ABSTRACT
OBJECTIVE: To assess the usefulness of scanning electron microscopy and energy dispersive x-ray spectroscopy in matching bullet wipe to the bullet. HYPOTHESIS: Bullet wipe can be used to match a bullet type to a crime scene.
Subject(s)
Forensic Ballistics/methods , Humans , Microscopy, Electron, Scanning , Observer Variation , Paper , Random Allocation , Spectrometry, X-Ray EmissionABSTRACT
OBJECTIVE: The aim of this study was to investigate the use of field emission scanning electron microscopy and electron dispersive spectrography (SEM-EDS) to identify silver solder "tattoo." STUDY DESIGN: SEM-EDS was used to analyze material present in the connective tissue of a patient who presented with bilateral pigmentation of the mandibular lingual gingiva adjacent to the first molars. No dental restorations were present. RESULTS: SEM-EDS analysis identified silver, with no evidence of tin, copper, or mercury. The patient was wearing an orthodontic appliance where brackets had been soldered to the archwire with silver solder. It is hypothesed that the solder underwent electrolytic corrosion with subsequent regrouping of silver ions in the submucosa leading to blue-gray discoloration. CONCLUSION: Spectrography proved to be a powerful diagnostic tool in identifying the metal within the oral mucosa. Attention is drawn to this newly described lesion, which should be included as a differential diagnosis for pigmented oral mucosal lesions.
Subject(s)
Dental Soldering , Mouth Diseases/chemically induced , Mouth Mucosa/drug effects , Pigmentation Disorders/chemically induced , Silver/adverse effects , Tattooing , Adolescent , Corrosion , Electrolysis , Electron Probe Microanalysis , Female , Humans , Microscopy, Electron, Scanning , Mouth Diseases/pathology , Mouth Mucosa/ultrastructure , Orthodontic Brackets , Orthodontic Wires , Pigmentation Disorders/pathologyABSTRACT
OBJECTIVES: To identify any potentially toxic elements in porcelain-fused-to-metal (PFM) crowns and a bridge manufactured in China. MATERIALS AND METHODS: Eight PFM crowns and part of a bridge were sourced from China for testing. They were given a typical glaze firing cycle prior to scanning electron microscope analysis. Electron dispersive spectroscopic spot and mapping analysis was carried out on the porcelain/metal collar interface areas in order to determine their elemental composition and distribution. RESULTS: No toxic elements were detected. The alloy used in the crowns was a nickel-chromium base metal, and that in the bridge was a gold-palladium noble alloy. The veneering porcelain was similar to a standard dental veneering porcelain. CONCLUSIONS: Within the limitations of the testing method and small sample size, no toxic elements were detected.
