ABSTRACT
The benzimidazole ring in the title compound, C16H17N3O2S, is almost planar, with the greatest deviation from the mean plane being 0.032â (1)â Å. The fused-ring system makes dihedral angles of 19.91â (7) and 24.51â (8)° with the best plane through each of the thia-zol-4-yl and 1,3-dioxolan-4-yl rings, respectively; the latter exhibits an envelope conformation with the methyl-ene C atom being the flap. Finally, the thia-zol-4-yl ring makes a dihedral angle of 33.85â (9)° with the 1,3-dioxolan-4-yl ring. In the crystal, mol-ecules are connected by a pair of C-Hâ¯π(imidazole) inter-actions to form centrosymmetric aggregates.
ABSTRACT
In the title compound, [CoCl2(C17H13N3S)2], the Co(II) atom exhibits a distorted octa-hedral coordination geometry involving two chloride ligands, one of which is split over two positions [refined site-occupancy ratio = 0.847â (18):0.153â (18)], and four N-atom donors from two 1-benzyl-2-(1,3-thia-zol-4-yl)-1H-benzimidazole ligands. The two chelate rings including the Co(II) atom are essentially planar, the maximum deviations from the mean planes being 0.080â (2) and 0.046â (2)â Å; the dihedral angle between them is 74.1â (1)°. In both ligands, the thia-zole and benzimidazole rings are nearly coplanar, as indicated by the dihedral angles between their planes of 1.16â (8) and 6.29â (7)°. Each pendant benzene ring is almost perpendicular to the benzimidazole mol-ecule to which it is attached; the dihedral angles between their planes are 75.94â (9) and 75.55â (10)°. The crystal structure is stabilized by non-classical C-Hâ¯Cl hydrogen bonding forming a three-dimensional network.
ABSTRACT
The nine-membered fused-ring of the title compound, C(10)H(13)N(5)O(2), is approximately planar [maximum deviation = 0.012â (1)â Å]; the bond angle at the methylene C atom is 111.33â (10)°. In the crystal, the amino group forms hydrogen bonds to the N atoms of the triazole rings of adjacent mol-ecules, generating a ribbon running along the a axis.