Dilute gel networks vs. clumpy gels in colloidal systems with a competition between repulsive and attractive interactions.

Using Brownian dynamics simulations we study gel-forming colloidal systems. The focus of this article lies on the differences of dense and dilute gel networks in terms of structure formation both on a local and a global level. We apply reduction algorithms and observe that dilute networks and dense gels differ in the way structural properties like the thickness of strands emerge. We also analyze the percolation behavior and find that two different regimes of percolation exist which might be responsible for structural differences. In dilute networks we confirm that solidity is mainly a consequence of pentagonal bipyramids forming in the network. In dense gels, tetrahedral structures also influence solidity.

Structural and dynamical properties of dilute gel networks in colloid-polymer mixtures.

The competition of short-ranged depletion attraction and long-ranged repulsion between colloidal particles in colloid-polymer mixtures leads to the formation of heterogeneous gel-like structures. Our special focus will be on the states where the colloids arrange in thin strands that span the whole system and that we will refer to as dilute gel networks. These states occur at low packing fractions for attractions that are stronger than those at both the binodal line of the equilibrium gas-liquid phase separation and the directed percolation transition line. By using Brownian dynamics simulations, we explore the formation, structure, and aging dynamics of dilute gel networks. The essential connections in a dilute gel network are determined by constructing reduced networks. We compare the observed properties to those of clumpy gels or cluster fluids. Our results demonstrate that both the structure and the (often slow) dynamics of the stable or meta-stable heterogeneous states in colloid-polymer mixtures possess distinct features on various length and time scales and thus are richly diverse.