ABSTRACT
Laser-Powder Bed Fusion (L-PBF) of metallic parts is a highly multivariate process. An understanding of powder feedstock properties is critical to ensure part quality. In this paper, a detailed examination of two commercial stainless steel 316L powders produced using the gas atomization process is presented. In particular, the effects of the powder properties (particle size and shape) on the powder rheology were examined. The results presented suggest that the powder properties strongly influence the powder rheology and are important factors in the selection of suitable powder for use in an additive manufacturing (AM) process. Both of the powders exhibited a strong correlation between the particle size and shape parameters and the powder rheology. Optical microscope images of melt pools of parts printed using the powders in an L-PBF machine are presented, which demonstrated further the significance of the powder morphology parameters on resulting part microstructures.
ABSTRACT
Nitinol (nickel-titanium or Ni-Ti) is the most utilized shape memory alloy due to its good superelasticity, shape memory effect, low stiffness, damping, biocompatibility, and corrosion resistance. Various material characteristics, such as sensitivity to composition and production thermal gradients, make conventional methods ineffective for the manufacture of high quality complex Nitinol components. These issues can be resolved by modern additive manufacturing (AM) methods which can produce net or near-net shape parts with highly precise and complex Nitinol structures. Compared to Laser Engineered Net Shape (LENS), Selective Laser Melting (SLM) has the benefit of more easily creating a high quality local inert atmosphere which protects chemically-reactive Nitinol powders to a higher degree. In this paper, the most recent publications related to the SLM processing of Nitinol are reviewed to identify the various influential factors involved and process-related issues. It is reported how powder quality and material composition have a significant effect on the produced microstructures and phase transformations. The effect of heat treatments after SLM fabrication on the functional and mechanical properties are noted. Optimization of several operating parameters were found to be critical in fabricating Nitinol parts of high density. The importance of processing parameters and related thermal cooling gradient which are crucial for obtaining the correct phase structure for shape memory capabilities are also presented. The paper concludes by presenting the significant findings and areas of prospective future research in relation to the SLM processing of Nitinol.
ABSTRACT
This review summarizes the development of methacrylate-based polymer monoliths for separation science applications. An introduction to monoliths is presented, followed by the preparation methods and characteristics specific to methacrylate monoliths. Both traditional chemical based syntheses and emerging additive manufacturing methods are presented along with an analysis of the different types of functional groups, which have been utilized with methacrylate monoliths. The role of methacrylate based porous materials in separation science in industrially important chemical and biological separations are discussed, with particular attention given to the most recent developments and challenges associated with these materials. While these monoliths have been shown to be useful for a wide variety of applications, there is still scope for exerting better control over the porous architectures and chemistries obtained from the different fabrication routes. Conclusions regarding this previous work are drawn and an outlook towards future challenges and potential developments in this vibrant research area are presented. Discussed in particular are the potential of additive manufacturing for the preparation of monolithic structures with pre-defined multi-scale porous morphologies and for the optimization of surface reactive chemistries.
ABSTRACT
The synthesis and characterisation of two terpyridine based ruthenium/palladium heteronuclear compounds are presented. The photocatalytic behaviour of the Ru/Pd complex containing the linear 2,2':5',2''-terpyridine bridge (1a) and its analogue the non-linear 2,2':6',2''-terpyridine bridge (2a) are compared together with the respective mononuclear complexes 1 and 2. Irradiation of 1a with visible light (e.g., 470 nm) results in the photocatalytic generation of dihydrogen gas. Photocatalysis was not observed with complex 2a by contrast. A comparison with the photocatalytic behaviour of the precursors 1 and 2 indicates, that while for 1a the photocatalysis is an intramolecular process, for the mononuclear precursors it is intermolecular. The photophysical and electrochemical properties of the mono- and heterobinuclear compounds are compared. Raman spectroscopy and DFT calculations indicate that there are substantial differences in the nature of the lowest energy (3)MLCT states of 1a and 2a, from which the contrasting photocatalytic activities of the complexes can be understood.
Subject(s)
Hydrogen/chemistry , Palladium/chemistry , Ruthenium/chemistry , Catalysis , Ligands , Photochemical ProcessesABSTRACT
Novel cyclometallated iridium-Pt/Pd dinuclear complexes containing the bridging ligand 2,2':5',2''-terpyridine (BPP) and the peripheral phenylpyridine (ppy) ligand produced hydrogen under both visible (470 nm) and UV (350 nm) irradiation. The turnover numbers using visible light were found to be significantly higher, indicating an interplay between two independent excited states, only one of which produces H(2) efficiently.
ABSTRACT
A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not.
ABSTRACT
The synthesis and characterization of a series of mono- and dinuclear ruthenium(II) and osmium(II) polypyridyl complexes based on the heteroditopic bridging ligand PT are reported. This ligand incorporates bidentate phen (1,10-phenanthroline) and terdentate tpy (2,2':6',2''-terpyridine) units directly connected by their 3 and 5 positions, respectively. The dinuclear complexes have been synthesized via a Pd(0) catalyzed cross-coupling reaction between a bromo-substituted Ru-phen complex and a tpy derivative incorporating a boronate ester, followed by Ru(II) or Os(II) complexation. The compounds obtained are fully characterized using spectroscopic and electrochemical measurements. The electrochemical studies do not yield any evidence for interaction between the two metal centers in the dinuclear compounds. Emission studies indicate, however, energy transfer from the phen moiety to the tpy center. For the ruthenium/osmium species, this process is relatively slow, resulting in a dual emission. The emission of the mononuclear ruthenium compound is enhanced by the addition of Zn(II).
