ABSTRACT
In the title compound, C14H14N2O5S, the mol-ecule exists in the enamine (C=C-NH) tautomeric form. The hydrazone fragment derived from the 3-acetyl-4-hy-droxy-6-methyl-2H-pyran-2-one moiety is approximately planar, with a maximum deviation of 0.1291â (11)â Å for the N atom bound to the S atom of the benzensulfono-hydrazide group. The latter adopts a gauche conformation relative to the hydrazone N-N bond, with an N-N-S angle of 113.54â (10)°. There is an intra-molecular N-Hâ¯O=C hydrogen bond that stabilizes the tautomeric form. In the crystal, mol-ecules are linked by N-Hâ¯O=C hydrogen bonds into chains extending parallel to [100].
ABSTRACT
In the title compound, C22H26N4O3S, the dihedral angle between the pyrazoloneand phenyl rings is 21.73â (4)°. The benzensulfono-hydrazide group adopts a gauche conformation about the N-N vector. The C-N-N-S torsion angle is -109.88â (13)°. The mol-ecule exists as the enamine tautomeric form (C=C-NH). An intra-molecular N-Hâ¯O=C hydrogen bond occurs. In the crystal, mol-ecules are linked by pairs of N-Hâ¯O=C hydrogen bonds, forming centrosymmetric dimers.
ABSTRACT
The preparations and structures are described of four new polyoxostibonates, [Co(p-MeC(6)H(4)Sb)(12)O(28){Co(H(2)O)(3)}(4)]Cl(2)·6H(2)O, [Co(p-ClC(6)H(4)Sb)(12)O(28){Co(H(2)O)(3)}(4)]Cl(2)·22H(2)O, (PhCH(2)NMe(3))(2)[Zn(p-ClC(6)H(4)Sb)(12)O(28)Zn(4)Cl(2.54)Br(1.46)]·8MeCN·H(2)O and [BaCoH(4)(p-MeC(6)H(4)Sb)O(28)]·5H(2)O. Each of these has a framework of 12 (RSb) groups linked by 28 O atoms, with one transition metal ion in a tetrahedral site in the centre. Other metal ions are coordinated to the polyhedral faces. Three of the complexes have the ε Keggin ion geometry, while the fourth is a δ isomer.
Subject(s)
Cobalt/chemistry , Tungsten Compounds/chemistry , Zinc/chemistry , Coordination Complexes/chemical synthesis , Coordination Complexes/chemistry , Crystallography, X-Ray , Ions/chemistry , Molecular ConformationABSTRACT
The crystal structure of the title compound, C(30)H(38)N(2)O(5)Si, has been investigated to establish the relative stereochemistry at the spiro ring junction and the two anomeric centres. Each of the O atoms in the tetra-hydro-pyran rings adopts an axial position on the neighbouring ring. This bis--diaxial conformation is adopted, thus gaining maximum stablization from the anomeric effect. The silyl-protected hydroxy-methyl and uracil substituents adopt equatorial positions on their associated tetra-hydro-pyran rings, thereby minimizing unfavourable steric inter-actions. The dimeric (2'R*,6'R*,8'R*)- and (2'S*,6'S*,8'S*)-uridine units are connected to each other across crystallographic inversion centres via inter-molecular N-Hâ¯O hydrogen bonds.