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In situ preparation of beta-D-1-O-hydroxylamino carbohydrate polymers mediated by galactose oxidase.
Org Lett
; 4(11): 1863-6, 2002 May 30.
Article
in English
| MEDLINE
| ID: mdl-12027633
ABSTRACT
[reaction: see text] Galactose oxidase produced a C-6 aldehyde in various terminal-containing galactose hydroxylamines for the simultaneous in situ generation of an A-B type condensation for the construction of unique oxime polymers. Molecular weights of the corresponding polymers were determined to be in the range of 4200-8900 g/mol, respectively. This indicates that approximately 20-25 sugar units were incorporated in these unique polymers.