ABSTRACT
Structures that are highly ordered in nature show unique light propagation abilities. Among them, micro-honeycomb arrays are attractive owing to their advantages relating to the collection of light or enlarging the viewing angle and, also, owing to their potential applications in precision optics. Inspired by the natural phenomenon of droplet condensation on a cold surface, breath figure self-assembly has been a common approach used to fabricate such ordered micro-honeycomb arrays. However, the harsh preparation conditions and specific polymer architecture required have limited the widespread application of this approach. In this work, by using a commercial linear homopolymer and introducing its nonsolvent, we successfully fabricated uniform micro-honeycomb arrays on a large scale in just seconds and at ambient humidity. The morphology of the structures can be easily tuned via controlling the preparation conditions. Furthermore, high fill-factor convex micro-lenses were prepared based on the as-prepared concave micro-honeycomb arrays as templates through a simple replication process. They demonstrate properties such as clear multiple image presentation and light diffraction. They can also assist the strong scattering of light, which enhances the fluorescent intensity by more than 10%. This method is envisaged as a potential candidate to replace breath figure self-assembly for micro-honeycomb arrays in a low-cost and high-efficiency manner under mild conditions.
ABSTRACT
Photothermal conversion behavior has a vital application to disease therapy, water purification, or uncontacted heaters. The fabrication of high-performance photothermal conversion materials especially for near-infrared (NIR) light and microstructures has attracted a great deal of attention. Among numerous substances, MXene as a new type of 2D material with semi-metallic and unique electromagnetic properties presents a broader absorption of light and even a typical plasmonic absorption near the NIR-I area (808 nm), which has made it suitable for photothermal conversion. Here, we propose a facile approach for preparing a Ti3C2Tx/ionic liquid ink with a high photothermal conversion efficiency. The as-prepared ink has showed good wettability of various substrates as well as the high sensitivity of 808 nm NIR light irradiation and a wide range of thermal variation. After packing the ink into a gel pen refill, the flexible thermal chips could be easily obtained just by pen writing on the soft surface with the designed size, which also have become an optimal candidate for the thermal alarm system.
ABSTRACT
Conductive microwrinkles present a superior performance in ultrasensitive sensing, smart controlling, as well as energy conservation because of their unique structures. These wrinkles are usually prepared by the deposition of a thin conductive stiff layer on a soft substrate under a certain strain. However, traditional conductive materials may encounter some deficiencies, such as fragility or poor dispersity, in any solvent. To promote the applicability of conductive microwrinkles, here, we adopt a new two-dimensional nanomaterial Ti3C2Tx MXene as the conductive stiff layer to construct the microwrinkles. By combining the spraying and inflating techniques, the hierarchical complex and delicate Ti3C2Tx-polyurethane (Ti3C2Tx-PU) microwrinkles have become facilely available. The characteristic wavelength and amplitude of the microwrinkles could be easily adjusted by altering the inflating height of the PU film or the spraying volume of the Ti3C2Tx solution. Because the as-prepared Ti3C2Tx wrinkles could sensitively generate deformation inducing a resistance change under a force, these structures are also assembled to detect the applied force. The Ti3C2Tx force sensors showed quick response to a tiny force and stable reliability over hundreds of cycles, which hold a promising potential to monitor or employ the microforce.
