Zn, Cu, Al, and Fe varied from 4.79 to 9.69, 2-12, 39-142, 18-90, 15-58, 184-425, 7-45.9, 6-42.4, 4-20 µg/g dw, 0.75-4.12%, and 0.35-1.62%, respectively. Multivariate analysis, such as principal component analysis (PCA) and cluster analysis (CA), coupled with correlation coefficient analysis, was used to analyze the analytical data and to identify possible pollution sources. The results of this study provided the background information on the extent of POP contamination in the sediment and highlighted the need to further control pollution in MPAs.

Secondhand and thirdhand smoke: a review on chemical contents, exposure routes, and protective strategies.

Secondhand smoke (SHS: a mixture of sidestream and mainstream smoke) and thirdhand smoke (THS: made up of the pollutants that settle indoors after smoking in closed environments) are a significant public health concern. SHS and THS contain various chemicals which can be released into the air or settle on surfaces. At present, the hazards of SHS and THS are not as well documented. In this review, we describe the chemical contents of THS and SHS, exposure routes, vulnerable groups, health effects, and protective strategies. The literature search was conducted for published papers on September 2022 in Scopus, Web of Science, PubMed, and Google Scholar databases. This review could provide a comprehensive understanding of the chemical contents of THS and SHS, exposure routes, vulnerable groups, health effects, protective strategies, and future researches on environmental tobacco smoke.

Hypoxia in the Persian Gulf and the Strait of Hormuz.

In this article dissolved oxygen results of research cruises through the Persian Gulf during 2018-2019 are discussed. The results showed that summer to autumn hypoxia occurred mainly at depths ≥ 50 m to the bottom. This seasonal hypoxia started in late summer reaching its greatest severity in mid-autumn with an area of 50,000 km2 in the Persian Gulf. The minimum oxygen measured at the near-bottom layer of the western basin in autumn (25.8 µmol/kg) was lower than any previous measurement in the open waters of the Persian Gulf. In the Strait of Hormuz, the seasonal hypoxia appeared in summer in the near bottom of the most eastern part at the Iranian side. pHT values recorded in hypoxic waters were as low as what is predicted for surface ocean under ocean acidification in 2100. Considering the results, we suggest evaluating the effects of hypoxia and acidification on the Persian Gulf ecosystems.

Investigating the parameters affecting the adsorption of amino acids onto AgCl nanoparticles with different surface charges.

In this paper, adsorption behaviors of typical neutral (alanine), acidic (glutamic acid) and basic (lysine) amino acids onto the surfaces of neutral as well as positively and negatively charged silver chloride nanoparticles were examined. Silver chloride nanoparticles with different charges and different water content were synthesized by reverse micelle method. The adsorptions of the above mentioned amino acids onto the surfaces of differently charged silver chloride nanoparticles were found to depend strongly on various parameters including pH of the aqueous solution, type of amino acid, water to surfactant mole ratio, and type of charges on the surfaces of silver chloride nanoparticles. It was found that the interaction of -NH(3) (+) groups of the amino acids with silver ion could be a driving force for adsorption of amino acids. Alanine and Glutamic acid showed almost similar trend for being adsorbed on the surface of silver chloride nanoparticles. Electrostatic interaction, hydrophobicity of both nanoparticle and amino acid, complex formation between amine group and silver ion, interaction between protonated amine and silver ion as well as the number of nanoparticles per unit volume of solution were considered for interpreting the observed results.