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A FeCl3-catalyzed highly regioselective 1,2-addition/substitution sequence for the construction of coumarin-substituted bis(indolyl)methanes.
Wang, Wen-Bo; Zhu, Yan-Shuo; Guo, Sheng-Qiang; Wang, Qi-Lin; Bu, Zhan-Wei.
Org Biomol Chem ; 14(19): 4420-5, 2016 May 11.
Article in English | MEDLINE | ID: mdl-27086776

ABSTRACT

A FeCl3-catalyzed highly regioselective 1,2-addition/substitution sequence of 3-acetylcoumarins and indoles has been developed to afford highly hindered tetrasubstituted bis(indolyl)methanes bearing a biologically useful coumarin motif in 56-99% yields.


Subject(s)
Chlorides/chemistry , Coumarins/chemistry , Ferric Compounds/chemistry , Indoles/chemistry , Methane/chemistry , Catalysis , Stereoisomerism
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