A facile strategy to prepare ZSM-5-based composites with enhanced light olefin selectivity and stability in the HTO process.

In this study, the influence of different ZSM-5 composite materials (ASA, γ-alumina, η-Al2O3, SiO2, and attapulgite) and their performance in the n-hexane catalytic cracking process in a fixed bed microreactor at 550 °C under atmospheric pressure was studied. XRD, FT-IR spectroscopy, NH3-TPD, BET, FE-SEM, and TG analyses were performed to characterize the catalysts. The result of the n-hexane to olefin process indicated that the A2 catalyst (γ-alumina composition with ZSM-5) showed the highest conversion of 98.89%, highest propylene selectivity of 68.92%, highest yield of light olefins of 83.84%, and highest propylene to ethylene ratio of 4.34. The reason for the significant increase in all these factors and the lowest amount of coke in this catalyst is the use of γ-alumina, which increased the hydrothermal stability and resistance to deactivation, improved the acidic properties with a strong to weak acid ratio of 0.382, and increased the mesoporosity to 0.242. This study indicates the effect of the extrusion process and the composition and the major effect of the properties of this material on the physicochemical properties and distribution of the product.

Dietary intake of carotenoids and fiber is inversely associated with aggression score in adolescent girls.

BACKGROUND: Violence and aggression are considered to be important public health issues. There is limited data on the association between dietary intake and aggression score. AIM: We aimed to examine the relationship between the dietary intake and aggressive behavior in Iranian adolescent girls. METHODS: The study was carried out among 670 girls aged 12-18 years. A valid and reliable food frequency questionnaire (FFQ) containing 147 food items was used to estimate dietary intake of the study participants. Aggression score was determined using a validated Persian version of the Buss-Perry questionnaire. We analyzed our data using crude and adjusted models. RESULTS: Participants in the fourth quartile of aggression score had significantly higher energy intake compared with those in the first quartile (2808±949 vs 2629±819, p-trend = 0.01). Dietary intakes of soluble fiber (0.42±0.37 vs 0.35±0.29, p = 0.03) and insoluble fiber (2.17±1.65 vs 1.82±1.36, p = 0.02) were significantly higher in the first quartile than in the fourth quartile. In addition, the strongest negative correlations were found between aggression score and dietary soluble fiber (p = 0.003) and insoluble fiber intake (p = 0.001). Moreover, aggression score was negatively correlated with dietary α-carotene (p = 0.02) and ß-carotene (p = 0.04) intake. These associations remained significant even after adjustment for potential confounders. CONCLUSIONS: Our results indicated that dietary intakes of fiber, α-carotene, and ß-carotene were inversely associated with aggression score. Moreover, a significant positive association was observed between energy intake and aggression score in adolescent girls.

The Effects of Curcumin and Curcumin-Phospholipid Complex on the Serum Pro-oxidant-Antioxidant Balance in Subjects with Metabolic Syndrome.

Metabolic syndrome (MetS) is defined by a clustering of metabolic and anthropometric abnormalities and is associated by an increased risk of cardiovascular disease. We have investigated the effect of curcumin supplementation on the serum pro-oxidant-antioxidant balance (PAB) in patients with MetS. This double-blind, randomized, placebo-controlled trial was conducted over 6 weeks. Subjects (n = 120) were randomly allocated to one of three groups (curcumin, phospholipidated curcumin, and placebo). The curcumin group received 1 g/day of simple curcumin, the phospholipidated curcumin group received 1 g/day of phospholipidated curcumin (containing 200 mg of pure curcumin), and the control group received 1 g/day of placebo. Serum PAB was measured before and after the intervention (at baseline and at 6 weeks). Data analyses were performed using spss software (version 16.0). Serum PAB increased significantly in the curcumin group (p < 0.001), but in the phospholipidated curcumin group, elevation of PAB level was not significant (p = 0.053). The results of our study did not suggest any improvement of PAB following supplementation with curcumin in MetS subjects. Copyright © 2017 John Wiley & Sons, Ltd.