ABSTRACT
The influence of the addition of Bi to the dilute ferromagnetic semiconductor (Ga,Mn)As on its electronic structure as well as on its magnetic and structural properties has been studied. Epitaxial (Ga,Mn)(Bi,As) layers of high structural perfection have been grown using low-temperature molecular-beam epitaxy. Post-growth annealing of the samples improves their structural and magnetic properties and increases the hole concentration in the layers. Hard X-ray angle-resolved photoemission spectroscopy reveals a strongly dispersing band in the Mn-doped layers, which crosses the Fermi energy and is caused by the high concentration of Mn-induced itinerant holes located in the valence band. An increased density of states near the Fermi level is attributed to additional localized Mn states. In addition to a decrease in the chemical potential with increasing Mn doping, we find significant changes in the valence band caused by the incorporation of a small atomic fraction of Bi atoms. The spin-orbit split-off band is shifted to higher binding energies, which is inconsistent with the impurity band model of the band structure in (Ga,Mn)As. Spectroscopic ellipsometry and modulation photoreflectance spectroscopy results confirm the valence band modifications in the investigated layers.
ABSTRACT
The presented research was focused on the analysis of the impact of biochar application into the soil on the radon exhalation process as a new issue of radiation protection in agriculture. Field measurements of the radon exhalation rate utilizing two methods-active and passive as well as laboratory measurements of the radon emanation coefficient were performed. In laboratory a soil samples with sunflower husk biochar were analysed using the accumulation chamber technique. At the final step the assessment of the effective dose for humans coming from radon exhalation from soil depending on biochar dose applied were evaluated. The doses of biochar applied in the analysed experimental fields were 0, 20, 40, 60, 80, and 100 Mg ha-1. The results show that biochar application into the soil contribute to a decrease in the emanation coefficient from a value around 7% to less than 2% with a simultaneous decrease in the radon exhalation rate from 4.4 to 14.8 mBq m-2 s-1 when the biochar dose increase from 0 to 100 Mg ha-1.
ABSTRACT
Biochar application has been reported to improve the physical, chemical, and hydrological properties of soil. However, the information about the size fraction composition of the applied biochar as a factor that may have an impact on the properties of soil-biochar mixtures is often underappreciated. Our research shows how sunflower husk biochar (pyrolyzed at 650 °C) can modify the water retention characteristics of arable sandy soil depending on the biochar dose (up to 9.52 wt.%) and particle size (<50 µm, 50-100 µm, 100-250 µm). For comparison, we used soil samples mixed with biochar passed through 2 mm sieve and an unamended reference. The addition of sieved biochar to the soil caused a 30% increase in the available water content (AWC) in comparing to the soil without biochar. However, the most notable improvement (doubling the reference AWC value from 0.078 m3 m-3 to 0.157 m3 m-3) was observed at the lowest doses of biochar (0.95 and 2.24 wt.%) and for the finest size fractions (below 100 µm). The water retention effects on sandy soil are explained as the interplay between the dose, the size of biochar particles, and the porous properties of biochar fractions.
ABSTRACT
Biochar (charcoal made from biomass in the pyrolysis process) has found broad application in agriculture. It helps to improve both the physical and chemical properties of soil through decontamination of heavy metals and pesticides. This work examines the potential for biochar application to improve the radiological condition of soil. We investigated the activity concentration of natural and anthropogenic radionuclides in soil samples collected from fields treated with various doses of biochar (in 1-100 Mg ha-1 ). In addition, we directly measured radon emission rate at the experimental fields. The analyses were performed using gamma spectrometry and an active method for radon emission using an AlphaGUARD instrument equipped with an accumulation box. The results of activity concentration assessments for six radionuclides, five natural and one anthropogenic, show that the only effect of biochar application into the soil is associated with the reduction of soil bulk density by this material. The radon emission rate increased by 6 mBq m-1 s-1 , on average, depending on the biochar dose (from 1 to 100 Mg ha-1 ). Our results demonstrate that application of biochar into soil kept without vegetation had a limited influence on the radioactivity in the environment.
Subject(s)
Radioactivity , Soil Pollutants/analysis , Charcoal , SoilABSTRACT
Water resources on Earth become one of the main concerns for society. Therefore, remote sensing methods are still under development in order to improve the picture of the global water cycle. In this context, the microwave bands are the most suitable to study land-water resources. The Soil Moisture and Ocean Salinity (SMOS), satellite mission of the European Space Agency (ESA), is dedicated for studies of the water in soil over land and salinity of oceans. The part of calibration/validation activities in order to improve soil moisture retrieval algorithms over land is done with ground-based passive radiometers. The European Space Agency L-band Microwave Radiometer (ELBARA III) located near the Bubnów wetland in Poland is capable of mapping microwave emissivity at the local scale, due to the azimuthal and vertical movement of the horn antenna. In this paper, we present results of the spatio-temporal mapping of the brightness temperatures on the heterogeneous area of the Bubnów test-site consisting of an area with variable organic matter (OM) content and different type of vegetation. The soil moisture (SM) was retrieved with the L-band microwave emission of the biosphere (L-MEB) model with simplified roughness parametrization (SRP) coupling roughness and optical depth parameters. Estimated soil moisture values were compared with in-situ data from the automatic agrometeorological station. The results show that on the areas with a relatively low OM content (4-6%-cultivated field) there was good agreement between measured and estimated SM values. Further increase in OM content, starting from approximately 6% (meadow wetland), caused an increase in bias, root mean square error (RMSE), and unbiased RMSE (ubRMSE) values and a general drop in correlation coefficient (R). Despite a span of obtained R values, we found that time-averaged estimated SM using the L-MEB SRP approach strongly correlated with OM contents.
