Controlled design of Na-P1 zeolite/ porous carbon composites from coal gasification fine slag for high-performance adsorbent.

Low-cost and concentrated industrial wastes have been recognized as a sustainable resource for preparation of new functional materials. Here, a new method was designed for the synthesis of porous composites containing high-purity Na-P1 zeolite and porous carbon from waste coal gasification fine slag (CGFS), which was treated first by acid leaching to controllably remove metal impurities and adjust Si/Al ratio, followed by NaOH fusion and hydrothermal treatment. By leaching with 1.0 mol/L HCl solution, the Si/Al ratio of the raw CGFS increased to 5.7, and the obtained CZ-1.0 consisted of high-purity Na-P1 zeolite with a typical cone-shaped flower cluster shape. The residue carbon in CGFS can be further activated to form porous carbon and graphite carbon layers interposed in the zeolite structure. The specific surface area and pore volume of CZ-1.0 reached 153.91 m2/g and 0.18 cm3/g, respectively. CZ-1.0 exhibited remarkable adsorption performance for methylene blue (MB) with the adsorption capacity reaching 137.5 mg/g for 100 mg/L MB solution. The adsorption process is mainly controlled by the chemisorption mechanism, and the adsorption of MB by CZ-1.0 may include ion exchange, hydrogen bond interaction, π-π bond interaction and van der Waals force. NaCl solution was successfully used as the desorption agent to regenerate the composite material, and the removal rate remained above 92% after five cycles. This work provides an effective strategy to synthesize a practically applicable adsorbent from the waste coal gasification fine slag for the purification of MB wastewater.

Syngas production from biomass pyrolysis in a continuous microwave assisted pyrolysis system.

In light of the knowledge gap in the scale-up of microwave-assisted pyrolysis technology, this study developed a continuous microwave-assisted pyrolysis (CMAP) system and examined its feasibility for syngas production. Wood pellets were pyrolyzed in the system under various temperatures, and the product distribution and energy efficiency were investigated. At a processing temperature of 800 °C, the CMAP system obtained a high quality producer gas (lower heating value 18.0 MJ/Nm3 and a 67 vol% syngas content) at a yield of 72.2 wt% or 0.80 Nm3/kg d.a.f. wood, outperforming several conventional pyrolysis processes probably due to two factors: 1) reactions between primary tar and biochar enhanced by microwave irradiation, and 2) the absence of carrier gas in the process. Energy efficiency of the process was also assessed. Potentially the electricity consumption could be reduced from 7.2 MJ to 3.45 MJ per kg of wood, enabling net electricity production from the process.

Fast microwave-assisted pyrolysis of wastes for biofuels production - A review.

Microwave-assisted pyrolysis of waste suffers from the problem that the waste generally has low microwave absorptivity thereby resulting in low heating rate and low pyrolysis temperature. In this case, fast microwave-assisted pyrolysis is proposed and developed to help the pyrolysis of waste. This study describes two methods that can be used to realize fast microwave-assisted pyrolysis of waste: (1) premixed method (wastes are mixed with microwave absorbent) and (2) non-premixed method (wastes are poured onto the heated microwave absorbent bed). Then, biofuels (bio-oil, bio-gas, and bio-char) produced from fast microwave-assisted pyrolysis of wastes are reviewed. The review results show that the yields of bio-oil, bio-gas, and bio-char obtained from fast microwave-assisted pyrolysis of wastes varied significantly in the ranges of 2-96 wt%, 2.4-86.8 wt%, and 0.3-83.2 wt%, respectively. Although the present research focused mainly on the premixed method, non-premixed/continuous fast microwave-assisted pyrolysis is still promising and challenging.

Development of biochar-based nanocatalysts for tar cracking/reforming during biomass pyrolysis and gasification.

Gasification and pyrolysis have been considered as potential routes for the production of fuel gas from abundant, low-cost and renewable biomass materials. Tar is the undesirable but inevitable byproduct during these processes, which not only lowers the overall energy conversion efficiency but also leads to potential contamination and clogging problems. Catalytic reforming has been seen as one of the most promising methods for tar elimination, and biochar-based nanocatalysts (BBNs) show promise as an efficient tar reforming catalyst. Extensive research efforts have been devoted to the development of BBNs to reduce biomass tar below tolerable limits. This current study reviews the recent progress in the preparation and application of BBNs for converting tar into fuel gas during biomass gasification or pyrolysis. The formation and chemical characteristics of the BBNs are introduced for a better understanding of the catalytic mechanism; prospects for success, as well as challenges, are also discussed.

Enhanced CO2 biofixation and protein production by microalgae biofilm attached on modified surface of nickel foam.

In this work, a photobioreactor with microalgae biofilm was proposed to enhance CO2 biofixation and protein production using nickel foam with the modified surface as the carrier for immobilizing microalgae cells. The results demonstrated that, compared with microalgae suspension, microalgae biofilm lowered mass transfer resistance and promoted mass transfer efficiency of CO2 from the bubbles into the immobilized microalgae cells, enhancing CO2 biofixation and protein production. Moreover, parametric studies on the performance of the photobioreactor with microalgae biofilm were also conducted. The results showed that the photobioreactor with microalgae biofilm yielded a good performance with the CO2 biofixation rate of 4465.6 µmol m-3 s-1, the protein concentration of effluent liquid of 0.892 g L-1, and the protein synthesis rate of 43.11 g m-3 h-1. This work will be conducive to the optimization design of microalgae culture system for improving the performance of the photobioreactor.

Characterization of herb residue and high ash-containing paper sludge blends from fixed bed pyrolysis.

High ash-containing paper sludge which is rich in various metal oxides is employed in herb residue pyrolysis to enhance the yield of fuel gas and reduce tar yield in a drop tube fixed bed reactor. Effects of heat treatment temperature and blending ratio of paper sludge on the yields and composition of pyrolysis products (gas, tar and char) were investigated. Results indicate that paper sludge shows a significantly catalytic effect during the pyrolysis processes of herb residue, accelerating the pyrolysis reactions. The catalytic effect resulted in an increase in gas yield but a decrease in tar yield. The catalytic effect degree is affected by the paper sludge proportions, and the strongest catalytic effect of paper sludge is noted at its blending ratio of 50%. At temperature lower than 900 °C, the catalytic effect of paper sludge in the pyrolysis of herb residue promotes the formation of H2 and CO2, inhibits the formation of CH4, but shows slight influence on the formations of CO, while the formation of the four gas components was all promoted at 900 °C. SEM results of residue char show that ash particles from paper sludge adhere to the surface of the herb residue char after pyrolysis, which may promote the pyrolysis process of herb residue for more gas releasing. FT-IR results indicate that most functional groups disappear after pyrolysis. The addition of paper sludge promotes deoxidisation and aromatization reactions of hetero atoms tars, forming heavier polycyclic aromatic hydrocarbons and leading to tar yield decrease.

A multiphase mixture model for substrate concentration distribution characteristics and photo-hydrogen production performance of the entrapped-cell photobioreactor.

A multiphase mixture model was developed for revealing the interaction mechanism between biochemical reactions and transfer processes in the entrapped-cell photobioreactor packed with gel granules containing Rhodopseudomonas palustris CQK 01. The effects of difference operation parameters, including operation temperature, influent medium pH value and porosity of packed bed, on substrate concentration distribution characteristics and photo-hydrogen production performance were investigated. The results showed that the model predictions were in good agreement with the experimental data reported. Moreover, the operation temperature of 30 °C and the influent medium pH value of 7 were the most suitable conditions for photo-hydrogen production by biodegrading substrate. In addition, the lower porosity of packed bed was beneficial to enhance photo-hydrogen production performance owing to the improvement on the amount of substrate transferred into gel granules caused by the increased specific area for substrate transfer in the elemental volume.

Enhanced photo-H2 production by unsaturated flow condition in continuous culture.

A biofilm photobioreactor under unsaturated flow condition (BFPBR-U) is proposed using a polished optical fiber as the internal light source for photo-H2 production in continuous culture. The main chamber was filled with spherical glass beads to create the reaction bed and the cells were immobilized to form a biofilm under unsaturated flow condition obtained by pumping substrate solution over a packing bed at a rate to create a thin fluid film and injecting the argon to maintain the gas phase space. The effects of operational conditions, including flow rate and influent substrate concentration, on the photo-H2 production performance were investigated. The unsaturated flow conditions eliminated the inhibition caused by high organic loading rate and enhanced light transmission efficiency, leading to an improvement in the photo-H2 production performance.

An innovative example of herb residues recycling by gasification in a fluidized bed.

A utilization way of herb residues is designed to convert herb residues to gas fuel in industrial-scale by a circulating fluidized bed gasifier in this paper. The product gas is used in the production of Chinese medicine, and the heat of the flue gas from the boiler can be used in herb residues drying to realize the energy recycling and no herb residues discharge. The gasification characteristics of herb residues in the circulating fluidized bed of 300 kg/h were investigated for about 200 h. The results indicated that the gas composition and tar yield were affected by biomass flow rate, equivalence ratio (ER), moisture content and char circulating. The lower heating value of product gas was 4-5 MJ/m(3) using herb residues as feedstock. When mean biomass flow rate was at 5.5 kg m(-2)s(-1) and ER at 0.35, the product gas reached a good condition with lower heating value of 4.89 MJ/m(3) and cold gas efficiency of 62.36%. When the moisture content changed from 12.5% to 18.7%, the concentrations of H2, CO and CO2 changed from 4.66% to 6.92%, 11.23% to 10.15%, and 16.55% to 17.82% respectively, and the tar content in gas decreased from 15.1g/m(3) to 14.4 g/m(3) when the moisture content increased from 12.5% to 15.4%. There are metal oxides in the ash of herb residues, especially CaO, MgO, K2O, Al2O3, and Fe2O3 which have obvious function on tar catalytic decomposition. The ash that attaches to the char particles can decrease the tar yield and improve the quality of gas after returning to the gasifier.