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Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 10): m1324, 2010 Sep 30.
Article
in English
| MEDLINE
| ID: mdl-21587457
ABSTRACT
Reaction of 4-amino-pyridine with silver(I) perchlorate leads to a one-dimensional coordination polymer, {[Ag(C(5)H(6)N(2))]ClO(4)}(n), in which the amino-pyridine binds through both N atoms. The perchlorate anion is hydrogen bonded to the amino H atoms and inter-acts weakly with the silver(I) atoms (Ag-O > 2.70â Å), both located on inversion centres, and some aromatic H atoms (O-H > 2.55â ÅA), thereby extending the dimensionality of the assembly. This is the first silver complex in which this ligand acts in a bridging mode.