Treatability of hazardous substances in industrial wastewater: case studies for textile manufacturing and leather production sectors.

Hazardous substances used and produced by different industrial activities pose a potential risk to the environment and to human health. Different physicochemical and/or biological processes are used in industrial wastewater treatment; these methods, however, may not be effective in removing these substances. This study was carried out to comparatively evaluate the removal of hazardous substances through conventional wastewater treatment processes that are used by major industries in Turkey. A four-season monitoring study was carried out in textile manufacturing and leather production sectors, representing industrial activities in Turkey. Samples were analyzed for 45 priority substances defined by the European Union and 250 specific pollutants listed in the Turkish Regulation on Surface Water Quality. For both wastewaters, where biological treatment was performed after pretreatment, their characteristics showed that organics were almost completely removed. except for dichloromethane (44-51% removals) and dioxin and dioxin-like compounds (64-69% removals). Additionally, different removal ratios (16-97%) were obtained for metals; the poorer removal was observed for B, Ba, Ag, Sb, and Si. The remaining metals (Cu, Pb, Sb, V, Si for textile; Cr, Cu, Sb, Si for leather effluents) in the treated wastewaters were still higher than environmental quality standards (EQS) of receiving water bodies. The study revealed that existing treatment processes were not adequate for efficient hazardous substance removal and there is an urgent need to improve them. Finally, advanced treatment technologies were suggested for specific pollutants together with their unit treatment costs.

Effects of treatment on the characterization of organic matter in wastewater: a review on size distribution and structural fractionation.

Since it is difficult to analyze the components of organic matter in complex effluent matrices individually, the use of more collective, but at the same time, specific wastewater characterization methods would be more appropriate to evaluate changes in effluent characteristics during wastewater treatment. For this purpose, size distribution and structural (resin) fractionation tools have recently been proposed to categorize wastewater. There are several case studies available in the scientific literature being devoted to the application of these fractionation methods. This paper aimed to review the most relevant studies dealing with the evaluation of changes in wastewater characteristics using size distribution and structural (resin) fractionation tools. According to these studies, sequential filtration-ultrafiltration procedures, as well as XAD resins, are frequently employed for size and structural fractionations, respectively. This review focuses on the most relevant publications including biological treatment processes, as well as chemical treatment methods such as coagulation-flocculation, electrocoagulation, the Fenton's reagent and ozonation. This study aims at providing an insight into the possible treatment mechanisms and details the understanding what structural features of wastewater components enabled or prevented efficient treatment (removal) or targeted pollutants.