1.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 8): m1007, 2010 Jul 24.
Article
in English
| MEDLINE
| ID: mdl-21588087
ABSTRACT
In the crystal structure of the title compound, [Co(H(2)O)(6)](C(16)H(8)O(8)), both the cation and anion are centrosymmetric. The Co cation displays a CoO(6) octa-hedral geometry formed by six water mol-ecules. In the anion, the two carboxyl groups are oriented at dihedral angles of 4.8â (5) and 10.4â (7)° with respect to the benzene ring. Very strong O-Hâ¯O hydrogen bonds between the protonated and deprotonated carboxylate groups occur. Neighbouring cations and anions are connected through O-Hâ¯O hydrogen bonds into a three-dimensional supra-molecular structure.