ABSTRACT
We present a new technique for large-scale fabrication of colloidal crystals with controllable quality and thickness. The method is based on vertical deposition in the presence of a DC electric field normal to the conducting substrate. The crystal structure and quality are quantitatively characterized by microradian X-ray diffraction, scanning electron microscopy, and optical reflectometry. Attraction between the charged colloidal spheres and the substrate promotes growth of thicker crystalline films, while the best-quality crystals are formed in the presence of repulsion. Highly ordered thick crystalline layers with a small amount of stacking faults and a low mosaic spread can be obtained by optimizing the growth conditions.
ABSTRACT
Using microradian X-ray diffraction, we investigated the crystal structure of convectively assembled colloidal photonic crystals over macroscopic (0.5 mm) distances. Through adaptation of Wilson's theory for X-ray diffraction, we show that certain types of line defects that are often observed in scanning electron microscopy images of the surface of these crystals are actually planar defects at 70.5 degrees angles with the substrate. The defects consist of two parallel hexagonal close-packed planes in otherwise face-centered cubic crystals. Our measurements indicate that these stacking faults cause at least 10% of stacking disorder, which has to be reduced to fabricate high-quality colloidal photonic crystals.
ABSTRACT
We report what we believe to be the first demonstration of cw and passively mode-locked Yb(3+):YAlO(3) (Yb:YAP) laser operation under diode pumping. Spectroscopic properties of a 0.6 at.%Yb(3+)-doped YAP single crystal were investigated. Output power up to 1.2 W with slope efficiency of 64.5% in the cw regime and 225 fs pulse duration with average power of 0.8 W from a mode-locked Yb:YAP laser were demonstrated.
