1.
Dalton Trans
; 53(26): 10814-10818, 2024 Jul 02.
Article
in English
| MEDLINE
| ID: mdl-38859708
ABSTRACT
In this work, the insertion of CS2 into the Ge-Si bond of PhC(NtBu)2Ge-Si(SiMe3)3 (1) has been investigated, resulting in the formation of PhC(NtBu)2Ge-C(îS)-S-Si(SiMe3)3 (2). Interestingly, the addition of NHC to 2 allows the release of NHC·CS2 with concomitant regeneration of 1. Addition of another equivalent of 1 or an analogous hypersilyl silylene, [PhC(NtBu)2Si-Si(SiMe3)3], to 2 led to the formation of compounds with a GeîS (3) or a SiîS (4) bond.