Recovery of phosphorus as struvite from sewage sludge ash.

Phosphorus (P) is an element vital for all living organisms, yet the world's reserves of phosphate rock are becoming depleted. This study investigated an effective P recovery method from sludge ash via struvite precipitation. Results showed that more than 95% of the total P content was extracted from sludge ash by applying 0.5 mol/L HCl at a liquid/solid ratio of 50 mL/g. Although heavy metal leaching also occurred during P extraction, cation exchange resin efficiently removed the heavy metals from the P-rich solution. Orthogonal tests showed that the optimal parameters for P precipitation as struvite would be a Mg:N:P molar ratio of 1.6:1.6:1 at pH 10.0. X-ray diffraction analysis validated the formation of struvite. Further investigations revealed that the harvested precipitate had a high struvite content (97%), high P bioavailability (94%), and low heavy metal content, which could be considered a high quality fertilizer.

Distribution of C and N in soluble fractionations for characterizing the respective biodegradation of sludge and bulking agents.

This study utilized C and N distribution in different soluble fractionations instead of the routine C/N ratio to characterize the respective biodegradation of sludge and bulking agents in bio-drying or composting. For sludge, C was mainly distributed (31.8%) in the neutral detergent soluble and water insoluble fraction (SOL), whereas it was mainly distributed in the cellulose-like fraction (CEL) for straw (39.5%) and sawdust (45.8%). A large proportion of N was in the 35 °C water-soluble fraction (W35 °C) for sludge (34.0%) and straw (52.5%), while for sawdust it was in the lignin-like fraction (LIG; 49.4%). For sludge, the C and N loss were mainly contributed by W35 °C (36.9% and 52.4%). The other fractions also contributed a lot. For straw, 22.4% of C and 89.8% of N lose in W35 °C. The hemicellulose-like (HEM) and CEL fraction also gave a large contribution to C loss (28.5% and 40.1%), while contributing little to N loss.

Biodegradation potential of bulking agents used in sludge bio-drying and their contribution to bio-generated heat.

Straw and sawdust are commonly used bulking agents in sludge composting or bio-drying. It is important to determine if they contribute to the biodegradable volatile solids pool. A sludge bio-drying process was performed in this study using straw, sawdust and their combination as the bulking agents. The results revealed that straw has substantial biodegradation potential in the aerobic process and sawdust has poor capacity to be degraded. The temperature profile and bio-drying efficiency were highest in the trial that straw was added, as indicated by a moisture removal ratio and VS loss ratio of 62.3 and 31.0%, respectively. In separate aerobic incubation tests, straw obtained the highest oxygen uptake rate (OUR) of 2.14 and 4.75 mg O(2) g(-1)VS h(-1) at 35 °C and 50 °C, respectively, while the highest OUR values of sludge were 12.1 and 5.68 mg O(2) g(-1)VS h(-1) at 35 °C and 50 °C and those of sawdust were 0.286 and 0.332 mg O(2) g(-1)VS h(-1), respectively. The distribution of biochemical fractions revealed that soluble fractions in hot water and hot neutral detergent were the main substrates directly attacked by microorganisms, which accounted for the initial OUR peak. The cellulose-like fraction in straw was transformed to soluble fractions, resulting in an increased duration of aerobic respiration. Based on the potential VS degradation rate, no bio-generated heat was contributed by sawdust, while that contribution by straw was about 41.7% and the ratio of sludge/straw was 5:1 (w/w, wet basis).

Effect of air-flow rate and turning frequency on bio-drying of dewatered sludge.

Sludge bio-drying is an approach for biomass energy utilization, in which sludge is dried by means of the heat generated by aerobic degradation of its organic substances. The study aimed at investigating the interactive influence of air-flow rate and turning frequency on water removal and biomass energy utilization. Results showed that a higher air-flow rate (0.0909m(3)h(-1)kg(-1)) led to lower temperature than did the lower one (0.0455m(3)h(-1)kg(-1)) by 17.0% and 13.7% under turning per two days and four days. With the higher air-flow rate and lower turning frequency, temperature cumulation was almost similar to that with the lower air-flow rate and higher turning frequency. The doubled air-flow rate improved the total water removal ratio by 2.86% (19.5gkg(-1) initial water) and 11.5% (75.0gkg(-1) initial water) with turning per two days and four days respectively, indicating that there was no remarkable advantage for water removal with high air-flow rate, especially with high turning frequency. The heat used for evaporation was 60.6-72.6% of the total heat consumption (34,400-45,400kJ). The higher air-flow rate enhanced volatile solids (VS) degradation thus improving heat generation by 1.95% (800kJ) and 8.96% (3200kJ) with turning per two days and four days. With the higher air-flow rate, heat consumed by sensible heat of inlet air and heat utilization efficiency for evaporation was higher than the lower one. With the higher turning frequency, sensible heat of materials and heat consumed by turning was higher than lower one.