Experimental and Numerical Study of Healing Effect on Delamination Defect in Infusible Thermoplastic Composite Laminates.

The integrity of delaminated composite structures can be restored by introducing a thermally-based healing effect on continuous fiber-reinforced thermoplastic composites (CFRTPC). The phenomenon of thermoplastics retaining their properties after melting and consolidation has been applied by heating the delaminated composite plates above their glass transition temperature under pressure. In the current investigation, the composite is comprised of Methyl methacrylate (MMA)-based infusible lamination resin combined with benzoyl peroxide initiator, which polymerizes into a Polymethyl methacrylate (PMMA) matrix. For the reinforcement, unidirectional 220 gr/m2 glass filament fabric was used. Delamination damage is artificially induced during the fabrication of laminate plates. The distributed delamination region before and after thermally activated healing was determined by using non-destructive testing with active thermography. An experimental approach is employed to characterize the thermal healing effect on mechanical properties. Experimentally determined technological parameters for thermal healing have been successfully applied to repair delamination defects on composite plates. Based on the compression-after-impact (CAI) test methodology, the intact, damaged, and healed composite laminates were loaded cyclically to evaluate the healing effect on stiffness and strength. During the CAI test, the 3D digital image correlation (DIC) technique was used to measure the displacement and deformation fields. Experimental results reveal the difference between the behavior of healed and damaged specimens. Additionally, the numerical models of intact, damaged, and healed composite laminates were developed using the finite element code LS-Dyna. Numerical models with calibrated material properties and tie-break contact constants provide good correlation with experimental results and allow for the prediction of the mechanical behavior of intact, damaged, and healed laminated plates. The comparison analysis based on CAI test results and modal characteristics obtained by the 3D Laser Doppler Vibrometer (Polytec GmbH, Karlsbad, Germany) proved that thermal healing partially restores the mechanical properties of damaged laminate plates. In contrast, active thermography does not necessarily indicate a healing effect.

Dynamic Mechanical Properties of PVC Plastics in the Formation of Microstructures with Novel Magnetostrictor.

Molding in thermoplastic polymers using ultrasonic hot embossing technology is promising due to its high precision reproducibility. To understand, analyze and apply the formation of polymer microstructures by the ultrasonic hot embossing method, it is necessary to understand dynamic loading conditions. The Standard Linear Solid model (SLS) is a method that allows analyzing the viscoelastic properties of materials by representing them as a combination of springs and dashpots. However, this model is general, and it is challenging to represent a viscoelastic material with multiple relaxations. Therefore, this article aims to use the data obtained from dynamic mechanical analysis for extrapolation in a wide range of cyclic deformations and to use the obtained data in microstructure formation simulations. The formation was replicated using a novel magnetostrictor design that sets a specific temperature and vibration frequency. The changes were analyzed on a diffractometer. After the diffraction efficiency measurement, it was found that the highest quality structures were formed at a temperature of 68 °C, a frequency of 10 kHz, a frequency amplitude of 1.5 µm and a force of 1 kN force. Moreover, the structures could be molded on any thickness of plastic.

A Data-Driven System Identification Method for Random Eigenvalue Problem Using Synchrosqueezed Energy and Phase Portrait Analysis.

The primary purpose of this research is to evaluate the uncertainty associated with modal parameter estimation for an inverse dynamic problem in which the structural parameters are random. The random nature of the structure's parameters will be reflected in the modal features of the respected system. However, this may result in additive/subtractive errors in modal parameter identification, affecting the identification technique's efficiency. With this in mind, the present study aims to develop an automated modal identification algorithm for a random eigenvalue problem. This is achieved by a recently developed advanced version of the wavelet transform (i.e., synchrosqueezing), which offers better resolution. Using this technique, the measured responses are transformed into a time-frequency plane, which is further processed by unsupervised learning using K-means clustering for quantification of the modal parameters. This automated identification is repeated for an ensemble of measurements to quantify the random eigenvalues in a statistical sense. The proposed methodology is first tested using simulated time histories of a two degree-of-freedom (dof) system. It is followed by an experimental validation using a beam whose mass matrix is random. The numerical results presented in this work clearly demonstrate the performance (i.e., in terms of efficiency and accuracy) of the proposed output-only automated data-driven identification scheme for random eigenvalue problems.

Development of Finite Element Models of PP, PETG, PVC and SAN Polymers for Thermal Imprint Prediction of High-Aspect-Ratio Microfluidics.

Polymeric microstructures and microchannels are widely used in biomedical devices, optics, microfluidics and fiber optics. The quality, the shape, the spacing and the curvature of microstructure gratings are influenced by different mechanisms and fabrication techniques used. This paper demonstrates a cost-effective way for patterning high-aspect-ratio thermoplastic microstructures using thermal imprint technology and finite element modeling. Polymeric materials polypropylene (PP), polyethylene terephthalate glycol (PETG), polyvinyl chloride (PVC) and styrene-acrylonitrile (SAN) were chosen for the experimental investigations. A finite element model was constructed to define the most suitable parameters (time, heating temperature, pressure, etc.) for the formation of microstructures using the thermal imprint procedure. To confirm the relevance of the finite element model, different types of PP, PETG, PVC and SAN microstructures were fabricated using theoretically defined parameters. Experimental investigations of imprinted microstructures' morphological and optical properties were performed using scanning electron microscopy, atomic force microscopy and a diffractometer. Obtained results confirmed the relevance of the created finite element model which was applied in the formation of high-aspect-ratio microstructures. Application of this model in thermal imprint would not only reduce the fabrication time, but also would highly increase the surface quality and optical properties of the formed structures.

Lead Free Multilayered Polymer Composites for Radiation Shielding.

Silicone-based polymer composites containing high atomic number additives are prioritized for the development of new materials for radiation shielding, due to their mechanical, thermal, electrical, and multifunctional properties. The X-ray attenuation properties, as well as mechanical properties, of the newly developed-lead-free multi-layered structures for radiation shielding, based on silicone composite layers containing tin, cerium oxide, tungsten oxide, and bismuth additives, are analyzed and discussed in this paper. It is shown that, by varying the additive concentrations in silicone composites, lead-free and flexible layered structures, exhibiting lead-equivalent X-ray shielding, can be fabricated.

Effect of Hybridization and Ply Waviness on the Flexural Strength of Polymer Composites: An Experimental and Numerical Study.

The study aims to ascertain the influence of hybridisation and ply waviness on the flexural behaviour of polymer composites. Two different resin systems, namely epoxy and Poly(methyl methacrylate)-PMMA, were chosen for the study, wherein two batches of carbon/glass hybrid composites (CGHC) were fabricated with the two resin systems. In addition to CGHC samples, four other neat batches with waviness (glass/epoxy and glass/PMMA) were prepared to study the effect of out-of-plane ply waviness. Two sets were additionally made with in-plane waviness (angles ranging from 15-35°) with epoxy to further understand the effect of waviness on flexural behaviour. Thereafter, two more batches of samples with neither waviness nor hybrid architectures were tested to achieve a better understanding of hybridization and the presence of waviness. It was seen that the hybridization of polymer composites introduces a pseudo-ductile behaviour in brittle composites, which makes the failure more predictable. An energy-based model was implemented to quantify the ductility introduced by hybridization. The presence of in-plane waviness increased the flexural load but reduced the modulus considerably. The presence of out-of-plane waviness decreased the flexural properties of composites drastically, though the displacement rate was seen to increase considerably. From the comparison between epoxy and PMMA, it was seen that PMMA exhibited similar flexural properties vis-à-vis epoxy. PMMA is easy to re-cycle and thus could serve as an ideal replacement for epoxy resin. Finally, a numerical model was built based on an LS-DYNA commercial solver; the model predicted the flexural behaviour close to what was seen in the experiments. The model could be calibrated correctly by ascertaining the influence of failure strain in the longitudinal direction, which is fibre dependent, and the failure strain in the transverse direction, which is matrix dependent.

Investigation of the Robotized Incremental Metal-Sheet Forming Process with Ultrasonic Excitation.

During the single-point incremental forming (SPIF) process, a sheet is formed by a locally acting stress field on the surface consisting of a normal and shear component that is strongly affected by friction of the dragging forming tool. SPIF is usually performed under well-lubricated conditions in order to reduce friction. Instead of lubricating the contact surface of the sheet metal, we propose an innovative, environmentally friendly method to reduce the coefficient of friction by ultrasonic excitation of the metal sheet. By evaluating the tool-workpiece interaction process as non-linear due to large deformations in the metal sheet, the finite element method (FEM) allows for a virtual evaluation of the deformation and piercing parameters of the SPIF process in order to determine destructive loads.

Deformation and Failure of MXene Nanosheets.

This work is aimed at the development of finite element models and prediction of the mechanical behavior of MXene nanosheets. Using LS-Dyna Explicit software, a finite element model was designed to simulate the nanoindentation process of a two-dimensional MXene Ti3C2Tz monolayer flake and to validate the material model. For the evaluation of the adhesive strength of the free-standing Ti3C2Tz-based film, the model comprised single-layered MXene nanosheets with a specific number of individual flakes, and the reverse engineering method with a curve fitting approach was used. The interlaminar shear strength, in-plane stiffness, and shear energy release rate of MXene film were predicted using this approach. The results of the sensitivity analysis showed that interlaminar shear strength and in-plane stiffness have the largest influence on the mechanical behavior of MXene film under tension, while the shear energy release rate mainly affects the interlaminar damage properties of nanosheets.