ABSTRACT
The AlCoCrFeNi high-entropy alloy is sensitive to heat treatment. The aim of the present study was to test a similar correlation for AlxCoCrFeNi alloys with less than equimolar aluminum content. This paper presents a study of the annealing effect on the structure and mechanical properties of selected alloys. AlxCoCrFeNi alloys (x = 0, 0.5, 0.7) were fabricated by the induction melting method. The obtained specimens were annealed at 500 °C and 900 °C. A detailed study of the changes in crystalline structure due to annealing was conducted. Three-point bending and hardness tests were carried out for the as-cast and annealed specimens to determine selected mechanical properties. The study confirmed that increasing the aluminum content in the AlxCoCrFeNi alloy improves mechanical properties. For the alloy with aluminum content x = 0.7, hardness increased by 187% and yield strength by 252% compared to the alloy without aluminum. A significant effect of annealing on the crystalline structure of the Al0.7CoCrFeNi alloy was found, but this was not followed by changes in mechanical properties.
ABSTRACT
High-entropy alloys are a new generation of materials that have attracted the interest of numerous scientists because of their unusual properties. It seems interesting to use these alloys in biomedical applications. However, for this purpose, the basic condition of corrosion resistance must be fulfilled. In this article, selected corrosion properties of self-composed high-entropy alloys are investigated and compared with conventional biomedical alloys, that is titanium alloys and stainless steels. Corrosive parameters were determined using the potentiodynamic method. X-ray diffraction studies were performed to characterize the crystal structures. Microstructures of the prepared materials were examined using a scanning electron microscope, and surface hardness was measured by the Vickers method. The results show that investigated high-entropy alloys are characterized by simple structures. Three out of four tested high-entropy alloys had better corrosion properties than conventional implant alloys used in medicine. The Al0.7CoCrFeNi alloy was characterized by a corrosion potential of -224 mV and a corrosion current density of 0.9 µA/cm2; CoCrFeNiCu by -210 mV and 1.1 µA/cm2; TiAlFeCoNi by -435 mV and 4.6 µA/cm2; and Mn0.5TiCuAlCr by -253 mV and 1.3 µA/cm2, respectively. Therefore, the proposed high-entropy alloys can be considered as potential materials for biomedical applications, but this requires more studies to confirm their biocompatibility.
ABSTRACT
Recurrent oral infections, as manifested by endodontic and periodontal disease, are often caused by Enterococcus faecalis (E. faecalis) and Candida albicans (C. albicans). Here, we assessed the anti-biofilm activity of ceragenin CSA-44 against these microbes growing as a biofilm in the presence of saliva on the surface of human teeth and dental composite (composite filling) subjected to mechanical stresses. Methods: Biofilm mass analysis was performed using crystal violet (CV) staining. The morphology, viscoelastic properties of the biofilm after CSA-44 treatment, and changes in the surface of the composite in response to biofilm presence were determined by AFM microscopy. Results: CSA-44 prevented biofilm formation and reduced the mass of biofilm formed by tested microorganisms on teeth and dental composite. Conclusion: The ability of CSA-44 to prevent the formation and to reduce the presence of established biofilm on tooth and composite filling suggests that it can serve as an agent in the development of new methods of combating oral pathogens and reduce the severity of oral infections.
ABSTRACT
Fossil frustules of Ellerbeckia and Melosira were studied using laboratory-based nano X-ray tomography (nano-XCT), transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDS). Three-dimensional (3D) morphology characterization using nondestructive nano-XCT reveals the continuous connection of fultoportulae, tube processes and protrusions. The study confirms that Ellerbeckia is different from Melosira. Both genera reveal heavily silicified frustules with valve faces linking together and forming cylindrical chains. For this cylindrical architecture of both genera, valve face thickness, mantle wall thickness and copulae thickness change with the cylindrical diameter. Furthermore, EDS reveals that these fossil frustules contain Si and O only, with no other elements in the percentage concentration range. Nanopores with a diameter of approximately 15 nm were detected inside the biosilica of both genera using TEM. In situ micromechanical experiments with uniaxial loading were carried out within the nano-XCT on these fossil frustules to determine the maximal loading force under compression and to describe the fracture behavior. The fracture force of both genera is correlated to the dimension of the fossil frustules. The results from in situ mechanical tests show that the crack initiation starts either at very thin features or at linking structures of the frustules.
ABSTRACT
Nowadays, metallic alloys are extensively used in wear-related biomedical applications. However, it was shown that one of the factors which may contribute to the premature implant failure is the temperature effect caused by the sliding action between the bearing surfaces. Nevertheless, there are not many papers where the wear-related temperature phenomena of biomedical alloys are discussed. Thus, in our paper, we present findings from the tribological tests of the model metallic biomaterials-316L steel, CoCrMo alloy and Ti gr. 2. In our study, the temperature alterations induced by the wear action of the examined materials were analyzed. According to the findings, the temperature response of the biomedical alloys is tribological pair dependent. While the mass loss of the tribological pair 316L-316L steel was the slightest, at the same time the temperature increase was the greatest. Based on the presented findings, further analyses in friction-induced temperature response of biomedical alloys is recommended.
ABSTRACT
The paper presents an investigation that was conducted to determine the possibility of the occurrence of the process of dynamic recrystallization in 2024 alloy during monotonic tensile and creep tests at the elevated temperatures of 100 °C, 200 °C, and 300 °C. As-extruded material was subjected to creep process with constant force at elevated temperatures, until two varying degrees of deformation were reached. After cooling at ambient temperature, the pre-deformed material was subjected to monotonic and fatigue tests as well as metallographic analysis. The process of dynamic recrystallization was determined in monotonic tests to occur at low strain rate (0.0015/s) only at the temperature of 300 °C. However, in the creep tests, this process occurred with varying efficiency, both during creep at 200 °C and 300 °C. Dynamic recrystallization was indicated to have a significant influence on the monotonic and cyclic properties of the material.
