1.
Chem Commun (Camb)
; 51(25): 5287-9, 2015 Mar 28.
Article
in English
| MEDLINE
| ID: mdl-25558484
ABSTRACT
The conversion of readily available silylalkynes, iodobenzene diacetate, and azide anions was utilized to form and react cyanocarbenes. A copper(II)-catalyzed reaction was found to react in a different manner. Both of these methods benefit from the formation and in situ reaction of hypervalent iodonium alkynyl triflates in O-H insertion reactions.