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Analyst ; 134(10): 2118-22, 2009 Oct.
Article in English | MEDLINE | ID: mdl-19768223

ABSTRACT

This report presents the development of new selective gas sensors utilizing a b-oriented silicalite-1 layer-magneto-elastic ribbon assembly. The key principle for the operation of these sensors is monitoring the changes in the resonance frequency of the Metglas strip in relation to the concentration of a component in the gas phase. This technique provides a simple way for monitoring the effects of the amount of adsorbed gases in the silicalite-1 coating. The thickness of the zeolite layer is that of a single crystal. The silicalite-1 crystals are oriented in the b-direction, meaning that the straight channels are perpendicular to the sensor surface, which is confirmed by X-ray diffraction (XRD) analysis. The sensor was able to repeatedly sense carbon dioxide in air and could discriminate between linear and branched hydrocarbons. The sensor was able to detect n-butane, while it did not respond to the presence of iso-butane, indicating sensing selectivity.


Subject(s)
Chemistry Techniques, Analytical/instrumentation , Magnetics , Zeolites/chemistry , Elasticity , Free Radicals/chemistry , Gases/analysis , Gases/chemistry , Membranes, Artificial , Microscopy, Electron, Scanning , Oxidants/chemistry , Oxygen/chemistry , Ozone/chemistry , Temperature , Thermogravimetry , X-Ray Diffraction
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