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1.
Opt Express ; 26(10): A413-A419, 2018 May 14.
Article in English | MEDLINE | ID: mdl-29801262

ABSTRACT

A stationary catadioptric concentrating photovoltaic module with aperture area over 100 cm2, geometric concentration of 180×, and collection within 60° of polar incidence was designed, prototyped, and characterized. The module performance followed modeling closely with a peak power conversion efficiency of 26% for direct irradiance. Tracking of the sun is accomplished via translational micro-tracking completely internal to the module, avoiding the cost and complexity of mechanical two-axis trackers that point towards the sun. This demonstrates the potential for concentrating photovoltaic modules with significantly higher efficiency than industry standard silicon photovoltaic modules that could be installed in stationary configurations on rooftops.

2.
Adv Mater ; 27(40): 6131-6, 2015 Oct 28.
Article in English | MEDLINE | ID: mdl-26332896

ABSTRACT

Photoelectrochemical etching of silicon can be used to form lateral refractive index gradients for transformation optical devices. This technique allows the fabrication of macroscale devices with large refractive index gradients. Patterned porous layers can also be lifted from the substrate and transferred to other materials, creating more possibilities for novel devices.

3.
Phys Chem Chem Phys ; 15(2): 440-3, 2013 Jan 14.
Article in English | MEDLINE | ID: mdl-23183772

ABSTRACT

Nanoporous silicon (Si) networks with controllable porosity and thickness are fabricated by a simple and scalable electrochemical process, and then released from Si wafers and transferred to flexible and conductive substrates. These nanoporous Si networks serve as high performance Li-ion battery electrodes, with an initial discharge capacity of 2570 mA h g(-1), above 1000 mA h g(-1) after 200 cycles without any electrolyte additives.

4.
Nano Lett ; 11(7): 2825-8, 2011 Jul 13.
Article in English | MEDLINE | ID: mdl-21619019

ABSTRACT

We report an invisibility carpet cloak device, which is capable of making an object undetectable by visible light. The cloak is designed using quasi conformal mapping and is fabricated in a silicon nitride waveguide on a specially developed nanoporous silicon oxide substrate with a very low refractive index (n<1.25). The spatial index variation is realized by etching holes of various sizes in the nitride layer at deep subwavelength scale creating a local effective medium index. The fabricated device demonstrates wideband invisibility throughout the visible spectrum with low loss. This silicon nitride on low index substrate can also be a general scheme for implementation of transformation optical devices at visible frequencies.


Subject(s)
Light , Optical Devices , Equipment Design , Nanotechnology , Particle Size , Porosity , Silicon Compounds/chemistry , Silicon Dioxide/chemistry , Surface Properties
5.
Nature ; 469(7330): 385-8, 2011 Jan 20.
Article in English | MEDLINE | ID: mdl-21248848

ABSTRACT

When light illuminates a rough metallic surface, hotspots can appear, where the light is concentrated on the nanometre scale, producing an intense electromagnetic field. This phenomenon, called the surface enhancement effect, has a broad range of potential applications, such as the detection of weak chemical signals. Hotspots are believed to be associated with localized electromagnetic modes, caused by the randomness of the surface texture. Probing the electromagnetic field of the hotspots would offer much insight towards uncovering the mechanism generating the enhancement; however, it requires a spatial resolution of 1-2 nm, which has been a long-standing challenge in optics. The resolution of an optical microscope is limited to about half the wavelength of the incident light, approximately 200-300 nm. Although current state-of-the-art techniques, including near-field scanning optical microscopy, electron energy-loss spectroscopy, cathode luminescence imaging and two-photon photoemission imaging have subwavelength resolution, they either introduce a non-negligible amount of perturbation, complicating interpretation of the data, or operate only in a vacuum. As a result, after more than 30 years since the discovery of the surface enhancement effect, how the local field is distributed remains unknown. Here we present a technique that uses Brownian motion of single molecules to probe the local field. It enables two-dimensional imaging of the fluorescence enhancement profile of single hotspots on the surfaces of aluminium thin films and silver nanoparticle clusters, with accuracy down to 1.2 nm. Strong fluorescence enhancements, up to 54 and 136 times respectively, are observed in those two systems. This strong enhancement indicates that the local field, which decays exponentially from the peak of a hotspot, dominates the fluorescence enhancement profile.


Subject(s)
Electromagnetic Fields , Hot Temperature , Luminescent Measurements/methods , Metal Nanoparticles/chemistry , Microscopy, Fluorescence/methods , Molecular Imaging/methods , Aluminum/chemistry , Fluorescence , Fluorescent Dyes/analysis , Fluorescent Dyes/chemistry , Motion , Quartz , Silver/chemistry , Surface Properties
6.
Nature ; 461(7264): 629-32, 2009 Oct 01.
Article in English | MEDLINE | ID: mdl-19718019

ABSTRACT

Laser science has been successful in producing increasingly high-powered, faster and smaller coherent light sources. Examples of recent advances are microscopic lasers that can reach the diffraction limit, based on photonic crystals, metal-clad cavities and nanowires. However, such lasers are restricted, both in optical mode size and physical device dimension, to being larger than half the wavelength of the optical field, and it remains a key fundamental challenge to realize ultracompact lasers that can directly generate coherent optical fields at the nanometre scale, far beyond the diffraction limit. A way of addressing this issue is to make use of surface plasmons, which are capable of tightly localizing light, but so far ohmic losses at optical frequencies have inhibited the realization of truly nanometre-scale lasers based on such approaches. A recent theoretical work predicted that such losses could be significantly reduced while maintaining ultrasmall modes in a hybrid plasmonic waveguide. Here we report the experimental demonstration of nanometre-scale plasmonic lasers, generating optical modes a hundred times smaller than the diffraction limit. We realize such lasers using a hybrid plasmonic waveguide consisting of a high-gain cadmium sulphide semiconductor nanowire, separated from a silver surface by a 5-nm-thick insulating gap. Direct measurements of the emission lifetime reveal a broad-band enhancement of the nanowire's exciton spontaneous emission rate by up to six times owing to the strong mode confinement and the signature of apparently threshold-less lasing. Because plasmonic modes have no cutoff, we are able to demonstrate downscaling of the lateral dimensions of both the device and the optical mode. Plasmonic lasers thus offer the possibility of exploring extreme interactions between light and matter, opening up new avenues in the fields of active photonic circuits, bio-sensing and quantum information technology.

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