Coupling effect of superfine zeolite and fiber on enhancing the long-term performance of stabilized/solidified Pb-contaminated clayey soils.

The focus of the present study was on the applicability of superfine zeolite (SZ) and polypropylene fibers in improving the geo-environmental parameters as well as the durability of cement-based stabilized/solidified low plasticity clay containing different dosages of Pb. The leaching data revealed that while adding a low range (≤ 7.5%) of sole cement even in the severely polluted soils could fully eliminate the Pb bioavailability, the metal retention capacity might portray a marked sensitivity to the acid-washing process. A major reduction was also observed in the mechanical/leaching performance of those samples after undergoing the wetting-drying (w-d) cycle, especially at a high proportion of Pb, which could weaken the cementation bonding dramatically; hence, much more cement was needed to pass the required stabilization/solidification (S/S) standards. Besides, the micro level tests indicated that the application of SZ (with 25% cement replacement) would alleviate the Pb declining impact on the S/S reactions and modify the porous network of soil. As a result, the specimens amended by cement-SZ (CSZ) were more functional (~ 1.4 times) in immobilizing the toxic ions than the cement alone was. However, the CSZ admixture might not perfectly restrain the w-d forces/deteriorations. Such a potential drawback was found to be solvable by the insertion of fiber, in which case, an enhancement in the ductility and the metal capsulation could be also manifested. In fact, the CSZ/fiber treatment could form a well-intertwined matrix, showing high success rates in stabilizing/solidifying the contaminated soils alongside a significant decrease (~ 2-folds) in the quantity of needed amount of cement to give the S/S satisfactory operation under the harsh environmental conditions.

Long-term impacts of road salt application on the groundwater contamination in urban environments.

This study explores the contamination potential of groundwater due to the use of sodium chloride (NaCl) in the wintertime. The research was conducted in two Iranian cities, Malayer and Hamedan, where groundwater is the major source of water for drinking and irrigating purposes. However, the amount of deicing salt used in the former is about 10 times less than that used in the latter. The assessment of geochemical dataset from 2004 to 2018 revealed no significant trend in the groundwater characteristics of Malayer where the water quality indices were in the range of WHO and USEPA permissible limits. In contrast, the indices had a continually increasing trend (~ 2.3% annually) in Hamedan's supply wells over the same period and particularly near the urban areas that showed higher levels (> 5 times on average) than those observed in Malayer. This could mainly be ascribed to the influx of halite. Based on the USSL diagram, the water samples retrieved from the latter system were mostly classified as C3-S1 (decreasing the soil fertility) and even as C4-S2 (harmful for agriculture activities). Chloride contamination rates also reached 250 mg/L, which could negatively affect the water potability and threaten the aquatics microorganisms. In this region, a rather similar distribution of NaCl and arsenic was observed, implying mobilization of toxic trace metals with the increased salt encroachment into the aquifer. Based on such findings, it is suggested that in snow-influenced cities (e.g., Hamedan), new approaches for winter maintenance be considered to prevent the gradual deterioration of water resources.