ABSTRACT
This commentary draws together the confluence of current events - COVID-19 pandemic and racial injustice. Vulnerability to COVID-19 cannot be understood by age alone but within the context of inequity. We first review how COVID-19 has disproportionately affected Black and Latinx populations across the life span with the latest data from New York City Department of Health. We then discuss critical race theory and analyze longstanding inequities in health, economic, and social conditions that heighten the risk for vulnerability. We conclude with a discussion for the social work profession on the issues of defunding the police to undoing stereotypes.
Subject(s)
Ageism , COVID-19/epidemiology , Racism , Black or African American , COVID-19/ethnology , Health Status Disparities , Hispanic or Latino , Humans , New York City/epidemiology , Pandemics , SARS-CoV-2 , Social Determinants of HealthABSTRACT
Dications of p-substituted 3-phenylindenylidenefluorenes were prepared to examine the response of the resulting indenyl and fluorenyl cationic systems to magnetic measures of antiaromaticity. All measures, (1)H NMR shifts, nucleus independent chemical shifts (NICS(1)(zz)), and magnetic susceptibility exaltation, Lambda, supported the antiaromaticity of the dications 3a-f2+. The 1H NMR shifts and NICS(1)(zz) showed that the indenyl ring system was less antiaromatic than the fluorenyl ring system, contrary to the antiaromaticity of indenyl monocations compared to fluorenyl monocations. The presence of a phenyl substituent in the 3-position was able to stabilize the indenylidene cation through resonance, decreasing its antiaromaticity, but even in the absence of the 3-phenyl substituent, the indenyl system of indenylidenefluorene dications was less antiaromatic than the fluorenyl system. The decreased antiaromaticity of the 3-phenylindenylidenefluorene dications over the unsubstituted indenylidenefluorene dication was supported by (anti)aromatic (de)stabilization energy calculations, ASE.
