ABSTRACT
This research paper is the result of observations made during tests according to various standards carried out on behalf of industry. The article presents diffusion coefficient values calculated according to the thermodynamic migration model for twenty different concrete mixes and some selected mixes of the codified approaches known as ASTM 1202, NT BUILD 443, NT BUILD 492, ASTM 1556. The method used here, according to the thermodynamic model of migration, allows determination of the value of the diffusion coefficient after short studies of the migration of chloride ions into concrete and was described in earlier works by one of the authors. Unfortunately, when using standard methods, the values of diffusion coefficients differ significantly from each other. In each concrete, diffusion tests were carried out in the conditions of long-term natural diffusion to verify the values determined by standard methods and according to the thermodynamic model of migration. The analysis conducted for this research paper reveals that the chloride permeability test method according to the standard ASTM C1202-97 has an almost 2.8-fold greater dispersion of the obtained results compared to the thermodynamic model of migration. It was observed that the standard NT BUILD 492 has a 3.8-fold dispersion of results compared to the method with the thermodynamic model of migration. The most time-consuming method is the standard method NT BUILD 443. The largest 3.5-fold dispersion of values concerning the reference value are observed in that method. Moreover, a method based on a thermodynamic migration model seems to be the best option of all analyzed methods. It is a quite quick, but laborious, method that should be tested for a larger number of concrete mixes. A great advantage of this method is that it is promising for a wide range of concrete mixtures, both plain concrete and concrete with various additives and admixtures, as well as high-performance concrete.
ABSTRACT
This study investigated the variation of bulk resistivity (BR) and charge passed for various high-performance concrete (HPC) mixtures based on significant factors (i.e., geometric size, operation frequency, and mixture constituents and proportions) using three testing instruments. These instruments were a surface resistivity (SR) meter and two bulk conductivity meters: one for using the BR data at a constant frequency, and the other at a wide range of frequencies. These HPC mixtures were categorized into several groups based on various supplementary cementitious materials (SCMs). The variation and distribution of BR and the charge passed were investigated and statistical analysis results showed that the addition of SCMs and their varying replacement level remarkably influenced the reduction of charge passed in each group over an extended period. The results revealed that, for fly ash-based ternary mixtures, the addition of 3% metakaolin or 12% silica fume resulted in the highest reduction of charge passed over time (82% and 90%, respectively). For cost purposes, 5% silica fume replacement in ternary mixtures was chosen as an optimal solution. Finally, this study offered promising options for charge passed computation to assess corrosion in light of simple, rapid, and reliable SR/BR measurement.
ABSTRACT
The numerical modelling of chloride penetration into concrete is very sensitive to the correct description of the input data. In the recent era, high-performance concrete (HPC), which combines Portland cement and other supplementary cementitious materials, has been gaining attraction due to their desirable material properties and durability. The presented results show the application of the modified approach for the evaluation of the suitability of the time-dependent model for the variation of the diffusion coefficient. The 26 various binary and ternary-based concrete mixtures blended with volcanic pumice pozzolan (VPP) as a major supplementary cementitious material (SCM) are compared with the reference Ordinary Portland Cement mixture. Other SCMs namely fly ash, slag, silica fume, and metakaolin were also utilized in ternary-based concrete mixtures. In-depth statistical analysis was carried out to show the variability and effects of the amount of the volcanic pumice as an SCM on the diffusion coefficient. The mean value and regression via linear approximation of the time-dependent coefficient of variation of the diffusion coefficients were used as well as the Root of Mean Squared Error approach. The presented results are suitable as the component of the input parameters for the durability-related probabilistic assessment of the reinforced concrete structures exposed to chlorides. In addition, the time-dependent ultimate limit state-related data was presented.
