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1.
Insects ; 10(8)2019 Aug 14.
Article in English | MEDLINE | ID: mdl-31416241

ABSTRACT

The adult male of Allokermes galliformis (Riley, 1881) (Hemiptera: Coccomorpha: Kermesidae) is described for the first time in Colorado, United States of America. This scale insect species recently emerged as a significant pest of red oaks in Colorado through its causative role in drippy blight disease. A description and illustration of the adult male characterize its key external morphological characteristics.

2.
J Org Chem ; 70(24): 9740-54, 2005 Nov 25.
Article in English | MEDLINE | ID: mdl-16292802

ABSTRACT

[reaction: see text] Glycosyl disulfides have been shown for the first time to be effective glycosyl donors. Glucosylation and galactosylation of a panel of representative alcohol acceptors allowed the formation of 28 simple glycosides, disaccharides, and glycoamino acids in yields of up to 90%. As well as providing a novel class of effective glycosyl donors, the ability to easily alter the nature of the aglycon and the ability to differently activate donors that differ only in their aglycon simply through altering conditions lends glycosyl disulfide donors to their use in latent-active reactivity tuning strategies.


Subject(s)
Disulfides/chemistry , Doxorubicin/chemical synthesis , Glycosides/chemistry , Disulfides/chemical synthesis , Doxorubicin/analogs & derivatives , Doxorubicin/chemistry , Glycosides/chemical synthesis , Glycosylation , Molecular Conformation
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