Effect of ZnO surface morphology on its electrochemical performance.

The purpose of this paper is to bridge the gap between ZnO surface morphology and its electrochemical performance. For this reason, ZnO nanowires (NWs) of different length were synthesized using an electrochemical method. Then, the electrochemical performance of the synthesized ZnO surfaces was studied using cyclic voltammetry and electrochemical impedance spectroscopy. The electrochemical analysis results revealed that the increase of ZnO NW length contributes to the retrogression of electrochemical performance. Indeed, the electrochemical performance is mainly related to the wettability behavior of the ZnO nanowire surfaces. When the ZnO NWs length increases, the surface become more hydrophobic, therefore, charge transfers between the electrode/electrolyte decrease. To improve the electrochemical performance of ZnO, we propose a new strategy combining NWs and microsheets (µSs) for further improving the morphology. Finally, the surfaces based on the double structure of ZnO provide good propagation of charge at the surface, good transfer in the electrode, good stability, and excellent scanning ability. In the present work we intend to pave the way for achieving high electrochemical performance ZnO-based layers.

Wettability of zinc oxide nanorod surfaces.

In this work, we have studied the wettability of zinc oxide (ZnO) nanorods grown on fluorine-doped tin oxide (FTO) by highlighting the effect of polar and non-polar ZnO facets on contact angle (CA) results. The variation in the wettability behaviors of the synthesized surfaces is mainly related to physical and chemical surface texturing which influenced the liquid drop penetration. Indeed, three main penetration states can be deduced: total, partial, and null-penetration. Where, low CA (100.9°) with high contact angle hysteresis (CAH) (13°) is observed for total penetration of the liquid drop. While, high CA (139.6°) with low CAH (7°) is observed for null-penetration. Moreover, we have found that the chemical texturing of ZnO, especially the hydrophilicity of ZnO tips, responsible for liquid drop sticking, prevents the liquid slipping over the surface. In order to promote the liquid rolling on the ZnO surface, we reported the physical modification of the ZnO structures. Therefore, the rolling of the liquid drop on the inclined surface of ZnO is achieved by using a new structure based on double scale roughness. This surface exhibits superhydrophobic behavior with a CA of 153° and CAH of 3°.