Synthesize optimization, characterization, and application of ZIF-8 adsorbent for elimination of olive oil from aqueous solution.

In view of the importance of water quality and environmental aspect, zeolitic imidazolate framework-8 (ZIF-8) adsorbent was synthesized via a solvothermal approach for oil removal from water. Response surface methodology-central composite design approach (RSM-CCD) using a statistical software (Design expert, version 8.0.6) was employed to identify the influence of three independent variables of ZIF-8 synthesis procedure including ligand/salt molar ratio, solvent/salt molar ratio, and synthesis temperature on the oil adsorption capacity and yield of adsorbent as RSM responses. The optimum conditions for preparing ZIF-8 were found as follows: ligand/salt molar ratio of 10.4, solvent/salt ratio of 702.7, and temperature of 52.9 °C, which resulted in 1120 mg/g of olive oil uptake and 43% of ZIF-8 yield. Morphological and structural properties of the prepared adsorbent were characterized by N2 adsorption-desorption, XRD, FE-SEM, and FTIR analyses. Batch equilibrium adsorption experiments were conducted under varied system parameters expected to affect the ZIF-8 adsorption capacity including oil concentration, ZIF-8 dosage, contact time, and temperature. The isotherm and kinetic of olive oil adsorption onto ZIF-8 followed the Freundlich and pseudo-first-order models, respectively. The evaluation of thermodynamic parameters demonstrated that olive oil adsorption onto optimized ZIF-8 was spontaneous and exothermic in nature. In addition, the used ZIF-8 can be recovered effectively using a simple ethanol-washing method. Based on experimental results, the ZIF-8 prepared in this study can be successfully used in oil/water emulsion separation.

Electricity generation through degradation of organic matters in medicinal herbs wastewater using bio-electro-Fenton system.

In the present study, the potential application of the bio-electro-Fenton (BEF) process for the treatment of medicinal herbs wastewater in a mediator-less microbial fuel cell (MFC) system is investigated. This process is operated in a dual-chamber MFC with anaerobic seed sludge as biocatalyst in an anode chamber under conditions of neutral pH, an aerobic cathode chamber equipped with a Fe@Fe2O3/graphite composite cathode and a Nafion membrane as a separator. The performance of the MFC is determined in three different mixed liquor suspended solids (MLSS) loadings, Nafions (112, 115) and a salt bridge in an air-cathode BEF process, in terms of power generation, chemical oxygen demand (COD) removal efficiency, columbic and energy efficiencies. Under optimal conditions, the batch experiment results show that the cathode chamber of the BEF reactor, equipped with Nafion 112 and inoculated with seed sludge at 3000 mg L(-1) MLSS concentration, produces the maximum power density of 49.76 mW m(-2), 0.56 mg L(-1) and 29 mol L(-1) of H2O2 and Fe(2+), respectively. Under these conditions, the MFC achieves COD removal 78.05% in the anaerobic anode chamber and 84.02% as a result of aerobic processes from the air-cathode BEF chamber, whilst the maximum voltage εcb and εE values are 600 mV, 4.09% and 1.37%, respectively.

Thionine increases electricity generation from microbial fuel cell using Saccharomyces cerevisiae and exoelectrogenic mixed culture.

Microbial fuel cells (MFCs) have been shown to be capable of clean energy production through the oxidation of biodegradable organic waste using various bacterial species as biocatalysts. In this study we found Saccharomyces cerevisiae, previously known electrochemcially inactive or less active species, can be acclimated with an electron mediator thionine for electrogenic biofilm formation in MFC, and electricity production is improved with facilitation of electron transfer. Power generation of MFC was also significantly increased by thionine with both aerated and non-aerated cathode. With electrochemically active biofilm enriched with swine wastewater, MFC power increased more significantly by addition of thionine. The optimum mediator concentration was 500 mM of thionine with S. cerevisae in MFC with the maximum voltage and current generation in the microbial fuel cell were 420 mV and 700 mA/m(2), respectively. Cyclic voltametry shows that thionine improves oxidizing and reducing capability in both pure culture and acclimated biofilm as compared to non-mediated cell. The results obtained indicated that thionine has great potential to enhance power generation from unmediated yeast or electrochemically active biofilm in MFC.