Elucidating of potentially toxic elements contamination in topsoils around a copper smelter: Spatial distribution, partitioning and risk estimation.

Soil pollution by potentially toxic elements (PTEs) as one of the major environmental hazards is associated with metal exploration and refining acting. In this study, forty-five topsoil samples surrounding a copper smelter factory were taken and analysed using standard routine methods. The total concentration, chemical fractionation and the mobility potential of As, Cd, Cr, Cu, Pb and Zn were analysed. Additionally, the spatial distribution of PTEs, the potential ecotoxicological, and human health risks was assessed. The range of total Cu was 1478-4718 mg kg-1, reaching up to 501.5, 21.6, 118.4, 573.5 and 943.3 mg kg-1 for total contents of As, Cd, Cr, Pb and Zn, respectively. The potentially available fractions after sequential extraction reveal all studied PTE were dramatically mobile and available in the studied area (86%, 69.3%, 59.5%, 87.2%, 84% and 68% for As, Cd, Cr, Pb, Zn and Cu, respectively), reflecting that the concentration and accumulation of these elements are profoundly affected or originated by smelting activities and deposition of atmospheric emissions of the Cu smelting factory. The spatial distribution of all PTEs indicated that concentrations of these element near the smelter Cu-factory were elevated. Accordingly, the ecotoxicology status of the studied area suggests that significantly high risks are posed by the measured PTEs. Non-carcinogenic effects of As, Pb and Cu were significantly much higher than the recommended value (HI = 1), suggesting that these three PTEs could adversely impact children's health. For adults, only the HI value of As was greater than one.

Occurrence and source apportionment of polycyclic aromatic hydrocarbons (PAHs) in dust of an emerging industrial city in Iran: implications for human health.

Polycyclic aromatic hydrocarbons (PAHs) bounded to street dust are a severe environmental and human health danger. This study provides preliminary information on the abundance of PAHs in street dust from Rafsanjan city, Iran, where industrial emissions are high and data are lacking. Seventy street dust samples were collected from streets with different traffic loads. The United States Environmental Protection Agency (USEPA) Standard Methods 8270D and 3550C were used for the measurement of PAHs using GC mass spectroscopy. The total concentration of PAHs was 1443 ng g-1, with a range of 1380-1550 ng g-1. Additionally, the concentration of carcinogenic PAHs (∑carcPAHs) ranged from 729.5 to 889.4 ng g-1, with a mean value of 798.1 ng g-1. Pyrene was the most abundant PAH, with an average concentration of 257 ng g-1. Source identification analyses showed that vehicle emissions along with incomplete combustion and petroleum were the main sources of PAHs. The ecological risk status of the studied area was moderate. Spatial distribution mapping revealed that the streets around the city center and oil company had higher PAH levels than the other sectors of Rafsanjan. The results indicated that dermal contact and ingestion of contaminated particles were the most important pathways compared to inhalation. The mean incremental lifetime cancer risk (ILCR) was 1.4 × 10-3 and 1.3 × 10-3 for children and adults, respectively. This implies potentially adverse health effects in exposed individuals. The mutagenic risk for both subpopulations was approximately 18 times greater than the one recommended by USEPA. Our findings suggest that children are subjected to a higher carcinogenic and mutagenic risk of PAHs, especially dibenzo[a,h]anthracene (DahA), bounded to street dust of Rafsanjan. Our study highlights the need for the development of emission monitoring and control scenarios.