A novel phytoremediation method assisted by magnetized water to decontaminate soil Cd based on harvesting senescent and dead leaves of Festuca arundinacea.

It is more economical and feasible to harvest above-ground plant tissues, especially leaves, than to uproot the entire plant during phytoremediation. The major goal of this study is to estimate the promoting effect of an external magnetic field on soil Cadmium (Cd) remediation efficiency by harvesting the leaves of Festuca arundinacea, irrigated by normal and magnetized water. Changes in the amount of emerging, mature, senescent, and dead leaves, as well as Cd concentrations in the corresponding tissues were compared. It was found that F. arundinacea irrigated by either kind of water accumulated significantly more Cd in senescent and dead leaves than in other tissues. After irrigation with magnetized water, the biomass of senescent and dead leaves increased from 15.7 and 6.4% to 17.2 and 11.6%, respectively, and a significantly higher amount of Cd (˜23.6%) was redistributed into dead leaves compared with the control. Thus, significantly more Cd was removed by harvesting the senescent and dead leaves of F. arundinacea. These results indicate that magnetic fields can increase the phytoremediation efficiency of F. arundinacea for Cd, and simultaneously reduce the cost of harvested residue disposal.

Comparing storage battery and solar cell in assisting Eucalyptus Globulus to phytoremediate soil polluted by Cd, Pb, and Cu.

Metal decontamination and leaching alleviation capacity of Eucalyptus globulus with and without electric field were investigated using ICP-MS. The biomass production of the chosen plant increased from 0.87 kg in planting control without electrokinetic treatment to 1.16 and 1.42 kg in experiments with electric field supplied by storage battery and solar cell, respectively. Under the influence of electric field with a voltage of 6.5 V, significantly more Cd, Pb and Cu were extracted by the species. Precipitation simulation was performed to evaluate the capacity of battery and solar panel to intercept leaching. The total volume of leachate gathered from the control decreased from 1012 mL to 299 and 336 mL in containers treated by storage battery and solar cell, respectively. In addition to reduction of leachate, the leaching mass of Cd, Pb and Cu was decreased significantly by electric fields (both battery and solar cell) treatments. The effect of remediation and environmental risk alleviation by solar cell was comparable with storage battery, at least during the 30-day experimental period. On the basis of the present study, solar cell should be a suitable substitute for conventional power supply to improve metal polluted soil when considering phytoremediation efficiency and energy consumption.

Trace Elements and Polycyclic Aromatic Hydrocarbons Variation Along the Guang-Shen Expressway Before and After the 2016 Qingming Festival in Guangzhou.

PM2.5 samples (particles with aerodynamic diameter < 2.5 µm) were collected along the Guang-Shen expressway around the Qingming Festival, one of the most congested periods in China, which started from April 2-4, in 2016. Twenty-five trace elements and 16 priority polycyclic aromatic hydrocarbons (PAHs) of the samples were analyzed. Their major sources at different periods were identified. The concentrations of PAHs distinctly increased with growing traffic flow 2 days before the Qingming Festival (March 31th and April 1st), decreased gradually on the first 2 days of the 3-day festival (April 2nd and 3rd) and rose again on the last day (April 4th). The proportion changing of higher molecular weight containing 5- and 6-ring PAHs (HMW PAHs) closely related to the traffic flow variation were consistent with the concentration variation of PAHs during the experimental period. Indicators of gasoline/diesel engines emission, i.e., Mo, Co, Mn, and Pb showed similar concentration variation with PAHs. The concentrations of trace elements, mainly derived from wear instead of combustion process, such as Cu, Zn, Ti, and Sb, raised significantly during the rainy days. Incremental lifetime cancer risk (ILCR) values were calculated to evaluate the health risk caused by PAH around the Qingming Festival. The ILCR values increased by 3-10 times 2 days before and on the last day of the festival comparing with other days, as a result of traffic related sources, including engine emission and wearing of tires. It concluded by recommending the necessity of traffic diversion to alleviate the health risk to drivers and nearby residents during important festivals.

Using solar cell to phytoremediate field-scale metal polluted soil assisted by electric field.

Eucalyptus globulus were used to remediate a real scale site endangered by e-waste with electric fields supplied by solar cell and conventional storage battery. The capacity of the species to produce biomass, absorb pollutants and decontaminate metals, as well as the soil moisture of various layers under different treatments was compared. During the 3-month experiment, the output potential of solar cell influenced by weather conditions was less stable (ranging from 0 to 8.3 V) comparing with traditional power supply. Solar cell and storage battery stimulated the growth of the species from 5.92 in control to 7.21 and 7.38 kg per plant, respectively, demonstrating their similar improvement effect. Electric fields of either power source increased the metal concentrations of plant roots and shoots in equal proportions and subsequently greatly promoted the efficiency to decontaminate pollutants. Relative to the control without electric field, solar cell and storage battery treatments reduced the soil moisture of each corresponding layer and consequently, alleviated the leaching risk. At the termination of the experiment, metals tended to distribute in the surface layer under electric field assisted phytoremediation either by solar cell or storage battery. Comparing with conventional battery, solar cell has similar effect on improving remediation and mitigating leaching risk, but is less energy consuming and easier to manage, especially under real scale field. Solar cell treatment was suggested to be a suitable supplementary means to improve phytoremediation efficiency.

A real scale phytoremediation of multi-metal contaminated e-waste recycling site with Eucalyptus globulus assisted by electrical fields.

The combined utilization of direct or alternating electric fields and phytoremediation was designed to decontaminate multi-metal polluted soil at a field scale e-waste recycling impacted site. Eucalyptus globulus was chosen for metal purification for its resilient and unpalatable nature. Biomass production, metal concentration and water use efficiency of the species under direct current (DC) and alternating current (AC) fields with various voltages were investigated. DC and AC fields stimulated the growth of the plant, except for DC field with high voltage (10 V). Metal concentrations increased in plant tissues under the influence of AC or DC fields irrespective of voltages. DC fields elevated the root and shoot metal contents of plants in equal proportions and AC fields tended to migrate metals from roots to the aboveground parts of the species. Compared to the control, soil moisture of various soil layers at the planted site was significantly lower and subsequently leading to the decrease of metal leaching. In soil profile metal distributes differently between DC and AC treatments. Compared to AC field, more metals tended to accumulate in soil surface under the influence of DC fields due to the stable converse gravitational pathway of metals. Considering decontamination efficiency, leaching interception and energy consumption, DC field with moderate voltage was a suitable candidate for real scale multi-metal polluted soil phytoremediation.

Effect of planting density and harvest protocol on field-scale phytoremediation efficiency by Eucalyptus globulus.

The phytoremediation efficiency of multi-metal-polluted sites in an electronic waste recycling town by Eucalyptus globulus was evaluated through a series of 2-year field experiments. Different initial planting densities (2500, 5000, and 10,000 plants per ha), coppice rotations, and harvesting position (5 or 30 cm above the ground) protocols were designed to improve the remediation potential of the species. There were unnoticeable variations in metal concentrations and distribution characteristics in plant tissues in a low and medium planting-density field during the experimental period. At the end of the experiment, total biomass production per hectare in different protocols displayed a wide range with maximum yield produced in high density, moderate harvesting, and coppice rotation protocol being 2.9 times higher than the minimum yield. The moderate harvest protocol performed with medium planting density was the optimal Cd and Cu decontamination technique. Although the high planting-density field without coppice rotation had the strongest potential for Pb decontamination, it would take more time to remove other metals for the multi-metal-polluted soil decontamination. Considering the remediation efficiency and maintainability of the cultivation system, the moderate harvest protocol performed with the medium planting density was commended for phytoremediation of e-waste recycling impacted area.

Heavy metal remediation with Ficus microcarpa through transplantation and its environmental risks through field scale experiment.

The phytoremediation efficiency of various metals by Ficus microcarpa was evaluated through a real scale experiment in the present study. The root biomass production of the species varied significantly from 3.68 to 5.43 g because of the spatial heterogeneity of different metals. It would take 4-93 years to purify the excess Cd of the experimental site. Mercury was the most inflexible element which can barely be phytoremediated by F. microcarpa. After the species transplanted from the polluted soil to the clean site, Cd and Cu were transferred to the rhizosphere soil to different extent while the bulk soil was barely influenced. Relative to Cd and Cu, significantly fewer amounts of Pb and Hg were released. The highest concentrations of Cd, Cu, Hg and Pb in the clean soil were far below their corresponding safe thresholds for agricultural land after 3 months of the polluted plants were cultivated and metal concentrations of plant leaves were negligible, both indicated the low ecological risk of transplantation. Results from this study suggested a feasible disposal method for metal rich plants after phytoremediation.