ABSTRACT
The mechanical behavior of titanium alloys has been mostly studied in quasi-static conditions when the strain rate does not exceed 10 s-1, while the studies performed in dynamic settings specifically for Ti-based composites are limited. Such data are critical to prevent the "strength margin" approach, which is used to assure the part performance under dynamic conditions in the absence of relevant data. The purpose of this study was to obtain data on the mechanical behavior of Ti-based composites under dynamic condition. The Metal Matrix Composites (MMC) on the base of the alloy Ti-6Al-4V (wt.%) were made using Blended Elemental Powder Metallurgy with different amounts of reinforcing particles: 5, 10, and 20% of TiC or 5, 10% (vol.) of TiB. Composites were studied at high strain rate compression ~1-3 × 103·s-1 using the split Hopkinson pressure bar. Mechanical behavior was analyzed considering strain rate, phase composition, microstructure, and strain energy (SE). It is shown that for the strain rates up to 1920 s-1, the strength and SE of MMC with 5% TiC are substantially higher compared to particles free alloy. The particles TiC localize the plastic deformation at the micro level, and fracturing occurs mainly by crushing particles and their aggregates. TiB MMCs have a finer grain structure and different mechanical behavior. MMC with 5 and 10% TiB do not break down at strain rates up to almost 3000 s-1; and 10% MMC surpasses other materials in the SE at strain rates exceeding 2200 s-1. The deformation mechanism of MMCs was evaluated.
ABSTRACT
Transmission Kikuchi Diffraction (TKD) in the scanning electron microscope has been developing at a fast pace since its introduction less than a decade ago. The recently presented on-axis detector configuration, with its optimized geometry, has significantly increased the signal yield and facilitated the acquisition of STEM images in bright field (BF) and dark field (DF) mode, in addition to the automated orientation mapping of nanocrystalline electron transparent samples. However, the physical position of the integrated imaging system, located outside the detector screen, requires its movement in order to combine high resolution STEM images with high resolution orientation measurements. The difference between the two positions makes it impossible to acquire optimal signals simultaneously, leading to challenges when investigating site-specific nanocrystalline microstructures. To eliminate this drawback, a new imaging capability was added at the centre of the on-axis TKD detector, thus enabling acquisition of optimal quality BF images and orientation maps without detector movement. The advantages brought about by this new configuration are presented and the associated limitations are discussed.
ABSTRACT
A new setup for automatic 3D EBSD data collection in static mode has been developed using a conventional FIB-SEM system. This setup requires no stage or sample movements between the FIB milling and EBSD mapping. Its capabilities were tested experimentally on a coherent twin boundary of an INCONEL sample. Our result demonstrates that this static setup holds many advantages in terms of data throughput and quality as compared with other ones requiring stage/sample movements. The most important advantages are the better slice alignment and an improved orientation precision in 3D space, both being prerequisite for a reliable grain boundary characterization.
ABSTRACT
The structure and phase evolution of nanocrystalline Ce(1-x)Ln(x)O(2-x/2-delta) (Ln = Yb, Lu, x = 0 - 1) oxides upon heating in H(2) was studied for the first time. Up to 950 degrees C the samples were single-phase, with structure changing smoothly with x from fluorite type (F) to bixbyite type (C). For the Lu-doped samples heated at 1100 degrees C in the air and H(2), phase separation into coexisting F- and C-type structures was observed for ~0.40 < x < ~0.70 and ~0.25 < x < ~0.70, respectively. It was found also that addition of Lu(3+) and Yb(3+) strongly hinders the crystallite growth of ceria during heat treatment at 800 and 950 degrees C in both atmospheres. Valency of Ce and Yb in Ce(0.1)Lu(0.9)O(1.55-delta) and Ce(0.95)Yb(0.05)O(1.975-delta) samples heated at 1100 degrees C was studied by XANES and magnetic measurements. In the former Ce was dominated by Ce(4+), with small contribution of Ce(3+) after heating in H(2). In the latter, Yb existed exclusively as 3+ in both O(2) and H(2).
