Self-Assembled Organic Nanocrystals with Strong Nonlinear Optical Response.

Facile molecular self-assembly affords a new family of organic nanocrystals that, unintuitively, exhibit a significant nonlinear optical response (second harmonic generation, SHG) despite the relatively small molecular dipole moment of the constituent molecules. The nanocrystals are self-assembled in aqueous media from simple monosubstituted perylenediimide (PDI) molecular building blocks. Control over the crystal dimensions can be achieved via modification of the assembly conditions. The combination of a simple fabrication process with the ability to generate soluble SHG nanocrystals with tunable sizes may open new avenues in the area of organic SHG materials.

Enhanced Third-Harmonic Generation from a Metal/Semiconductor Core/Shell Hybrid Nanostructure.

Nonlinear optical processes can be dramatically enhanced via the use of localized surface plasmon modes in metal nanoparticles. Here we show how more elaborate structures, based on shape-controlled Au/Cu2O core/shell nanostructures, enable further enhancement of the nanoparticle third-harmonic scattering cross-section. The semiconducting component takes a twofold role in this structure, both providing a knob to tune the resonant frequency of the gold plasmon and providing resonant enhancement by virtue of its excitonic states. The advantages and deficiencies of using such core/shell metal/semiconductor structures are discussed.

Single-beam coherent Raman spectroscopy and microscopy via spectral notch shaping.

We present a simple and easily implementable scheme for multiplexed Coherent Anti-Stokes Raman Scattering (CARS) spectroscopy and microscopy using a single femtosecond pulse, shaped with a narrow spectral notch. We show that a tunable spectral notch, shaped by a resonant photonic crystal slab, can serve as a narrowband, optimally time-delayed probe, resolving a broad vibrational spectrum with high spectral resolution in a single-shot measurement. Our single-source, single-beam scheme allows the simple transformation of any multiphoton microscope with adequate bandwidth into a nearly alignment-free CARS microscope.

Real-time measurement of unique space-variant polarizations.

A configuration for real-time measurement of unique, space-variant, polarizations is presented. The experimental results reveal that the full state of polarization at each location within the beam can be accurately obtained every 10 msec, limited only by the camera frame rate. We also present a more compact configuration which can be modified to determine the real-time wavelength variant polarization measurements.

Nonlinear immunofluorescent assay for androgenic hormones based on resonant structures.

We report for the first time the use of two photon fluorescence as detection method of affinity binding reactions. We use a resonant grating waveguide structure as platform enhancement for detecting the interaction between fluorescent labeled Boldenone, a non-natural androgenic hormone, and a specific anti-anabolic antibody. We were able to detect a surface coverage of approximately 0.7 ng/mm(2).

Role of photonic bandgaps in polarization-independent grating waveguide structures.

Polarization independence in a one-dimensional resonant grating waveguide structure involves the simultaneous excitation of two guided modes propagating in different directions. Possible simultaneous excitations occur when the two excited guided modes have either the same polarization, i.e., TE-TE (transverse electric) or TM-TM (transverse magnetic), or different polarizations, i.e., TE-TM. Simultaneous excitations may result in bandgaps and singularities. We confirm and show that in order to achieve polarization independence, it is necessary to find the conditions that minimize the effects of such bandgaps and singularities and experimentally demonstrate tunable polarization independence for simultaneously excited TE-TM-guided modes.