Investigation on the interaction mechanism during co-combustion of sewage sludge and coal slime: The effect of coal slime type and pretreatment method.

Co-combustion of sewage sludge (SS) and coal slime (CS) is the preferred method for mitigating their environmental impact and increasing their added value. However, the interaction mechanism between SS and CS during the co-combustion process has not yet developed a unified understanding. This work aims to obtain the effect of CS types on SS-CS co-combustion and reveal the interaction mechanism between SS and CS based on the influence of pretreatment methods on the interaction. The results showed that during co-combustion, SS reduced the ignition and burnout temperatures, and CS with high fixed carbon content (e.g., XCS) improved the comprehensive combustion characteristics. Principal component analysis showed that the effect of CS on co-combustion was more significant. The interaction between SS and CS mainly occurred within 100-700 °C, in which inhibition and synergism coexisted. The large differences in the interactions before and after de-volatilization and pickling treatments revealed that the volatiles and ash in SS were the main interaction factors. The analysis of the interaction mechanisms showed that the free radicals and heat released from the SS volatiles combustion accelerated the weight loss of CS, but the formation of tars from its incomplete combustion may inhibit the decomposition of CS. The interaction in the fixed carbon combustion stage was mainly caused by SS ash, which can catalyze the combustion of CS fixed carbon, but for the high ash CS (e.g., QCS), the combustion of fixed carbon was hindered by the addition of SS ash higher than 10 %. The final manifestation (synergy or inhibition) of SS and CS interactions was the result of the competitive balance of the above interactive behaviors. This work provides a more comprehensive understanding of the interaction between SS and CS during co-combustion.

Investigation of interaction mechanisms during co-combustion of sewage sludge and coal slime: Combustion characteristics and NO/SO2 emission behavior.

Co-combustion of sewage sludge (SS) and coal slime (CS) is a promising method to achieve resource utilization of both solid wastes. However, the emission characteristics of NO/SO2 and the interaction mechanisms between SS and CS are unclear. In this paper, the co-combustion characteristics and NO/SO2 emission behavior of SS and CS were investigated using a thermogravimetric analyzer and a tube furnace combustion system, and the interactions between SS and CS were explored. The results revealed the presence of remarkable interactions between SS and CS during the co-combustion. For the combustion characteristics, non-catalytic factors (interaction between volatiles and heat synergy) and catalytic factors (catalysis of inorganic components) controlled the combustion stage of the heavy volatiles and fixed carbon of the blends, respectively, leading to an earlier combustion process. For NO and SO2 emission characteristics, SS-CS co-combustion had significant NO in-situ reduction and self-desulphurization characteristics at 800 °C and 900 °C. The best inhibition occurred at 900 °C and 50 % CS ratio, and NO and SO2 emission amounts were reduced by 0.25 mg/g and 1.37 mg/g, respectively, compared to the theoretical values. At 1000 °C, co-combustion promoted the emissions of both NO and SO2. The interaction mechanisms suggested that the reducing atmosphere created and the reducing gases released by SS combustion promoted the reduction of CS-NO, while the char formed by CS exhibited a significant reduction of SS-NO. In addition, the effect of CS addition on the mass transfer process enhanced the sulfur fixation of inorganic components in SS, which led to the suppression of SO2 production. These findings provide a better understanding of the interactions between SS and CS during SS-CS co-combustion.

N migration and transformation during the co-combustion of sewage sludge and coal slime.

The co-combustion of sewage sludge and coal slime is considered a promising technique for reducing the volume of sewage sludge, adding value, and decreasing the risks associated with these wastes. This work aimed to study N migration and transformation mechanisms and the related interactions during the co-combustion of sewage sludge (SS) and coal slime (CS) by thermogravimetric-mass spectrometry combined with X-ray photoelectron spectroscopy. The results revealed that the main N-containing gases produced during the combustion of SS and CS were NH3 generated from Amino-N at 200-400 °C and HCN generated from heterocyclic nitrogen at 400-600 °C, respectively. The increase of CS ratio led to a decrease in the release of NH3 and NO, but an increase in the release of HCN. Distinct interactions were observed during the co-combustion process, which promoted the production of NH3 and inhibited the production of HCN and NO. Co-combustion inhibited the release of NO by 36.9% when the CS ratio was 50%. The interaction mechanism suggested that H radicals from SS promoted the premature decomposition of N species in CS, and increased the selectivity of N species for NH3 formation by promoting the conversion of heterocyclic-N to Amino-N. In addition, the interaction of char (in SS) and char (in CS) enhanced the reduction of NO. Above 600 °C, co-combustion promoted the retention of N species in the ash.

K2CO3-Impregnated Al/Si Aerogel Prepared by Ambient Pressure Drying for CO2 Capture: Synthesis, Characterization and Adsorption Characteristics.

A new potassium-based adsorbent for CO2 capture with Al aerogel used as support is proposed in this work. The adsorbents with different surface modifiers (tetraethyl orthosilicate (TEOS) and trimethyl chlorosilane (TMCS)) and different K2CO3 loadings (10%, 20%, 30% and 40%) were prepared by sol-gel and iso-volume impregnation processes with ambient pressure drying. The CO2 adsorption performance of the adsorbents were tested by a fixed-bed reactor, and their adsorption mechanisms were studied by scanning electron microscopy (SEM), Brunauer Emmett Teller (BET), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, and X-ray fluorescence spectrometry (XRF). Furthermore, the adsorption kinetics and the cycling performance were investigated. The results show that using TEOS to modify the wet gel can introduce SiO2 to increase the strength of the skeleton. On the basis of TEOS modification, TMCS can further modify -OH, thus effectively avoiding the destruction of aerogel structure during ambient drying and K2CO3 impregnation. In this work, the specific surface area and specific pore volume of Al aerogel modified by TEOS + TMCS are up to 635.32 cm2/g and 2.43 cm3/g, respectively. The aerogels without modification (Al-B), TEOS modification (Al/Si) and TEOS + TMCS modification (Al/Si-TMCS) showed the best CO2 adsorption performance at 20%, 30% and 30% K2CO3 loading, respectively. In particular, the CO2 adsorption capacity and K2CO3 utilization rate of Al/Si-TMCS-30K are as high as 2.36 mmol/g and 93.2% at 70 degrees Celsius (°C). Avrami's fractional order kinetic model can well fit the CO2 adsorption process of potassium-based adsorbents. Al-B-20K has a higher apparent activation energy and a lower adsorption rate during the adsorption process. After 15 adsorption-regeneration cycles, Al/Si-TMCS-30K maintain a stable CO2 adsorption capacity and framework structure, while the microstructure of Al/Si-30K is destroyed, resulting in a decrease in its adsorption capacity by nearly 30%. This work provides key data for the application of Al aerogel in the field of potassium-based adsorbent for CO2 capture.

Study on CO2 Capture Characteristics and Kinetics of Modified Potassium-Based Adsorbents.

In this paper, a silica aerogel support was prepared by two-step sol-gel method, and the active component K2CO3 was supported on the support by wet loading to obtain a modified potassium-based CO2 adsorbent. As the influences of reaction conditions on the CO2 capture characteristics of modified potassium-based adsorbents, the reaction temperature (50 °C, 60 °C, 70 °C, 80 °C), water vapor concentration (10%, 15%, 20%), CO2 concentration (5%, 10%, 12.5%, 15%), and total gas flow rate (400 mL/min, 500 mL/min, 600 mL/min) were studied in a self-designed fixed-bed reactor. At the same time, the low-temperature nitrogen adsorption experiment, scanning electron microscope, and X-ray diffractometer were used to study the microscopic characteristics of modified potassium-based adsorbents before and after the reaction. The results show that the silica aerogel prepared by the two-step sol-gel method has an excellent microstructure, and its specific surface area and specific pore volume are as high as 838.9 m2/g and 0.85 cm3/g, respectively. The microstructure of K2CO3 loaded on the support is improved, which promotes the CO2 adsorption performance of potassium-based adsorbents. The adsorption of CO2 by potassium-based adsorbents can be better described by the Avrami fractional kinetic model and the modified Avrami fractional kinetic model, and it is a complex multi-path adsorption process, which is related to the adsorption site and activity. The optimal adsorption temperature, water vapor concentration, CO2 concentration, and total gas volume were 60 °C, 15%, 12.5%, and 500 mL/min, respectively.