ABSTRACT
We synthesized two nickel sulfide powders by simple method. One is nickel sulfide powder (CNS) by co-precipitation is composed of nano-sized nickel sulfides as NiS and NIS2. The other is nickel sulfide powder (HNS) by heat-treatment of CNS is composed nano-sized NIS. The electrode using CNS has a high first discharge capacity of 600 mA h g(-1) at 0.5 C and the discharge capacity after 20th cycle is 312 mA h g(-1). The electrode using HNS has a high first discharge capacity of 551 mA h g(-1) at 0.5 C and has the discharge capacity of 412 mA h g(-1) after 50th. The discharge rate capability has over 92% at 1 C versus 0.2 C. The nano-sized nickel sulfides are synthesized by simple co-precipitation method has good electrochemical properties such as high first discharge capacity, good cycle life and good rate capability for lithium secondary battery.
ABSTRACT
In this work, silicon (Si) containing carbon coated core-shell nanostructures were synthesized by electrical explosion of Si wires in ethanol solution followed by high energy mechanical milling (HEMM) process. Material characterization was carried-out using transmission electron microscopy (TEM), field-emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) analysis. HEMM led to very fine and amorphous Si particles in the presence of carbon and inactive Silicon-Carbide (SiC) matrix. These Si based nanocomposites, obtained through electrical explosion followed by HEMM (milled sample), exhibited enhanced electrochemical performance than unmilled nanocomposites, when evaluated as anode material for lithium-ion batteries (LIBs). On completion of (the) 1st cycle, milled and unmilled sample(s) showed specific discharge capacities around 825 mAh/g and 717 mAh/g, respectively. Interestingly, the coulombic efficiencies of milled and unmilled samples were 98.5% and 97% after 60th cycle respectively. The enhanced electrochemical performance is attributed to fine and amorphous Si based nanocomposite obtained through HEMM process.