1.
Org Biomol Chem
; 17(15): 3805-3811, 2019 04 10.
Article
in English
| MEDLINE
| ID: mdl-30916709
ABSTRACT
Gold(i) catalysed regio- and stereoselective intermolecular hydroamination of internal alkynes was developed for the effective synthesis of a series of (Z)-functionalised vinylazoles under solvent free conditions. The catalytic hydrogenation of the resulting enamines leads to substituted saturated azoles in good yields.