Conducting, Self-Assembled, Nacre-Mimetic Polymer/Clay Nanocomposites.

We demonstrate electrically and ionically conducting nacre-mimetic nanocomposites prepared using self-assembly of synthetic nanoclay in combination with PEDOT: PSS and a poly(ionic liquid) polymer from aqueous dispersions. The resulting nacre-mimetics show high degrees of mesoscale order and combine high stiffness and high strength. In terms of conductivities, the resulting hybrids exceed simple additive behavior and display synergetic conductivities due to high levels of interfaces and anisotropic conductivity pathways. The approach highlights the integration of relevant functionalities into stiff and strong bioinspired materials, and shows that synergetic properties beyond mechanical performance can be realized in advanced multifunctional nanocomposites using nacre-inspired design principles.

Thiazolium Poly(ionic liquid)s: Synthesis and Application as Binder for Lithium-Ion Batteries.

We report a synthetic route to thiazolium-type poly(ionic liquid)s (PILs), which can be applied as a polymeric binder in lithium-ion batteries. The ionic liquid monomers were first synthesized by quaternization reaction of 4-methyl-5-vinyl thiazole with methyl iodide, followed by anion exchange reactions to replace iodide by fluorinated anions to access a liquid state below 100 °C. Subsequently, these monomers bearing thiazolium cations in their structure underwent radical polymerizations in bulk to produce corresponding polymers. The dependence of solution and thermal properties of such monomeric and polymeric materials on the choice of the counteranion was investigated. Finally, the thiazolium-type PIL bearing a bis(trifluoromethanesulfonyl)imide (TFSI) anion was proven to be a high performance binder for lithium-ion battery electrodes.

Polyfluorene polyelectrolyte nanoparticles: synthesis of innovative stabilizers for heterophase polymerization.

Polyfluorene-bearing bromohexyl side chains are quaternized by 1-vinylimidazole in order to attach dialkylimidazolium bromide ionic liquid (IL) species along the conjugated backbone. Subsequently, polyfluorene polyelectrolyte nanoparticles (NPs) of 40 nm in average size are created via radical cross-linking of the pendant vinylimidazolium groups. Anion exchange from Br(-) to BF(4)(-), PF(6)(-), and bis(trifluoromethylsulfonyl)imide anion (TFSI(-) renders NPs adjustable dispersability in various organic solvents. The hydrophobic-conjugated backbone and the hydrophilic dialkylimidazolium bromide IL moieties depict an amphiphilic profile, which allows the NPs to be deployed as conductive stabilizer in the emulsion polymerization of styrene. The resultant latexes are fluorescent, tunable in size and can be transferred to organic solvents without forfeiting their colloidal stability.

Omnidispersible poly(ionic liquid)-functionalized cellulose nanofibrils: surface grafting and polymer membrane reinforcement.

We report a facile one-step route to graft poly(ionic liquid)s (PILs) onto cellulose nanofibrils (CNFs). The dispersibility of the PIL-functionalized CNFs in water and various organic solvents could be tuned by the choice of the PIL-binding anion. We demonstrate that such omnidispersible PIL@CNF hybrids can be used to reinforce porous poly(ionic liquid) membranes.