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1.
J Food Prot ; 73(10): 1891-901, 2010 Oct.
Article in English | MEDLINE | ID: mdl-21067678

ABSTRACT

Four Tunisian virgin olive oils (VOOs), derived from varieties (Chemlali Tataouine, Zarrazi Douirat, Fakhari Douirat, and Dhokar Douirat) grown in the harsh pedoclimatic conditions of the region of Tataouine, were evaluated for their responses to microwave heating. Aside from fatty acid composition, all other evaluated parameters were affected by microwave heating, and their variations depend on the genetic factor. Chemlali Tataouine VOO exhibited the slowest biophenol degradation rate and the least diminution in oxidative stability and consequently, its total fraction and both lipidic and methanolic fractions remained unchanged with an exceptional antioxidant potential. In the remaining studied VOOs, the biophenol contents, the oxidative stability, and the antioxidant potential underwent gradual decreases; nevertheless, their levels at the longer treatment time are close to some fresh VOOs. These results should be taken into consideration when Tataouine VOOs are recommended for microwave heating.


Subject(s)
Food Handling/methods , Microwaves , Plant Oils/chemistry , Plant Oils/radiation effects , Antioxidants/analysis , Antioxidants/metabolism , Fatty Acids/analysis , Fatty Acids/metabolism , Olive Oil , Oxidation-Reduction , Phenols/analysis , Phenols/metabolism , Tunisia
2.
J Agric Food Chem ; 56(17): 7992-8, 2008 Sep 10.
Article in English | MEDLINE | ID: mdl-18690679

ABSTRACT

The Tataouine province in southern Tunisia is well known for its severe pedoclimatic conditions. Using solid phase microextraction (SPME) and gas chromatography (GC), coupled to flame ionization and mass spectrometer detectors, we characterized virgin olive oils from Chemlali Tataouine, Fakhari Douirat, Zarrazi Douirat, and Dhokar Douirat varieties, which grow in the harsh arid region of Tataouine. Significant differences in the proportions of volatile constituents from oils of different varieties were detected. The results showed that lipoxygenase products were generally the major metabolites of the volatile fraction, and (E)-Hex-2-enal was the principal compound characterizing the olive oil headspace for most samples, though the absolute levels varied greatly, never exceeding 76.45 and 32.16%, respectively. The C5 compounds were unusually abundant, comprising 42.97% of the total lipoxygenase products and a remarkably high level of penten dimers. Each autochthonous variety could thus be differentiated according to the percentage of each metabolite.


Subject(s)
Plant Oils/chemistry , Climate , Gas Chromatography-Mass Spectrometry , Hexobarbital/analysis , Lipoxygenase/metabolism , Olive Oil , Oxidation-Reduction , Phenols/analysis , Triglycerides/analysis , Tunisia , Volatilization
3.
J Agric Food Chem ; 55(26): 10941-6, 2007 Dec 26.
Article in English | MEDLINE | ID: mdl-18044828

ABSTRACT

The physicochemical and stability properties as well as the fatty acid, triacylglycerol, sterol, and triterpenic dialcohol compositions of Tunisian olive oil varieties were analyzed. On the basis of our results, we classified all of the monovarietal oils into the extra virgin category. Oleic and linoleic acids were the most useful fatty acids to discriminate three cultivars, Neb Jmel, Chétoui, and Ain Jarboua, from the others. Of the six monovarietal virgin olive oils analyzed, the main triacylglycerols were OOO, POO, PLO plus SLL, and OLO, which was expected given the high oleic acid and low linoleic and linolenic acids content observed in total fatty acids. In total, these accounted for more than 80% of the total HPLC chromatogram peak area. The main sterols found were beta-sitosterol, Delta5-avenasterol, and campesterol. The statistical analysis showed significant differences between oil samples, and the obtained results showed a great variability in the oil composition between cultivars, which is influenced exclusively by genetic factors.


Subject(s)
Fatty Acids/analysis , Fruit/chemistry , Olea/chemistry , Phytosterols/analysis , Triglycerides/analysis , Species Specificity , Tunisia
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