Fate of sulfur and chlorine during co-incineration of municipal solid waste and industrial organic solid waste.

In China, the co-incineration of municipal solid waste (MSW) with industrial organic solid waste (IOSW) is increasingly adopted. Compared with MSW, IOSW contains higher levels of sulfur (S) and chlorine (Cl), presenting significant challenges for controlling S/Cl emissions in MSW incineration plants. In this study, the impact of co-incinerating IOSW was investigated in a 500 t/d incinerator grate, focusing on the emissions and transformation behaviors of S/Cl. IOSW, with a consistent sulfur content of about 0.22 wt% and a more variable chlorine content averaging 0.53 wt%, contains over 40 % organic sulfur and >90 % organic chlorine, higher than in MSW. The results of co-incineration experiments showed that the median SO2 concentration in the flue gas was stable at 50 mg/m3, while HCl concentration decreased initially and then increased as the co-incineration ratio of IOSW rose from 20 % to 40 %. Furthermore, the concentrations of SO2 and HCl were not significantly influenced by wind flow but were positively affected by the rising furnace temperatures. Besides, the co-incineration ratio had minimal impact on sulfur in fly ash before deacidification, primarily derived from the gas stream. However, the (Na + K)/Cl ratio in fly ash progressively increased from 1.5 to 1.9, and the Ca content decreased from 0.35 % to 0.15 % as the co-incineration ratio rose to 40 %, indicating more chlorine migration into the fly ash at higher co-incineration rates. This research offers essential guidance for effectively controlling pollutant emissions during the co-incineration of IOSW, specifically the S/Cl pollutants.

Evolution and speciation transformation of chlorine during automobile shredder residue pyrolysis.

Disposal of automobile shredder residue (ASR) via pyrolysis enables the recovery of valuable products; however, the production of hazardous pollutants and low-value products is inevitable due to its high chlorine content. In this work, chlorine evolution behavior and the conversion mechanism during ASR pyrolysis between 480 and 600 °C were systematically studied. The experimental results for organic chlorine (Org-Cl) showed that released chlorinated gases were complex, and HCl only accounted for 35% of the gas phase products, while short-chain hydrocarbons with carbon atoms between two and four accounted for 52%. Chlorine was predominantly retained in the char, and Org-Cl was the primary contributor to the residual chlorine, accounting for over 50% of the char. The content of inorganic chlorine (InO-Cl) was low in the raw sample but significantly increased in the char. Through the distinction between organic and inorganic chlorine content in char, it was confirmed that Org-Cl could be converted to InO-Cl due to complex secondary reactions with metallic compounds. The conversion was favored by increasing the Org-Cl content and the temperature. Our findings clarified the evolution mechanism of chlorine and the transformation from Org-Cl to InO-Cl, thus providing guidance for chlorine regulation and the efficient recycling of metal resources.

Investigation of properties change in the reacted molten salts after molten chlorides cyclic thermal treatment of toxic MSWI fly ash.

To realize the thermal detoxification of municipal solid waste incineration (MSWI) fly ash in a relatively mild environment, molten salts thermal treatment technology was proposed in our previous research, which showed good effects. To investigate the properties of molten salts (NaCl-CaCl2) during cycling reusing, the change of the main components and the physical properties of the used molten salts were estimated. Results showed that the salts in fly ash would dissolve into molten salts. During this process, the concentration of K+, SO42- kept increasing while Cl- was decreased. The changing trend of Na+ and Ca2+ was dependent on the ratio of Ca/Na in raw fly ash. Ca(OH)2 in fly ash would react with CaCl2 to form CaClOH. Moreover, the introduction of the salt components on the thermal properties of molten salts were also studied. The melting point hardly changed by NaCl, CaSO4, and SiO2. Nevertheless, it was lowered to 431 °C with 15% CaCO3 addition, while increased to 523 °C with 20% KCl. Besides, there were no significant influences on the viscosity, stability, and thermal diffusivity of molten salts. KCl had the greatest influence on the specific heat capacity of molten salt, with an increase of about 20%.

Ash formation and the inherent heavy metal partitioning behavior in a 100 t/d hazardous waste incineration plant.

Hazardous waste incineration (HWI) ash is also defined as hazardous waste and its disposal performance depends largely on the ash compositions as well as the potential environmental risk of heavy metals. In this work, HWI ashes of four sampling sites were collected in a 100 t/d hazardous waste incineration plant with rotary kiln over three consecutive days. The formation characteristics of ash samples including heavy metal partitioning were given, with further discussions on the melting disposal of HWI ash mixtures. Results showed significant differences in the ash compositions among the sampling sites. Caused by NaHCO3 injection as de-acidizing adsorbent, the sum of Na, S and Cl content in bag filter ash even exceeded 70%. Cu/Mn/Cr tended to transfer into the bottom ash due to low volatilities, while Zn/Pb/Cd/Se/As were more likely to be enriched in the ash particles. In particular, chemical adsorption at medium- to high- temperature range was dominant for As enrichment in the waste heat boiler ash. Despite the complexity and diversity of raw hazardous wastes, little difference was found in the melting temperature of bottom ash during the sampling period. However, it could vary by more than 200 °C for fly ash due to the fluctuation of alkali components in raw wastes. Moreover, slagging medium was encouraged in order to achieve rapid and complete melting of ash mixtures. The objective of this study is to gain knowledge on the HWI ash formation and inherent heavy metal partitioning behavior, expecting to provide guidelines on the deep harmless disposal of HWI ash in future.